Provided are a laminate which includes an organic semiconductor film, a water-soluble resin layer, and a photosensitive resin layer and in which cracks are unlikely to occur; and a kit. The laminate includes a water-soluble resin layer containing a water-soluble resin and a photosensitive resin layer containing a photosensitive resin, which are provided in this order on an organic semiconductor film. The water-soluble resin layer and the photosensitive resin layer are adjacent to each other, the water-soluble resin is at least one of polyvinylpyrrolidone having a weight-average molecular weight of 300,000 or greater or polyvinyl alcohol having a weight-average molecular weight of 15,000 or greater, and the photosensitive resin has a weight-average molecular weight of 30,000 or greater.

A conductive composition comprising a conductive polymer (A), a water-soluble polymer (B), and a solvent (C1), wherein: the water-soluble polymer (B) comprises a water-soluble polymer (B11) represented by formula (11), and an amount of a water-soluble polymer (B2) represented by formula (2) as the water-soluble polymer (B) is 0.15% by mass or less, based on a total mass of the conductive composition:

##STR00001##

wherein R.sup.1 denotes a linear or branched alkyl group with 6 to 20 carbon atoms, each of R.sup.4 and R.sup.5 independently denotes a methyl or ethyl group, R.sup.6 denotes a hydrophilic group, R.sup.7 denotes a hydrogen atom or a methyl group, Y.sup.1 denotes a single bond, S, S(O), C(O)O or O, Z denotes a cyano group or a hydroxy group, each of p1 and q denotes an average number of repetitions, and is a number of from 1 to 50, and m denotes a number of from 1 to 5.

Chiral polyvinylpyrrolidinone (CSPVP), complexes of CSPVP with a core species, such as a metallic nanocluster catalyst, and enantioselective oxidation reactions utilizing such complexes are disclosed. The CSPVP complexes can be used in asymmetric oxidation of diols, enantioselective oxidation of alkenes, and carbon-carbon bond forming reactions, for example. The CSPVP can also be complexed with biomolecules such as proteins, DNA, and RNA, and used as nanocarriers for siRNA or dsRNA delivery.

The present invention discloses a method for improving the blood compatibility of a material surface by using a controllable grafting technique. The method involves placing a monomer NVP, an RAFT reagent and a solvent acetonitrile in a container, adding an initiator AIBN, mixing the same uniformly, removing oxygen with liquid nitrogen, making the same react in an oil bath; after polymerization, adding liquid nitrogen to quench and stop the reaction, thus obtaining PVP-COOH; mixing the PVP-COOH with DCC and NHS; adding dry dichloromethane to the mixture in a nitrogen atmosphere, adding mercaptoethylamine, and making the same react in darkness at room temperature; obtaining a crude sample; dissolving the crude sample in water, and performing dialysis with deoxygenated water in darkness, and then obtaining HS-PVP by freeze-drying. An AuS bond chemisorption method is used to controllably graft an anti-protein high-molecular polymer onto an Au surface.

The present invention discloses a method for improving the blood compatibility of a material surface by using a controllable grafting technique. The method involves placing a monomer NVP, an RAFT reagent and a solvent acetonitrile in a container, adding an initiator AIBN, mixing the same uniformly, removing oxygen with liquid nitrogen, making the same react in an oil bath; after polymerization, adding liquid nitrogen to quench and stop the reaction, thus obtaining PVP-COOH; mixing the PVP-COOH with DCC and NHS; adding dry dichloromethane to the mixture in a nitrogen atmosphere, adding mercaptoethylamine, and making the same react in darkness at room temperature; obtaining a crude sample; dissolving the crude sample in water, and performing dialysis with deoxygenated water in darkness, and then obtaining HS-PVP by freeze-drying. An AuS bond chemisorption method is used to controllably graft an anti-protein high-molecular polymer onto an Au surface.

An organic tellurium compound is disclosed having a versatility that, when used as a living radical polymerization initiator, it is applicable to polymerization of a vinyl monomer in an aqueous vehicle without using any surfactant or dispersant. The organic tellurium compound is represented by a general formula (1),

##STR00001##

where R.sup.1 and R.sup.2 each independently represent a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, A represents an alkali metal atom or an alkaline earth metal atom, x=1 when A is monovalent, x= when A is divalent, and R.sup.3 is represented by a general formula (2),

##STR00002##

where in the general formula (2) R.sup.4 represents a hydrogen atom or an alkyl group having 1 to 8 carbon atoms, R.sup.5 and R.sup.6 each independently represent an alkylene group having 2 to 8 carbon atoms, and a represents an integer from 0 to 10.

Nanoparticles having a plurality of PVP chains covalently bonded to a surface of the nanoparticle are provided, along with their methods of formation and the RAFT agents for the polymerization of the PVP chains. RAFT agents are generally provided, along with their methods of formation and use. Methods are also generally provided for grafting a PVP polymer onto a nanoparticle. In one embodiment, the method includes polymerizing a plurality of monomers in the presence of a RAFT agent to form a polymeric chain covalently bonded to the nanoparticle.

Nanoparticles having a plurality of PVP chains covalently bonded to a surface of the nanoparticle are provided, along with their methods of formation and the RAFT agents for the polymerization of the PVP chains. RAFT agents are generally provided, along with their methods of formation and use. Methods are also generally provided for grafting a PVP polymer onto a nanoparticle. In one embodiment, the method includes polymerizing a plurality of monomers in the presence of a RAFT agent to form a polymeric chain covalently bonded to the nanoparticle.

The disclosure belongs to the technical field of synthetic adhesives, and discloses a bionic wet surface adhesion promoter and the preparation thereof, and a room temperature curable silicone sealant composition and the preparation thereof. A method for preparing a bionic wet surface adhesion promoter includes: reacting polyvinylpyrrolidone with 2-chloro-3,4-dihydroxyacetophenon; purifying the product obtained in the reaction step using n-hexane; drying the product obtained in the purification step using a vacuum drying process; and grinding the product obtained in the drying step into powder using a ball milling process; wherein the mass ratio of polyvinylpyrrolidone to 2-chloro-3,4-dihydroxyacetophenon is (0.81.2):1. The room temperature curable silicone sealant composition according to the disclosure includes the bionic wet surface adhesion promoter prepared by the above method, has good adhesion performance on both dry and wet surfaces and is well-suited for use in the construction field, especially for use in humid environments.

The disclosure belongs to the technical field of synthetic adhesives, and discloses a bionic wet surface adhesion promoter and the preparation thereof, and a room temperature curable silicone sealant composition and the preparation thereof. A method for preparing a bionic wet surface adhesion promoter includes: reacting polyvinylpyrrolidone with 2-chloro-3,4-dihydroxyacetophenon; purifying the product obtained in the reaction step using n-hexane; drying the product obtained in the purification step using a vacuum drying process; and grinding the product obtained in the drying step into powder using a ball milling process; wherein the mass ratio of polyvinylpyrrolidone to 2-chloro-3,4-dihydroxyacetophenon is (0.81.2):1. The room temperature curable silicone sealant composition according to the disclosure includes the bionic wet surface adhesion promoter prepared by the above method, has good adhesion performance on both dry and wet surfaces and is well-suited for use in the construction field, especially for use in humid environments.