Multi-block isoporous structures for non-aqueous and/or harsh chemical media having at least one of high separation specificity, chemical resistance, and antifouling properties, methods of manufacturing and use, for replacements or alternatives to existing separation membrane technologies.

Multi-block isoporous structures for non-aqueous and/or harsh chemical media having at least one of high separation specificity, chemical resistance, and antifouling properties, methods of manufacturing and use, for replacements or alternatives to existing separation membrane technologies.

Multi-block isoporous structures for non-aqueous and/or harsh chemical media having at least one of high separation specificity, chemical resistance, and antifouling properties, methods of manufacturing and use, for replacements or alternatives to existing separation membrane technologies.

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

Embodiments of the invention relate generally to anion exchange membranes and, more particularly, to anion exchange membranes comprising a styrene block copolymer and methods for their manufacture. In one embodiment, the invention provides a polymer according to formula IV, wherein x and y are mol %, QA is or each of R.sub.1 and R.sub.2 is, independently, a linear alkyl chain or a cyclic alkyl chain, and Z is selected from a group consisting of: a linear alkyl chain, a cyclic alkyl chain, and an alkylene ether chain.

Provided is an ionomer resin including a copolymer containing the following first structural unit. ##STR00001## L.sub.1 to L.sub.5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is Z.sub.2-M.sub.1-Z.sub.1(R.sub.1)(R.sub.2)(R.sub.3). R.sub.1 to R.sub.3 are directly bonded to Z.sub.1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M.sub.1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z.sub.1 is a nitrogen atom or a phosphorus atom, and Z.sub.2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L.sub.6 is a hydrogen atom, a methyl group, or an ethyl group.

Provided is an ionomer resin including a copolymer containing the following first structural unit. ##STR00001## L.sub.1 to L.sub.5 are each independently a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, an alkanol group having 1 to 4 carbon atoms, or a specific functional group including an anion-exchange group, and an example of the functional group is Z.sub.2-M.sub.1-Z.sub.1(R.sub.1)(R.sub.2)(R.sub.3). R.sub.1 to R.sub.3 are directly bonded to Z.sub.1 and are each independently an alkyl group having 1 to 8 carbon atoms or an alkanol group having 1 to 8 carbon atoms. M.sub.1 is a linear hydrocarbon chain having 3 to 8 carbon atoms, Z.sub.1 is a nitrogen atom or a phosphorus atom, and Z.sub.2 is a nitrogen atom bonded to one hydrogen atom, an oxygen atom, or a sulfur atom. L.sub.6 is a hydrogen atom, a methyl group, or an ethyl group.

The present invention relates to an iminodiacetic acid chelating resin, wherein the water amount in the resin is from 50 to 75% and the volume ratio of Na form/H form is from 1.4 to 1.8. Furthermore, the present invention relates to a method for producing an iminodiacetic acid chelating resin, wherein an alcohol is used as a solvent for the amination reaction of a chloromethylated styrene crosslinked copolymer with iminodiacetonitrile or sodium iodide and/or potassium iodide is used as a catalyst for the amination reaction.

The present invention relates to an iminodiacetic acid chelating resin, wherein the water amount in the resin is from 50 to 75% and the volume ratio of Na form/H form is from 1.4 to 1.8. Furthermore, the present invention relates to a method for producing an iminodiacetic acid chelating resin, wherein an alcohol is used as a solvent for the amination reaction of a chloromethylated styrene crosslinked copolymer with iminodiacetonitrile or sodium iodide and/or potassium iodide is used as a catalyst for the amination reaction.