Patent classifications
C08F110/06
Arylaminosilane compound, propylene polymerization catalyst and preparation thereof
The present disclosure discloses an arylaminosilane compound, a propylene polymerization catalyst and preparation thereof. The arylaminosilane compound has a structure of ##STR00001##
wherein R.sub.1 is a C.sub.1-C.sub.8 alkyl group or a C.sub.1-C.sub.8 silanyl group; R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 are each independently H or a C.sub.1-C.sub.12 alkyl group; R.sub.7, R.sub.8 and R.sub.9 are each independently a C.sub.1-C.sub.8 alkyl group or a C.sub.1-C.sub.8 alkoxy group. When the arylaminosilane compound is used as an external electron donor of a propylene polymerization catalyst in propylene polymerization reaction, the catalyst has good hydrogen response.
METALLOCENE SUPPORTED CATALYST AND METHOD FOR PREPARING OLEFINE POLYMER USING THE SAME
Provided are a metallocene supported catalyst capable of greatly reducing generation of fine powder during preparation of olefin polymers while exhibiting excellent catalyst activity, and a method of preparing olefin polymers using the same.
METALLOCENE SUPPORTED CATALYST AND METHOD FOR PREPARING OLEFINE POLYMER USING THE SAME
Provided are a metallocene supported catalyst capable of greatly reducing generation of fine powder during preparation of olefin polymers while exhibiting excellent catalyst activity, and a method of preparing olefin polymers using the same.
ANTISTATIC AGENT FOR THERMOPLASTIC RESIN
An antistatic agent for thermoplastic resins (Z) containing a block polymer (A) having a block of a hydrophobic polymer (a) and a block of a hydrophilic polymer (b) as structure units, and a C6-C18 branched alkylbenzenesulfonate (S); an antistatic resin composition (Y) containing the antistatic agent (Z) and a thermoplastic resin (E); and a molded article of the antistatic resin composition (Y).
ANTISTATIC AGENT FOR THERMOPLASTIC RESIN
An antistatic agent for thermoplastic resins (Z) containing a block polymer (A) having a block of a hydrophobic polymer (a) and a block of a hydrophilic polymer (b) as structure units, and a C6-C18 branched alkylbenzenesulfonate (S); an antistatic resin composition (Y) containing the antistatic agent (Z) and a thermoplastic resin (E); and a molded article of the antistatic resin composition (Y).
HETEROPHASIC PROPYLENE ETHYLENE COPOLYMER COMPOSITION WITH DESIRABLE BALANCE OF MECHANICAL PROPERTIES
A heterophasic propylene ethylene copolymer composition having an MFR.sub.2 in the range from 1.0 to 55.0 g/10 min and a melting temperature in the range from 155 to 162° C., comprising: i) from 60 to 88 wt.-% of a xylene cold insoluble fraction (XCI) having an intrinsic viscosity iV(XCI) in the range from 1.40 to 2.50 dl/g, an isotactic pentad concentration [mmmm] of more than 97.0% and a content of 2,1-regiodefects in the range from 0.1 to 0.4 mol %, ii) from 12 to 40 wt.-% of a xylene cold soluble fraction (XCS) having an intrinsic viscosity iV(XCS) in the range from 1.80 to 3.20 dl/g and an ethylene content C2(XCS) in the range from 25 to 80 wt.-%, wherein the ratio of the intrinsic viscosities of the two fractions, iV(XCS)/iV(XCI), is in the range from 1.0 to 2.0.
HETEROPHASIC PROPYLENE ETHYLENE COPOLYMER COMPOSITION WITH DESIRABLE BALANCE OF MECHANICAL PROPERTIES
A heterophasic propylene ethylene copolymer composition having an MFR.sub.2 in the range from 1.0 to 55.0 g/10 min and a melting temperature in the range from 155 to 162° C., comprising: i) from 60 to 88 wt.-% of a xylene cold insoluble fraction (XCI) having an intrinsic viscosity iV(XCI) in the range from 1.40 to 2.50 dl/g, an isotactic pentad concentration [mmmm] of more than 97.0% and a content of 2,1-regiodefects in the range from 0.1 to 0.4 mol %, ii) from 12 to 40 wt.-% of a xylene cold soluble fraction (XCS) having an intrinsic viscosity iV(XCS) in the range from 1.80 to 3.20 dl/g and an ethylene content C2(XCS) in the range from 25 to 80 wt.-%, wherein the ratio of the intrinsic viscosities of the two fractions, iV(XCS)/iV(XCI), is in the range from 1.0 to 2.0.
POLYPROPYLENE COMPOSITION WITH IMPROVED PROCESSABILITY AND IMPACT STRENGTH
The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.
POLYPROPYLENE COMPOSITION WITH IMPROVED PROCESSABILITY AND IMPACT STRENGTH
The present invention relates to heterophasic polypropylene compositions comprising a propylene homo- or copolymer forming a crystalline fraction as a matrix and an amorphous propylene ethylene elastomer as a soluble fraction dispersed in said matrix. The heterophasic polypropylene compositions further comprise an elastomeric ethylene/alpha-olefin random copolymer. The heterophasic polypropylene compositions have a well-balanced relation between stiffness and impact strength, low volatile and semi-volatile emissions and good processability.
METALLOCENE COMPOUND, AND PREPARATION METHOD THEREFOR AND APPLICATION THEREOF
A metallocene compound having a structure shown by formula (I). A functional group connected to a bridging atom of the metallocene compound is an amine-substituted group and/or a metallocene-substituted group and/or a substituted metallocene group. A metallocene catalyst containing the metallocene compound has high catalytic activity, and can synthesize metallocene polypropylene having high isotacticity.
R.sup.IR.sup.IIZ(Cp.sup.III).sub.n(E).sub.2-nML.sup.IVL.sup.V (I)