Patent classifications
C08F116/14
METHOD FOR PRODUCING FLUOROPOLYMER, METHOD FOR PRODUCING POLYTETRAFLUOROETHYLENE, METHOD FOR PRODUCING PERFLUOROELASTOMER, AND COMPOSITION
The present disclosure provides a method for producing a fluoropolymer, the method includes polymerizing a fluoromonomer in an aqueous medium in the presence of a polymer (1) to obtain a fluoropolymer, wherein the polymer (1) is a polymer of a monomer (1) represented by the general formula (1) below, in which the content of a dimer and a trimer of the monomer (1) is 1.0% by mass or less based on the polymer (1):
CF.sub.2═CF—R—CZ.sup.1Z.sup.1-A.sup.0 (1)
wherein R is a linking group; Z.sup.1 and Z.sup.2 are each independently F or CF.sub.3; and A.sup.0 is an anionic group.
POLYTETRAFLUOROETHYLENE PRODUCTION METHOD
Provided is a method for producing polytetrafluoroethylene, which includes polymerizing tetrafluoroethylene in an aqueous medium in the presence of a nucleating agent and a polymer (I) containing a polymerization unit (I) based on a monomer represented by the general formula (I) to obtain polytetrafluoroethylene:
CX.sup.1X.sup.3═CX.sup.2R(—CZ.sup.1Z.sup.2-A.sup.0).sub.m (I)
wherein X.sup.1 and X.sup.3 are each independently F, Cl, H, or CF.sub.3; X.sup.2 is H, F, an alkyl group, or a fluorine-containing alkyl group; A.sup.0 is an anionic group; R is a linking group; Z.sup.1 and Z.sup.2 are each independently H, F, an alkyl group, or a fluorine-containing alkyl group; and m is an integer of 1 or more.
Method for producing vinyl ether polymer containing oxyethylene chain by radical polymerization
A method for producing a vinyl ether polymer containing an oxyethylene chain is provided, including a the step of polymerizing vinyl ether represented by formula (1) in the presence of water as a polymerization solvent, a basic compound as an additive, and an organic azo-based compound as a radical polymerization initiator, and in pH of 5 or more, and the amount of the basic compound used is 0.01 to 0.5 mol % based on an amount of the vinyl ether. Formula (1) is ##STR00001##
wherein R1 represents an alkyl group having 1 to 3 carbons, and n represents an integer from 1 to 10.
VINYLETHER-BASED POLYMER AS DIELECTRIC
The present invention provides polymers comprising units of formula (1) as well as compositions comprising the polymers, processes for the preparation of the polymers, electronic devices comprising the polymers, and processes for the preparation of the electronic devices, and the use of the polymers as dielectric materials.
##STR00001##
DRAW SOLUTE, DRAW SOLUTION, AND FORWARD-OSMOSIS WATER TREATMENT METHOD
A draw solute may have a low viscosity, and can be circulated during a forward-osmosis water treatment, and has a sedimentation under heating and a higher osmotic pressure than that of seawater, when used as a draw solution. A draw solute may include at least one of vinyl ether polymer containing an oxyethylene chain in a side chain and having a number average molecular weight (Mn) of 13,000 or less.
CHLORIDE-FREE CATIONIC POLYMERS USING ACETATE ANIONS
A composition contains ethylenically unsaturated quaternary ammonium cations with acetate counterions, where each of the ethylenically unsaturated ammonium cations contain only one non-aromatic carbon-carbon double bond and the composition contains less than one mole-percent chloride relative to quaternary ammonium cations can be polymerized to form a cationic polymer acetate.
CHLORIDE-FREE CATIONIC POLYMERS USING ACETATE ANIONS
A composition contains ethylenically unsaturated quaternary ammonium cations with acetate counterions, where each of the ethylenically unsaturated ammonium cations contain only one non-aromatic carbon-carbon double bond and the composition contains less than one mole-percent chloride relative to quaternary ammonium cations can be polymerized to form a cationic polymer acetate.
PROTEIN ADSORPTION PREVENTING AGENT, PROTEIN ADSORPTION PREVENTING FILM, AND MEDICAL TOOL USING SAME
To provide a protein adsorption preventing agent having an excellent film forming property and excellent water solubility, capable of easily coating various substrates, and having an excellent protein adsorption preventing property, and also to provide a protein adsorption preventing film using the protein adsorption preventing agent and a medical tool including the protein adsorption preventing film. A protein adsorption preventing agent containing an aqueous solvent and a polymer having at least a structural unit (A) represented by the following formula (1) (wherein R.sup.1 represents a methyl group or an ethyl group and n represents an integer of 1 to 10), and further containing a hydrophobic group, a protein adsorption preventing film using the protein adsorption preventing agent, and a medical tool including the protein adsorption preventing film.
##STR00001##
PROTEIN ADSORPTION PREVENTING AGENT, PROTEIN ADSORPTION PREVENTING FILM, AND MEDICAL TOOL USING SAME
To provide a protein adsorption preventing agent having an excellent film forming property and excellent water solubility, capable of easily coating various substrates, and having an excellent protein adsorption preventing property, and also to provide a protein adsorption preventing film using the protein adsorption preventing agent and a medical tool including the protein adsorption preventing film. A protein adsorption preventing agent containing an aqueous solvent and a polymer having at least a structural unit (A) represented by the following formula (1) (wherein R.sup.1 represents a methyl group or an ethyl group and n represents an integer of 1 to 10), and further containing a hydrophobic group, a protein adsorption preventing film using the protein adsorption preventing agent, and a medical tool including the protein adsorption preventing film.
##STR00001##
Polymerizable Monomer, Polymer Compound, Resist Composition, And Patterning Process
The present invention is a polymerizable monomer represented by the following general formula (1),
##STR00001##
wherein R.sup.A represents a hydrogen atom, a fluorine atom, a methyl group, or a trifluoromethyl group; Z.sup.L is a single bond or (backbone) C(O)O; R.sup.ALU is an acid-labile group formed with an adjacent oxygen atom; X.sup.L represents an oxygen atom or a sulfur atom; R.sup.aa represents a hydrogen atom or a fluorine atom; R.sup.1a independently represents a hydrocarbyl group having 1 to 20 carbon atoms; n1 is an integer of 0 to 2; n2 is an integer of 1 or 2; n3 is an integer of 1 or 2; and n4 is an integer of 0 to 4.