Patent classifications
C08F26/10
BISMUTH-TITANIUM OXIDE NANOWIRE MATERIAL USED FOR PHOTOCATALYSIS, AND PREPARATION METHOD
The present invention relates to bismuth-titanium oxide composite nanowires used for photocatalysis and a preparation method, belonging to the field of inorganic nanomaterials. The preparation of the bismuth-titanium oxide composite nanowires is: polyvinylpyrrolidone (PVP) and bismuth nitrate are added to N-N dimethylformamide (DMF), tetrabutyl titanate and acetylacetone are added after magnetic stirring has been performed for a period of time, continual stirring is performed for more than six hours, and a transparent, stable solution is obtained. Electrospinning is performed on the solution in an electrospinning generation device under certain conditions, and the obtained electrospinning precursor nano fibres are air-fired in a muffle furnace to remove organic matter. After being cooled to room temperature, the electrospinning precursor nano fibres are placed in a tube furnace to be reduced and sintered in a hydrogen atmosphere. The method is energy-saving and environmentally friendly, the conditions are easy to control, costs are low, and large-scale industrial production is easy. The obtained bismuth-titanium oxide nanowires exhibit good degradation activity on methyl orange under illumination, where the methyl orange degradation rate is reaching more than 95% in a reaction lasting for 20 minutes. The obtained bismuth-titanium oxide nanowires have wide application prospects in relation to sewage treatment.
Pharmaceutical Composition of Killed Cells with Substantially Retained Immunogenicity
The present invention relates to a lyophilized composition comprising killed cancer cells with substantially retained immunogenicity and morphology, an intracellular cryopreservative such as trehalose and an extracellular cryopreservative such as polyvinylpyrrolidone. The present invention also relates to a process for the preparation of said lyophilized composition. The lyophilized composition of the present invention can be used for cancer immunotherapy.
LAMINATE AND KIT
Provided are a laminate which includes an organic semiconductor film, a water-soluble resin layer, and a photosensitive resin layer and in which cracks are unlikely to occur; and a kit.
The laminate includes a water-soluble resin layer containing a water-soluble resin and a photosensitive resin layer containing a photosensitive resin, which are provided in this order on an organic semiconductor film. The water-soluble resin layer and the photosensitive resin layer are adjacent to each other, the water-soluble resin is at least one of polyvinylpyrrolidone having a weight-average molecular weight of 300,000 or greater or polyvinyl alcohol having a weight-average molecular weight of 15,000 or greater, and the photosensitive resin has a weight-average molecular weight of 30,000 or greater.
AZOLE DERIVATIVES FOR CORROSION MITIGATION
Anticorrosion compounds and compositions can be used in methods for preventing metal corrosion. More specifically, the method comprises contacting an anticorrosion composition to an aqueous system in contact with a metal. The anticorrosion composition comprises substituted and/or hydrogenated benzotriazoles and tolyltriazoles.
Method for Separating and Washing of Microparticles via A Stratified Coflow of Non-Newtonian and Newtonian Fluids
The present invention relates to a method for separating and washing microparticles via a stratified co-flow of non-Newtonian fluid and Newtonian fluid, wherein the Newtonian fluid as well as the non-Newtonian fluid may flow into a transfer channel formed in a fluid chip at a predetermined flow rate ratio matching with an effective diameter of the target particles contained in the non-Newtonian fluid, thereby inducing a change in positions of particle focusing points with respect to the target particles within the stratified co-flow thereof formed in the transfer channel. As a result, it is possible to more easily separate only the target particles among the microparticles contained in the non-Newtonian fluid toward the Newtonian fluid without using an additional device and human power, or transfer the target particles contained in the non-Newtonian fluid toward the Newtonian fluid for washing the same. Accordingly, since native biofluids used in the studies and clinical experiments are mostly non-Newtonian fluid, it is possible to directly separate and wash the target particles without a need of changing a solution for containing cells/particles or additional diluting the same for executing experiments. If the native biofluids as the non-Newtonian fluid lack a relaxation time, any artificial polymer could be simply added thereto in order to increase the relaxation time, thereby greatly increasing an amount of treatment per time. Further, since high working efficiency can be achieved in a wide range of flow rate, high efficient separation and washing processes may be achieved by a simple hand work of pushing and pumping an injector alone, without any accurate pumping device.
DISPERSIONS CONTAINING GRAPHENIC CARBON NANOPARTICLES AND DISPERSANT RESINS
Graphenic carbon nanoparticles that are dispersed in solvents through the use of dispersant resins are disclosed. The graphenic carbon nanoparticles may be milled prior to dispersion. The dispersant resins may comprise a polymeric dispersant resin comprising an addition polymer comprising the residue of a vinyl heterocyclic amide, an addition polymer comprising a homopolymer, a block (co)polymer, a random (co)polymer, an alternating (co)polymer, a graft (co)polymer, a brush (co)polymer, a star (co)polymer, a telechelic (co)polymer, or a combination thereof. The solvents may be aqueous, non-aqueous, inorganic and/or organic solvents. The dispersions are highly stable and may contain relatively high loadings of the graphenic carbon nanoparticles.
DISPERSIONS CONTAINING GRAPHENIC CARBON NANOPARTICLES AND DISPERSANT RESINS
Graphenic carbon nanoparticles that are dispersed in solvents through the use of dispersant resins are disclosed. The graphenic carbon nanoparticles may be milled prior to dispersion. The dispersant resins may comprise a polymeric dispersant resin comprising an addition polymer comprising the residue of a vinyl heterocyclic amide, an addition polymer comprising a homopolymer, a block (co)polymer, a random (co)polymer, an alternating (co)polymer, a graft (co)polymer, a brush (co)polymer, a star (co)polymer, a telechelic (co)polymer, or a combination thereof. The solvents may be aqueous, non-aqueous, inorganic and/or organic solvents. The dispersions are highly stable and may contain relatively high loadings of the graphenic carbon nanoparticles.
Multi-armed polymers comprising free-radical-polymerizable monomers and compositions, systems and methods pertaining to the same
In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.
Multi-armed polymers comprising free-radical-polymerizable monomers and compositions, systems and methods pertaining to the same
In some aspects, the present disclosure pertains to multi-arm polymers that comprise a core, a plurality of polymer segments having a first end that is covalently attached to the core and a second end comprising a moiety that comprises a reactive group, wherein the polymer segments comprise one or more free-radical-polymerizable monomers. In some aspects, systems are provided that comprise a first composition comprising such a multi-arm polymer and a second composition comprising a multifunctional compound that comprises functional groups that are reactive with the reactive groups of the multi-arm polymer. In some aspects, systems are provided that comprise crosslinked reaction products of such a multi-arm polymer and such a multifunctional compound.
Hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds
Described herein are hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds that may be produced through a reaction comprising: (A) at least one first reactant represented by a structure (I), wherein X is a functionalized or unfunctionalized C.sub.1-C.sub.5 alkylene group optionally having one or more heteroatoms, and each R.sub.1, R.sub.2, and R.sub.3 is independently selected from the group consisting of hydrogen and functionalized and unfunctionalized alkyl groups optionally having one or more heteroatoms, and (B) at least one second reactant having at least one hydroxyl moiety or thiol moiety. The hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds may comprise a polymerizable moiety, in which case they may be left as-is or used to create homopolymers or non-homopolymers, or they may not comprise a polymerizable moiety. A wide variety of formulations may be created using the hemi-aminal ethers and thioethers of N-alkenyl cyclic compounds, including personal care, oilfield, and construction formulations. ##STR00001##