C08F122/1006

Photoinitiators for light-curable compositions

Compounds of formula (I) are photoinitiators or photosensitizers in a photopolymerizable composition: ##STR00001## R.sub.1 represents a monovalent, linear, branched or cyclic, aliphatic hydrocarbon group having 1 to 20 carbon atoms, optionally substituted with substituent(s) selected from —Cl, —Br, —OH, ═O, —NH—CO— OR.sub.2, —NH—CO—R.sub.2 or free-radically or ionically polymerizable groups. Each R.sub.2 is independently —H or C.sub.1-6 alkyl; n is ≥1. If n=1, Z and Y are absent and X represents —OR.sub.3; if n is >1, Z represents —OR.sub.4—, Y represents —ORs— and X represents —H or —OH. R.sub.3 represents —H or R.sub.1; and R.sub.4 and R.sub.5 each independently represent a bivalent hydrocarbon group. The polymerizable moieties as optional substituents of R.sub.1 are polymerizable double or triple bonds, lactam, lactone and epoxide moieties, which are subjectable to ring-opening polymerization; and two of R.sub.1 to R.sub.5 may be linked to one another to form a ring or a dimer.

Photobase Generator, Compound, Photoreactive Composition, and Reaction Product
20220298268 · 2022-09-22 ·

A photobase generator includes a compound including a first skeleton represented by the following formula (a), and a second skeleton including a nitrogen atom bonding to a bonding position of the first skeleton to form an amide group, wherein the compound generates a base, in which a hydrogen atom is bonding with the nitrogen atom of the second skeleton, by light irradiation, and the pKa of a conjugate acid of the base in water is 12 or more. In formula (a), G is a divalent aromatic group, and * represents the bonding position with the nitrogen atom.

##STR00001##

CURABLE (METH)ACRYLATE COMPOSITIONS
20220251278 · 2022-08-11 ·

A two-part curable (adhesive) composition comprising a Part A and a Part B: Part A comprising: (i) a curable (meth)acrylate component; (ii) a peroxide; and (iii) a phenolic lipid; and Part B comprising: (i) a curable (meth)acrylate component; and (ii) a transition metal component. These compositions are tack free, demonstrate good cure through volume and desirable bond strengths on both active and passive substrates. The two-part curable (adhesive) composition can cure across relatively large bond gaps and are non-volatile.

QUANTUM DOT, CURABLE COMPOSITION COMPRISING THE SAME, CURED LAYER USING THE COMPOSITION, AND COLOR FILTER INCLUDING THE CURED LAYER

Disclosed are a surface-modified quantum dot, a curable composition including the quantum dot, a cured layer, and a color filter.

PREPARATION METHOD OF SUPER ABSORBENT POLYMER COMPOSITION
20220212166 · 2022-07-07 · ·

The present disclosure relates to a preparation method of a super absorbent polymer composition. More specifically, it relates to a preparation method of a super absorbent polymer composition capable of pulverizing the hydrogel polymer to a normal particle size without agglomeration between particles by adding an additive having a specific structure, reducing manufacturing cost by simultaneously performing a drying process and a surface cross-linking process, and significantly reducing the amount of fine powder generated during the process.

CURABLE RESIN COMPOSITION, CURED PRODUCT, DIFFRACTIVE OPTICAL ELEMENT, AND MULTILAYER DIFFRACTIVE OPTICAL ELEMENT

Provide are a curable resin composition containing ITO particles, in which a cured product obtained from the curable resin composition can exhibit high transmittance over a visible light to shortwave infrared wavelength region while maintaining a wavelength dependence of a desired refractive index; a cured product formed of the curable resin composition; and a diffractive optical element and a multilayer diffractive optical element.

A curable resin composition includes particles which have a core-shell structure, in which a core portion is composed of indium tin oxide, a monofunctional or higher (meth)acrylate compound, and a dispersant; a cured product formed of the curable resin composition; and a diffractive optical element and a multilayer diffractive optical element.

DUAL-MEDIATED POLYMERIZABLE COMPOSITE FOR ADDITIVE MANUFACTURING

A formulation for a photopolymer composite material for a 3D printing system includes an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator. In the formulation the acrylate monomer or the acrylate oligomer may be between about 10.0-30.0 w % of the formulation. The thermal initiator may be between about 0.001-0.05 w %, the co-initiator may be between about 0.001-0.05 w %, and the UV initiator may be between about 0.001-0.2 w % of the formulation. A method of generating a formulation of a photopolymer composite material for use in a 3D printing system includes using an acrylate monomer or an acrylate oligomer, an inorganic hydrate, a reinforcing filler, a co-initiator, a thermal initiator, and an ultraviolet (UV) initiator.

Method For Bonding Three-Dimensional Articles Made By Additive Manufacturing

A method of bonding a substrate comprising a three-dimensional printed article to another substrate, by activating the three-dimensional printed article is described, thereby facilitating bonding of the two substrates using redox curable adhesives, for example anaerobically curable adhesives.

Hierarchical printed product and composition and method for making the same

Disclosed herein are embodiments of a printable composition that can be used to make printed products of a chosen material chemistry that have different levels of porosity within the printed product's structure Also disclosed herein are embodiments of a printed product that has multiple levels of porosity throughout its structure, which can include a macroscale level of porosity, a microscale level of porosity, a nanoscale level of porosity and any combination thereof. These printed products can be made using a 3-D printer and can be made from a single printable composition without the need to add different structural components during the production process. Also disclosed herein are embodiments of a method for making and using a printed product.

Photopolymerization sensitizer composition and photopolymerizable composition comprising the same

To provide a photopolymerizable composition which can be quickly cured by light of from 300 nm to 450 nm, and a cured product of which is less colored. A photopolymerization sensitizer composition containing a compound represented by the following formula (1) and a compound, of which the maximum value of an absorption coefficient in a wavelength region ranging from at least 400 nm to at most 500 nm is higher than the maximum value of an absorption coefficient in a wavelength region ranging from at least 400 nm to at most 500 nm of said compound; and a photopolymerizable composition containing the photopolymerization sensitizer composition. In the formula (1), R.sup.1 is a C.sub.1-20 alkyl group, a C.sub.6-20 aryl group, a C.sub.1-20 alkoxy group or a C.sub.6-20 aryloxy group, and each of X.sup.1 and Y.sup.1 which may be the same or different, is a hydrogen atom or a C.sub.1-8 alkyl group ##STR00001##