Patent classifications
C08F14/04
Liquid compositions of fluorinated ion exchange polymers
A liquid composition comprising at least one aprotic organic solvent and at least one fluorinated ion exchange polymer which consists of recurring units derived from a chlorofluoroolefin of formula CF.sub.2CCIY, wherein Y is F or CI, and from at least one fluorinated functional monomer selected among those of formula CF.sub.2CFO(CF.sub.2CF(CF.sub.3)O).sub.m(CF.sub.2).sub.nSO.sub.2X, wherein m is an integer equal to 0 or 1, n is an integer from 0 to 10 and X is chosen among halogens (CI, F, Br, I), O.sup.M.sup.+, wherein M.sup.+ is a cation selected among H.sup.+, NH.sub.4.sup.+, K.sup.+, Li.sup.+, Na.sup.+, or mixtures thereof is disclosed. The liquid composition is suitable for the preparation of ion exchange membranes, in particular composite membranes, for use in fuel cell applications.
Liquid compositions of fluorinated ion exchange polymers
A liquid composition comprising at least one aprotic organic solvent and at least one fluorinated ion exchange polymer which consists of recurring units derived from a chlorofluoroolefin of formula CF.sub.2CCIY, wherein Y is F or CI, and from at least one fluorinated functional monomer selected among those of formula CF.sub.2CFO(CF.sub.2CF(CF.sub.3)O).sub.m(CF.sub.2).sub.nSO.sub.2X, wherein m is an integer equal to 0 or 1, n is an integer from 0 to 10 and X is chosen among halogens (CI, F, Br, I), O.sup.M.sup.+, wherein M.sup.+ is a cation selected among H.sup.+, NH.sub.4.sup.+, K.sup.+, Li.sup.+, Na.sup.+, or mixtures thereof is disclosed. The liquid composition is suitable for the preparation of ion exchange membranes, in particular composite membranes, for use in fuel cell applications.
PVDF-TrFE co-polymer having improved ferroelectric properties, methods of making a PVDF-TrFE co-polymer having improved ferroelectric properties and methods of changing the end group of a PVDF-TrFE co-polymer
A method of exchanging or transforming end groups in and/or improving the ferroelectric properties of a PVDF-TrFE co-polymer is disclosed. A bulky or chemically dissimilar end group, such as an iodine, sulfate, aldehyde or carboxylic acid end group, may be transformed to a hydrogen, fluorine or chlorine atom. A method of making a PVDF-TrFE co-polymer is disclosed, including polymerizing a mixture of VDF and TrFE using an initiator, and transforming a bulky or chemically dissimilar end group to a hydrogen, fluorine or chlorine atom. A PVDF-TrFE co-polymer or other fluorinated alkene polymer is also disclosed. The co-polymer may be used as a ferroelectric, electromechanical, piezoelectric or dielectric material in an electronic device.
PTFE AND ACTIVE PARTICLE COMPOSITIONS
Tapes, expanded tapes, and methods of making the same. The tapes and expanded tapes include long-strand PTFE fibrils, short-strand PTFE fibrils, and an oriented network. The oriented network includes nodes. The nodes include active particles and short-strand PTFE fibrils distributed among the active particles.
PTFE AND ACTIVE PARTICLE COMPOSITIONS
Tapes, expanded tapes, and methods of making the same. The tapes and expanded tapes include long-strand PTFE fibrils, short-strand PTFE fibrils, and an oriented network. The oriented network includes nodes. The nodes include active particles and short-strand PTFE fibrils distributed among the active particles.
Method of producing fluorine-containing compound and method of producing copolymer
A method of producing a fluorine-containing compound is a method of producing a compound (30) having partial structure (3) by an insertion reaction of compound (20) into compound (10) that has partial structure (1), in the presence of an ionic catalyst formed from a specific monovalent anion and a counter cation. In the formulas, * represents a bonding site, and X.sup.1 and R.sup.1 to R.sup.4 each independently represents a hydrogen atom, a fluorine atom, a chlorine atom, or an organic group having a carbon number of 1 to 20 which may have a substituent. ##STR00001##