The disclosure provides recording materials including thiophosphate derivatized monomers and polymers for use in volume Bragg gratings, including, but not limited to, volume Bragg gratings for holography applications. Several structures are disclosed for thiophosphate derivatized monomers and polymers for use in Bragg gratings applications, leading to materials with higher refractive index, low birefringence, and high transparency. The disclosed thiophosphate derivatized monomers and polymers thereof can be used in any volume Bragg gratings materials, including two-stage polymer materials where a matrix is cured in a first step, and then the volume Bragg grating is written by way of a second curing step of a monomer.

The present invention provides a compound represented by following formula (0):

##STR00001##

The present invention provides a compound represented by following formula (0):

##STR00001##

A compound of formula (I)

##STR00001##

wherein R.sup.1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R.sup.2, R.sup.3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

A compound of formula (I)

##STR00001##

wherein R.sup.1 is hydrogen or an organic radical of 1 to 100 carbon atoms, R.sup.2, R.sup.3 are independently hydrogen or an organic radical of 1 to 100 carbons, Z is a single bond or a divalent organic group of 1 to 100 carbons, A is an (n+m)-valent organic group of 1 to 1 000 000 carbons, X is a single bond or a divalent organic group of 1 to 40 carbons, n is an integer from 1 to 1000, m is 0, 1, or 2, the sum of n+m being an integer from 2 to 1002. Such compounds are obtainable from specific 4-oxy-but-2-yn-1-ol derivatives, or used as intermediate(s), crosslinker(s), or monomer(s) in polymerization or oligomerization reactions, or for two-component compositions having such compound(s) and multifunctional hardener(s). Such compound(s) may be used to prepare polyunsaturated compounds, by reaction with an (oligo/poly)-functional nucleophile, or polymers.

Vanillin and vanillyl alcohol were modified into methacrylated derivatives. The structures of vanillin-based monomers were characterized by NMR and FTIR. Renewable polymers were prepared from these vanillin-based monomers. The effects of structure and functionality of the vanillin-based monomers on the thermo-mechanical properties of the resulting polymers were investigated and discussed. Polymers from methacrylated vanillyl alcohol (MVA) demonstrated greater storage moduli, higher glass transition temperatures, and thermal resistance than those from methacrylated vanillin (MV) because of the different functionalities of their monomers.

Vanillin and vanillyl alcohol were modified into methacrylated derivatives. The structures of vanillin-based monomers were characterized by NMR and FTIR. Renewable polymers were prepared from these vanillin-based monomers. The effects of structure and functionality of the vanillin-based monomers on the thermo-mechanical properties of the resulting polymers were investigated and discussed. Polymers from methacrylated vanillyl alcohol (MVA) demonstrated greater storage moduli, higher glass transition temperatures, and thermal resistance than those from methacrylated vanillin (MV) because of the different functionalities of their monomers.

Embodiments in accordance with the present disclosure include methods, polymers, and complexes. For example, a method embodiments includes providing a solution including a disassembled supramolecular polymer and a bond disrupting agent, adding an antisolvent to the solution to precipitate the supramolecular polymer, and isolating the precipitated supramolecular polymer from the bond disrupting agent. The isolated supramolecular polymer is configured to selectively disperse single-walled carbon nanotubes (SWNTs) of a particular electrical type from a SWNT mixture including SWNTS of at least two electrical types.

Embodiments in accordance with the present disclosure include methods, polymers, and complexes. For example, a method embodiments includes providing a solution including a disassembled supramolecular polymer and a bond disrupting agent, adding an antisolvent to the solution to precipitate the supramolecular polymer, and isolating the precipitated supramolecular polymer from the bond disrupting agent. The isolated supramolecular polymer is configured to selectively disperse single-walled carbon nanotubes (SWNTs) of a particular electrical type from a SWNT mixture including SWNTS of at least two electrical types.

The present disclosure is directed to resins and to polymers, copolymers, and blends formed therefrom.