Described herein is method of making branched perfluorinated compounds, specifically (CF.sub.3).sub.2CFCF(CF.sub.3)OCF(CF.sub.3)C(═O)F and (CF.sub.3).sub.2CFCF(CF.sub.3)OCF═CF.sub.2. Also disclosed herein is a fluoropolymer derived from the branched perfluorovinyl ether monomer and methods of making the fluoropolymer.

Copolymers of one or more halogenated olefins and one or more halogenated co-monomers selected from the group consisting of halogenated alkenyl ethers, halogenated alkenyl esters, and halogenated (meth)acrylates are useful in various end-use applications wherein the presence of halogen (e.g., fluorine) in the copolymer imparts one or more desirable properties, as compared to analogous copolymers not containing halogen.

Disclosed apparatus may include a membrane, a first electrode supported by the membrane, a second electrode, and optionally a controller configured to control an electrical potential applied between the first electrode and the second electrode. Example apparatus may include one or more flexible membranes that may, at least in part, define an enclosure that is at least partially filled with a dielectric fluid. A flexible membrane may include a functionalized polymer or inorganic dielectric material, such as a fluoropolymer composite including at least one electrically conductive additive and/or at least one toughener. Examples also include associated materials (e.g., polymers), methods of fabrication, methods of apparatus operation, and systems.

Disclosed apparatus may include a membrane, a first electrode supported by the membrane, a second electrode, and optionally a controller configured to control an electrical potential applied between the first electrode and the second electrode. Example apparatus may include one or more flexible membranes that may, at least in part, define an enclosure that is at least partially filled with a dielectric fluid. A flexible membrane may include a functionalized polymer or inorganic dielectric material, such as a fluoropolymer composite including at least one electrically conductive additive and/or at least one toughener. Examples also include associated materials (e.g., polymers), methods of fabrication, methods of apparatus operation, and systems.

Disclosed apparatus may include a membrane, a first electrode supported by the membrane, a second electrode, and optionally a controller configured to control an electrical potential applied between the first electrode and the second electrode. Example apparatus may include one or more flexible membranes that may, at least in part, define an enclosure that is at least partially filled with a dielectric fluid. A flexible membrane may include a functionalized polymer or inorganic dielectric material, such as a fluoropolymer composite including at least one electrically conductive additive and/or at least one toughener. Examples also include associated materials (e.g., polymers), methods of fabrication, methods of apparatus operation, and systems.

The invention pertains to novel fluorinated thermoplastic elastomers, including PCTFE-like plastomeric blocks, contributing substantially to the improvement of sealing performances upon increasing temperature of the fluorinated thermoplastic elastomers comprising the same.

The invention pertains to novel fluorinated thermoplastic elastomers, including PCTFE-like plastomeric blocks, contributing substantially to the improvement of sealing performances upon increasing temperature of the fluorinated thermoplastic elastomers comprising the same.

The invention pertains to certain fluoropolymer-based hybrid organic/inorganic composites, to polymer electrolytes obtained therefrom and to use of said polymer electrolytes in electrochemical devices.

A process for the preparation of perhaloacyl peroxides from perhaloacyl halides which is performed in the presence of a hydrofluoroether as the solvent.

A process for the preparation of perhaloacyl peroxides from perhaloacyl halides which is performed in the presence of a hydrofluoroether as the solvent.