The present invention provides a composition comprising 1) an aqueous dispersion of polymer particles having a core-shell morphology wherein the core protuberates from the shell; wherein the core comprises from 5 to 90 weight percent structural units of a fluoroalkylated monomer, and 2) less than 0.09 weight percent structural units of a phosphorus acid monomer; and wherein the shell comprises from 0.1 to 5 weight percent of itaconic acid or a phosphorus acid monomer, based on the weight of the shell. The present invention addresses a need in the art by providing a way of selectively concentrating fluoroalkyl functionality into polymer particles with acorn morphology, thereby providing an improvement in dirt pick-up resistance of the subsequent coating.

Described herein is a polymer comprising: interpolymerized units of (i) a fluorinated terminal alkene monomer and (ii) a tertiary amine-containing fluorinated monomer comprising at least one of a vinyl amine, a substituted vinyl amine, an allyl amine, a substituted allyl amine, and combinations thereof; wherein the polymer can be amorphous or semi-crystalline with a melting point no greater than 325C. Dispersions thereof and methods of making and using the same are also described.

Described herein is a polymer comprising: interpolymerized units of (i) a fluorinated terminal alkene monomer and (ii) a tertiary amine-containing fluorinated monomer comprising at least one of a vinyl amine, a substituted vinyl amine, an allyl amine, a substituted allyl amine, and combinations thereof; wherein the polymer can be amorphous or semi-crystalline with a melting point no greater than 325C. Dispersions thereof and methods of making and using the same are also described.

A method of producing fibers, includes placing a composition that includes one or more fluoropolymers in the body of a fiber producing device and rotating the device at a speed sufficient to eject material from the fiber producing device to form fluoropolymer microfibers and/or nanofibers.

A dielectric material, to a device comprising the dielectric material and to use of the dielectric material in the fabrication of a device. One dielectric material may comprise a halogen-based elastomer mixed with a halogen based surfactant and exhibiting electro-mechanical self-healing properties and/or an increased dielectric constant compared to the halogen-based elastomer. Another dielectric material may comprise a halogen-based polymer mixed with a halogen based surfactant and exhibiting an increased dielectric constant compared to the halogen-based polymer.

The invention relates to novel linear, semi-crystalline fluoropolymers containing 0.5 to 25 mole percent of at least one vinyl ester monomer unit. At least 40 mole percent of the vinyl ester monomer units are present in the copolymer as single monomer units (not diads or triads or greater) between two fluoromonomer units. The invention also relates to a process for forming the fluoromonomers/vinyl ester copolymer. The fluoropolymer of the invention may be used in applications benefiting from a functional fluoropolymers including as a binder or coating in batteries, or for use in forming hydrophilic membranes and hollow fibers.

The invention relates to novel linear, semi-crystalline fluoropolymers containing 0.5 to 25 mole percent of at least one vinyl ester monomer unit. At least 40 mole percent of the vinyl ester monomer units are present in the copolymer as single monomer units (not diads or triads or greater) between two fluoromonomer units. The invention also relates to a process for forming the fluoromonomers/vinyl ester copolymer. The fluoropolymer of the invention may be used in applications benefiting from a functional fluoropolymers including as a binder or coating in batteries, or for use in forming hydrophilic membranes and hollow fibers.

The present invention pertains to vinylidene fluoride copolymers comprising recurring units derived from hydrophilic (meth)acrylic monomers and from perhalogenated monomers and to their use as binders for silicon negative electrodes.

The present invention pertains to vinylidene fluoride copolymers comprising recurring units derived from hydrophilic (meth)acrylic monomers and from perhalogenated monomers and to their use as binders for silicon negative electrodes.

A fluoroelastomer comprising a copolymer of fluoroolefin monomers selected from one or more of the group consisting of 2,3,3,3-tetrafluoropropene, 1,3,3,3-tetrafluoropropene and 1-chloro-3,3,3-trifluoropropene, and ethylenically unsaturated co-monomers; wherein the fluoroelastomer has a glass transition temperature (Tg) of from about 60 C. to about 53 C. A process of making the fluoroelastomer.