Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

Urea (multi)-(meth)acrylate (multi)-silane precursor compounds, synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds, either neat or in a solvent, and optionally with a catalyst, such as a tin compound, to accelerate the reaction. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-(meth)acrylate (multi)-silane precursor compound synthesized by reaction of (meth)acrylated materials having isocyanate functionality with aminosilane compounds. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making the urea (multi)-(meth)acrylate (multi)-silanes and their use in composite films and electronic devices are described.

The silicone emulsion composition for forming a rubber coating film according to the present invention, including

(A) an organopolysiloxane having at least two hydroxyl groups bonded to silicon atoms at terminal ends of the molecule in each molecule thereof,

(B) an aminoalkyltrialkoxysilane represented by formula (1)

##STR00001##

(where R.sup.1 through R.sup.3 represent H or a univalent hydrocarbon group, R.sup.4 and R.sup.5 represent divalent hydrocarbon groups, R.sup.6 represents a univalent hydrocarbon group, and n is an integer 0 to 6),

(C) a vinyltrialkoxysilane represented by formula (2):

CH.sub.2CHSi(OR.sup.7).sub.3

(where R.sup.7 represents a univalent hydrocarbon group),

(D) a surfactant, and

(E) water

and not containing an organic tin compound, is free of problems with storage stability or byproducts, and a rubber coating film can be formed thereby in a short time without the use of an organic tin compound.

The silicone emulsion composition for forming a rubber coating film according to the present invention, including

(A) an organopolysiloxane having at least two hydroxyl groups bonded to silicon atoms at terminal ends of the molecule in each molecule thereof,

(B) an aminoalkyltrialkoxysilane represented by formula (1)

##STR00001##

(where R.sup.1 through R.sup.3 represent H or a univalent hydrocarbon group, R.sup.4 and R.sup.5 represent divalent hydrocarbon groups, R.sup.6 represents a univalent hydrocarbon group, and n is an integer 0 to 6),

(C) a vinyltrialkoxysilane represented by formula (2):

CH.sub.2CHSi(OR.sup.7).sub.3

(where R.sup.7 represents a univalent hydrocarbon group),

(D) a surfactant, and

(E) water

and not containing an organic tin compound, is free of problems with storage stability or byproducts, and a rubber coating film can be formed thereby in a short time without the use of an organic tin compound.

Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula R.sub.ANHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.S].sub.n, or R.sub.SNHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.A].sub.n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.

Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula R.sub.ANHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.S].sub.n, or R.sub.SNHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.A].sub.n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.

Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula R.sub.ANHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.S].sub.n, or R.sub.SNHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.A].sub.n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.

Compositions of matter described as urea (multi)-urethane (meth)acrylate-silanes having the general formula R.sub.ANHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.s].sub.n, or R.sub.SNHC(O)N(R.sup.4)R.sup.11[OC(O)NHR.sub.A].sub.n. Also described are articles including a substrate, a base (co)polymer layer on a major surface of the substrate, an oxide layer on the base (co)polymer layer; and a protective (co)polymer layer on the oxide layer, the protective (co)polymer layer including the reaction product of at least one urea (multi)-urethane (meth)acrylate-silane precursor compound. The substrate may be a (co)polymer film or an electronic device such as an organic light emitting device, electrophoretic light emitting device, liquid crystal display, thin film transistor, or combination thereof. Methods of making such urea (multi)-urethane (meth)acrylate-silane precursor compounds, and their use in composite films and electronic devices are also described. Methods of using multilayer composite films as barrier films in articles selected from solid state lighting devices, display devices, and photovoltaic devices are also described.