The present invention relates to a cross-linked porous membrane from hydrolysis of ester-containing side chain and a preparation method thereof. Firstly, membrane material is obtained through copolymerization of four monomers including butyl methacrylate, styrene, sodium sulfonated styrene and vinylbenzyl chloride. In membrane formation, a small amount of lithium chloride micromolecule porogen is added and cross-linked by using tetramethyl hexamethylene diamine to prepare a nanoscale dense membrane through hydrolysis under the alkaline condition. Through the characteristic of hydrolysis of a butyl ester side chain in the polymer under the alkaline condition, the space originally occupied by the butyl ester in the hydrolyzed membrane is vacated; and after hydrolysis, with the appearance of carboxylic acid ionic conduction groups, a large quantity of ester bonds is hydrolyzed, so that the patency of ion transfer channels in the membrane is enhanced. Thus, ionic conductivity of the membrane is greatly enhanced. The nanoscale porous membrane prepared by the present invention not only has good selectivity and battery performance, but also reduces the preparation cost of the membrane to a great extent, and is suitable for application in all vanadium flow batteries.

A polymer composition comprising a star-branched copolymer having a plurality of arms is disclosed. Each polymer arm has a molecular weight Mp of from 1 kg/mol to 50 kg/mol and comprises polymerized units (i) derived from a first vinyl aromatic monomer comprising a radical-reactive group, wherein from greater than 10 mol % to 100 mol % of the units (i) are unhydrogenated; and optionally, polymerized units (ii) comprising hydrogenated and unhydrogenated forms of polymerized units derived from a high Tg monomer, and hydrogenated form of polymerized units (i) or hydrogenated form of polymerized styrene units; and optionally, polymerized units (iii) comprising (a) hydrogenated form of polymerized units derived from one or more acyclic conjugated dienes, and (b) polymerized units derived from one or more of a second vinyl aromatic monomer; wherein less than 10 wt. % of units (a) are unhydrogenated.

A multi-copolymer, methods for producing the same and using thereof in wastewater treatment application are provided. The method includes pre-mixing by mass 10-30 parts by mass of alkenyl succinic anhydrides, 10-30 parts of vinylbenzyltrimethylammonium chloride, and 10-30 parts of dimethylaminoethyl methacrylate with water to form a first mixture; reacting the first mixture comprising passing thereof through inert gases to provide reflux protection, and adding by mass 10-30 parts of vinyl acetate and 10-30 parts of acrylamide to form a second mixture, followed by heating the second mixture and adding an initiator therein to initiate the reaction. The present invention is simple, at low cost, safe, non-toxic, environmentally friendly, easy to operate, with a better water purification efficiency than that of conventional macromolecule flocculants, multi-functional, good product stability, strong adsorption bridging ability, less dosage requirement for the water treatment agent, and results in a sturdy sludge cake and easily separated flocs.

A multi-copolymer, methods for producing the same and using thereof in wastewater treatment application are provided. The method includes pre-mixing by mass 10-30 parts by mass of alkenyl succinic anhydrides, 10-30 parts of vinylbenzyltrimethylammonium chloride, and 10-30 parts of dimethylaminoethyl methacrylate with water to form a first mixture; reacting the first mixture comprising passing thereof through inert gases to provide reflux protection, and adding by mass 10-30 parts of vinyl acetate and 10-30 parts of acrylamide to form a second mixture, followed by heating the second mixture and adding an initiator therein to initiate the reaction. The present invention is simple, at low cost, safe, non-toxic, environmentally friendly, easy to operate, with a better water purification efficiency than that of conventional macromolecule flocculants, multi-functional, good product stability, strong adsorption bridging ability, less dosage requirement for the water treatment agent, and results in a sturdy sludge cake and easily separated flocs.

Provided is a positive resist composition capable of improving the adhesion between a resist film formed through pre-baking and a workpiece and reducing changes in the molecular weight of the polymer in the resist film before and after pre-baking step over broader ranges of heating temperature and heating time (at lower heating temperatures) during pre-baking. The positive resist composition comprises a polymer and a solvent, wherein the polymer has a monomer unit (A) represented by the following general formula (I) and a monomer unit (B) represented by the following general formula (II), and wherein the solvent is at least one selected from the group consisting of isoamyl acetate, n-butyl formate, isobutyl formate, n-amyl formate, and isoamyl formate:

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The present invention relates to a graft copolymer having excellent thermal stability, a method of preparing the graft copolymer, a thermoplastic resin composition including the graft copolymer, and a molded part including the thermoplastic resin composition. According to the present invention, since the thermoplastic resin composition of the present invention includes the graft copolymer having excellent thermal stability, the thermoplastic resin composition and the molded part manufactured using the thermoplastic resin composition have excellent physical properties, such as impact strength, fluidity, and transparency. Furthermore, the degree of discoloration that may occur when the resin composition or the molded part is allowed to stay in an injection molding machine or stay at a high temperature for a long period of time may be reduced.

The present invention relates to a graft copolymer having excellent thermal stability, a method of preparing the graft copolymer, a thermoplastic resin composition including the graft copolymer, and a molded part including the thermoplastic resin composition. According to the present invention, since the thermoplastic resin composition of the present invention includes the graft copolymer having excellent thermal stability, the thermoplastic resin composition and the molded part manufactured using the thermoplastic resin composition have excellent physical properties, such as impact strength, fluidity, and transparency. Furthermore, the degree of discoloration that may occur when the resin composition or the molded part is allowed to stay in an injection molding machine or stay at a high temperature for a long period of time may be reduced.

The present disclosure relates to: a curable petroleum resin, which includes a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a styrene-based monomer, and is used as an additive for a reactive polyolefin-based adhesive composition so as to increase adhesiveness to a polyolefin-based substrate used for various components; a preparation method thereof; and a use thereof.

The present disclosure relates to: a curable petroleum resin, which includes a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a styrene-based monomer, and is used as an additive for a reactive polyolefin-based adhesive composition so as to increase adhesiveness to a polyolefin-based substrate used for various components; a preparation method thereof; and a use thereof.

Acid-functionalized copolymers of methyl methacrylate having relatively high glass transition temperatures and molecular weights may be employed to manufacture articles having high light transmission values, low haze, high heat resistance, and high environmental stability, which are useful as optical protection films, zero-zero optical retardation films, and compensation films as well as lighting pipes and optical imaging lenses.