Patent classifications
C08F216/14
Fluorinated copolymer dispersion, method for its production and article
To provide a fluorinated copolymer dispersion, whereby it is possible to obtain an article being excellent in water-and-oil repellency and less susceptible to a decrease in the water-and-oil repellency by alkali, etc. and which presents little impact to the environment by an organic solvent; a method for its production; and an article which is excellent in water-and-oil repellency and is less susceptible to a decrease in the water-and-oil repellency by alkali, etc. The fluorinated copolymer dispersion comprises an aqueous medium and a fluorinated copolymer dispersed in the aqueous medium, wherein the fluorinated copolymer has units based on the following monomer (a) and units based on the following monomer (b), the proportion of the units based on the monomer (a) being from 20 to 60 mol % to all units constituting the fluorinated copolymer, and the fluorinated copolymer has a number average molecular weight of from 10,000 to 100,000: Monomer (a): a compound represented by CH.sub.2═CH—R.sup.f (R.sup.f is a C.sub.1-8 perfluoroalkyl group); and Monomer (b): a monomer copolymerizable with the monomer (a).
Fluorinated copolymer dispersion, method for its production and article
To provide a fluorinated copolymer dispersion, whereby it is possible to obtain an article being excellent in water-and-oil repellency and less susceptible to a decrease in the water-and-oil repellency by alkali, etc. and which presents little impact to the environment by an organic solvent; a method for its production; and an article which is excellent in water-and-oil repellency and is less susceptible to a decrease in the water-and-oil repellency by alkali, etc. The fluorinated copolymer dispersion comprises an aqueous medium and a fluorinated copolymer dispersed in the aqueous medium, wherein the fluorinated copolymer has units based on the following monomer (a) and units based on the following monomer (b), the proportion of the units based on the monomer (a) being from 20 to 60 mol % to all units constituting the fluorinated copolymer, and the fluorinated copolymer has a number average molecular weight of from 10,000 to 100,000: Monomer (a): a compound represented by CH.sub.2═CH—R.sup.f (R.sup.f is a C.sub.1-8 perfluoroalkyl group); and Monomer (b): a monomer copolymerizable with the monomer (a).
Aqueous dispersion of multi-stage polymeric particles and process of making the same
A stable aqueous dispersion of multi-stage polymeric particles comprising a polymer and an oligomer, and an aqueous freeze-thaw stable coating composition comprising the aqueous dispersion providing coatings made therefrom with acceptable scrub resistance.
Aqueous dispersion of multi-stage polymeric particles and process of making the same
A stable aqueous dispersion of multi-stage polymeric particles comprising a polymer and an oligomer, and an aqueous freeze-thaw stable coating composition comprising the aqueous dispersion providing coatings made therefrom with acceptable scrub resistance.
FLUOROSULFONYL GROUP-CONTAINING FLUOROPOLYMER AND METHOD FOR PRODUCING SAME, SULFONIC ACID GROUP-CONTAINING FLUOROPOLYMER AND METHOD FOR PRODUCING SAME, SOLID POLYMER ELECTROLYTE MEMBRANE, MEMBRANE ELECTRODE ASSEMBLY, AND SOLID POLYMER FUEL CELL
The present invention provides a fluoropolymer containing fluorosulfonyl groups capable of forming a polymer electrolyte membrane with high conductivity and hot water resistance, a method for its production, a fluoropolymer containing acid-form sulfonic acid groups and a method for its production, a polymer electrolyte membrane, a membrane-electrode assembly and a polymer electrolyte fuel cell. The method for producing a fluoropolymer containing fluorosulfonyl groups of the present invention comprises copolymerizing a monomer m1 (CF.sub.2═CFCF.sub.2O-Q.sup.1-SO.sub.2F) and TFE in a reactor at a temperature of from 150 to 200° C. in the presence of a radical polymerization initiator, wherein the radical polymerization initiator is continuously or sequentially added into the reactor so that the concentration of the radical polymerization initiator is kept to at most 2.5 mass ppm of the initial feed of the monomer m1 present in the reactor before initiation of the copolymerization during the copolymerization, and the molar ratio of the total feed of the monomer m1 to the total feed of tetrafluoroethylene is from 1.5 to 20
COATED COLORANT, COLORING COMPOSITION, AND COATED COLORANT MANUFACTURING METHOD
A purpose of the present disclosure is to provide a coated colorant and a coloring composition that have superior dispersion stability, high compatibility with binder resins, low viscosity after being made into an ink, good preservation stability, and a good film gloss value. Provided is a coated colorant in which a surface of a colorant is coated with a resin (P), the resin (P) contains a colorant adsorption group-containing monomer unit, a maleic acid (anhydride) unit, and a (meth)aryl monomer unit, and the colorant adsorption group-containing monomer unit contains at least one of an α-olefin unit and a ring-containing monomer unit.
Fluorinated block copolymers derived from nitrile cure-site monomers
There is provided a curable composition comprising a fluorinated block copolymer having (a) at least one A block, wherein the A block is a semi-crystalline segment comprising repeating divalent monomeric units derived from at least a fluorinated monomer; and (b) at least one B block, wherein the B block is a segment comprising repeating divalent monomeric units that comprises at least a fluorinated monomer and a nitrile-containing cure-site monomer.
COMPOSITION AND MOLDED ARTICLE
A composition including a fluorine-containing polymer and a silicon-containing compound, wherein the phosphorus content in the composition is 20 ppm or less. Also disclosed is a molded article obtained from the composition, and a second composition containing a fluorine-containing polymer and a silicon-containing polymer, wherein a content of an amide solvent in the composition is less than 1000 ppm.
COMPOSITION AND MOLDED ARTICLE
A composition including a fluorine-containing polymer and a silicon-containing compound, wherein the phosphorus content in the composition is 20 ppm or less. Also disclosed is a molded article obtained from the composition, and a second composition containing a fluorine-containing polymer and a silicon-containing polymer, wherein a content of an amide solvent in the composition is less than 1000 ppm.
POLYMERS AND METHODS FOR OPHTHALMIC APPLICATIONS
Novel methods and materials particularly useful for ophthalmic applications and to methods for making and using the same are disclosed herein. More particularly, relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and implanting IOLs made therefrom are disclosed.