A heterophasic copolymer composition obtained by a process comprising polymerising in multiple steps and multiple polymerisation reactors propylene monomer and a comonomer selected from ethylene, alpha-olefins having 4 to 10 carbon atoms and their mixtures, in the presence of an olefin polymerisation catalyst comprising a solid catalyst component and a co-catalyst, wherein the solid catalyst component comprises titanium, magnesium, halogen and an internal donor of the formula (I):

##STR00001##

wherein R.sub.1 and R.sub.2 are the same or different being a linear or branched C.sub.1-C.sub.12-alkyl group and R is hydrogen or a linear, branched or cyclic C.sub.1 to C.sub.12-alkyl.

A heterophasic copolymer composition obtained by a process comprising polymerising in multiple steps and multiple polymerisation reactors propylene monomer and a comonomer selected from ethylene, alpha-olefins having 4 to 10 carbon atoms and their mixtures, in the presence of an olefin polymerisation catalyst comprising a solid catalyst component and a co-catalyst, wherein the solid catalyst component comprises titanium, magnesium, halogen and an internal donor of the formula (I):

##STR00001##

wherein R.sub.1 and R.sub.2 are the same or different being a linear or branched C.sub.1-C.sub.12-alkyl group and R is hydrogen or a linear, branched or cyclic C.sub.1 to C.sub.12-alkyl.

Polypropylenes and impact copolymers with low organic volatiles. The impact copolymers comprising a polypropylene and within a range from 5 wt% to 40 wt% of an ethylene-propylene copolymer or rubber, by weight of the impact copolymer; wherein the polypropylene has a melt flow rate within a range from 100 g/10 min to 400 g/10 min, and the impact copolymer has a melt flow rate within a range from 15 g/10 min to 150 g/10 min; and wherein there are less than 1000 .Math.g of oligomer per gram of impact copolymer. The polymers may be made by combining olefins with the reaction product of a solid magnesium compound and a halogen-containing titanium compound with at least one phthalic acid ester compound and at least one diether compound as internal electron donors.

Polypropylenes and impact copolymers with low organic volatiles. The impact copolymers comprising a polypropylene and within a range from 5 wt% to 40 wt% of an ethylene-propylene copolymer or rubber, by weight of the impact copolymer; wherein the polypropylene has a melt flow rate within a range from 100 g/10 min to 400 g/10 min, and the impact copolymer has a melt flow rate within a range from 15 g/10 min to 150 g/10 min; and wherein there are less than 1000 .Math.g of oligomer per gram of impact copolymer. The polymers may be made by combining olefins with the reaction product of a solid magnesium compound and a halogen-containing titanium compound with at least one phthalic acid ester compound and at least one diether compound as internal electron donors.

Polypropylenes and impact copolymers with low organic volatiles. The impact copolymers comprising a polypropylene and within a range from 5 wt% to 40 wt% of an ethylene-propylene copolymer or rubber, by weight of the impact copolymer; wherein the polypropylene has a melt flow rate within a range from 100 g/10 min to 400 g/10 min, and the impact copolymer has a melt flow rate within a range from 15 g/10 min to 150 g/10 min; and wherein there are less than 1000 .Math.g of oligomer per gram of impact copolymer. The polymers may be made by combining olefins with the reaction product of a solid magnesium compound and a halogen-containing titanium compound with at least one phthalic acid ester compound and at least one diether compound as internal electron donors.

A heterophasic polypropylene copolymer having an MFR2 of 0.05 to 20 g/10 min (ISO 1133 at 230° C. with a loading of 2.16 kg) and a melting point (Tm) of 156 to 164° C. (measured by DSC according to ISO 11357) wherein the heterophasic polypropylene copolymer comprises at least the following components: (A) 55.0 to 95.0 wt % of a crystalline fraction (CF) having a comonomer content of 0 to 3.0 wt %; and (B) 5.0 to 45.0 wt % of a soluble fraction (SF) having a comonomer content of 12 to 45 wt %; wherein the intrinsic viscosity (IV) (in decalin at 135° C.) of the soluble fraction (SF) is 2.5 to 11 dl/g, and wherein the amount of crystalline fraction (CF) and the amount of soluble fraction (SF) are determined in 1,2,4-trichlorobenzene at 40° C.

A heterophasic polypropylene copolymer having an MFR2 of 0.05 to 20 g/10 min (ISO 1133 at 230° C. with a loading of 2.16 kg) and a melting point (Tm) of 156 to 164° C. (measured by DSC according to ISO 11357) wherein the heterophasic polypropylene copolymer comprises at least the following components: (A) 55.0 to 95.0 wt % of a crystalline fraction (CF) having a comonomer content of 0 to 3.0 wt %; and (B) 5.0 to 45.0 wt % of a soluble fraction (SF) having a comonomer content of 12 to 45 wt %; wherein the intrinsic viscosity (IV) (in decalin at 135° C.) of the soluble fraction (SF) is 2.5 to 11 dl/g, and wherein the amount of crystalline fraction (CF) and the amount of soluble fraction (SF) are determined in 1,2,4-trichlorobenzene at 40° C.

A heterophasic polypropylene copolymer having an MFR2 of 0.05 to 20 g/10 min (ISO 1133 at 230° C. with a loading of 2.16 kg) and a melting point (Tm) of 156 to 164° C. (measured by DSC according to ISO 11357) wherein the heterophasic polypropylene copolymer comprises at least the following components: (A) 55.0 to 95.0 wt % of a crystalline fraction (CF) having a comonomer content of 0 to 3.0 wt %; and (B) 5.0 to 45.0 wt % of a soluble fraction (SF) having a comonomer content of 12 to 45 wt %; wherein the intrinsic viscosity (IV) (in decalin at 135° C.) of the soluble fraction (SF) is 2.5 to 11 dl/g, and wherein the amount of crystalline fraction (CF) and the amount of soluble fraction (SF) are determined in 1,2,4-trichlorobenzene at 40° C.

The present invention relates to an anionic polymerization initiator represented by Formula 1 below for producing a polyolefin-polystyrene block copolymer, an anionic polymerization initiator composition, and a production method therefor,

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wherein R.sub.1, and A are described herein.

The present invention relates to an anionic polymerization initiator represented by Formula 1 below for producing a polyolefin-polystyrene block copolymer, an anionic polymerization initiator composition, and a production method therefor,

##STR00001##

wherein R.sub.1, and A are described herein.