C08F6/22

ACRYLIC RUBBER BALE EXCELLENT IN STORAGE STABILITY AND PROCESSABILITY
20220267491 · 2022-08-25 · ·

An acrylic rubber bale excellent in storage stability and processability, a method for producing the same, a rubber mixture obtained by mixing the acrylic rubber bale, and a rubber cross-linked product of the rubber mixture are provided. The acrylic rubber bale according to the present invention includes an acrylic rubber having a reactive group and a weight average molecular weight (Mw) of 100,000 to 5,000,000, wherein an amount of gel insoluble in methyl ethyl ketone is 50% by weight or less, and pH is 6 or less.

Process for producing polytetrafluoroethylene molding powder and process for producing polytetrafluoroethylene agglomerated product

To provide a process for producing a PTFE molding powder having a high bulk density from granular polymer particles without using an emulsifying agent having problems of bioaccumulation and toxicity. A process for producing a polytetrafluoroethylene molding powder, which comprises a step of suspension-polymerizing a monomer containing at least 99.8 mass % of tetrafluoroethylene in an aqueous medium to produce granular polymer particles and a step of milling the granular polymer particles, wherein the aqueous medium contains a compound represented by R.sup.F(OCF(X.sup.1)CF.sub.2).sub.k-1OCF(X.sup.2)COO.sup.−M.sup.+, at a concentration of from 0.5 to 2,000 ppm. R.sup.F is a perfluorinated C.sub.1-10 monovalent organic group, X.sup.1 and X.sup.2 are fluorine atoms, etc., and M.sup.+ is an ammonium ion or the like.

Process for producing polytetrafluoroethylene molding powder and process for producing polytetrafluoroethylene agglomerated product

To provide a process for producing a PTFE molding powder having a high bulk density from granular polymer particles without using an emulsifying agent having problems of bioaccumulation and toxicity. A process for producing a polytetrafluoroethylene molding powder, which comprises a step of suspension-polymerizing a monomer containing at least 99.8 mass % of tetrafluoroethylene in an aqueous medium to produce granular polymer particles and a step of milling the granular polymer particles, wherein the aqueous medium contains a compound represented by R.sup.F(OCF(X.sup.1)CF.sub.2).sub.k-1OCF(X.sup.2)COO.sup.−M.sup.+, at a concentration of from 0.5 to 2,000 ppm. R.sup.F is a perfluorinated C.sub.1-10 monovalent organic group, X.sup.1 and X.sup.2 are fluorine atoms, etc., and M.sup.+ is an ammonium ion or the like.

Process for producing polytetrafluoroethylene molding powder and process for producing polytetrafluoroethylene agglomerated product

To provide a process for producing a PTFE molding powder having a high bulk density from granular polymer particles without using an emulsifying agent having problems of bioaccumulation and toxicity. A process for producing a polytetrafluoroethylene molding powder, which comprises a step of suspension-polymerizing a monomer containing at least 99.8 mass % of tetrafluoroethylene in an aqueous medium to produce granular polymer particles and a step of milling the granular polymer particles, wherein the aqueous medium contains a compound represented by R.sup.F(OCF(X.sup.1)CF.sub.2).sub.k-1OCF(X.sup.2)COO.sup.−M.sup.+, at a concentration of from 0.5 to 2,000 ppm. R.sup.F is a perfluorinated C.sub.1-10 monovalent organic group, X.sup.1 and X.sup.2 are fluorine atoms, etc., and M.sup.+ is an ammonium ion or the like.

THERMOPLASTIC RESIN COMPOSITION, METHOD OF PREPARING THE SAME AND MOLDED PRODUCT USING THE SAME

Disclosed are a thermoplastic resin composition and a method of preparing the same. More particularly, the present invention relates to a thermoplastic resin composition including 10 to 90% by weight of a graft copolymer resin coagulated by an organic acid or an organic acid salt; and 90 to 10% by weight of a non-graft copolymer resin and having a moist-heat characteristic of 20 or less, wherein a refractive index difference between the graft copolymer resin and the non-graft copolymer resin is less than 0.01, a method of preparing the same, and a molded product comprising the same. According to the present disclosure, provided are a thermoplastic resin composition having superior overall property balance, color, and transparency, and being applicable to products that are exposed to high-temperature water or should be sterilized, due to excellent moist-heat resistance thereof, a method of preparing the same, and a molded product comprising the same.

THERMOPLASTIC RESIN COMPOSITION, METHOD OF PREPARING THE SAME AND MOLDED PRODUCT USING THE SAME

Disclosed are a thermoplastic resin composition and a method of preparing the same. More particularly, the present invention relates to a thermoplastic resin composition including 10 to 90% by weight of a graft copolymer resin coagulated by an organic acid or an organic acid salt; and 90 to 10% by weight of a non-graft copolymer resin and having a moist-heat characteristic of 20 or less, wherein a refractive index difference between the graft copolymer resin and the non-graft copolymer resin is less than 0.01, a method of preparing the same, and a molded product comprising the same. According to the present disclosure, provided are a thermoplastic resin composition having superior overall property balance, color, and transparency, and being applicable to products that are exposed to high-temperature water or should be sterilized, due to excellent moist-heat resistance thereof, a method of preparing the same, and a molded product comprising the same.

THERMOPLASTIC RESIN AND THERMOPLASTIC RESIN COMPOSITION INCLUDING THE SAME

The present invention relates to a thermoplastic resin. In accordance with the present invention, a thermoplastic resin exhibiting superior heat resistance, gloss, and whiteness while having mechanical properties identical to or higher than those of a conventional thermoplastic resin and a thermoplastic resin composition including the same are provided.

THERMOPLASTIC RESIN AND THERMOPLASTIC RESIN COMPOSITION INCLUDING THE SAME

The present invention relates to a thermoplastic resin. In accordance with the present invention, a thermoplastic resin exhibiting superior heat resistance, gloss, and whiteness while having mechanical properties identical to or higher than those of a conventional thermoplastic resin and a thermoplastic resin composition including the same are provided.

Thermoplastic resin powder and method for producing same

The objective of the present invention is to provide a thermoplastic resin powder that suppresses a decrease in fluidity of a composition during melt molding and that has a suppressed alteration of the resin resulting from retention. The thermoplastic resin powder is obtained by coagulating a polymer from a latex produced by means of emulsion polymerization of a monomer, the content of metal-corroding free acids in the thermoplastic resin powder is no greater than 500 ppm, and the thermoplastic resin powder satisfies a predetermined formula (1).

Thermoplastic resin powder and method for producing same

The objective of the present invention is to provide a thermoplastic resin powder that suppresses a decrease in fluidity of a composition during melt molding and that has a suppressed alteration of the resin resulting from retention. The thermoplastic resin powder is obtained by coagulating a polymer from a latex produced by means of emulsion polymerization of a monomer, the content of metal-corroding free acids in the thermoplastic resin powder is no greater than 500 ppm, and the thermoplastic resin powder satisfies a predetermined formula (1).