Provided are a polymer electrolyte and a lithium-ion battery including the polymer electrolyte. A preparation method of a polymer electrolyte includes: (1) dissolving a functional polymer with an organic solvent, and uniformly mixing to obtain a system A, where the functional polymer has a mass ratio of 0.2%-30% in the system A; (2) uniformly mixing the A system, a lithium salt, and a functional additive to obtain a mixed solution; (3) subjecting the mixed solution to in-situ polymerizing to obtain the polymer electrolyte. The polymer electrolyte has better affinity with anions of the lithium salt and relatively high electrical conductivity, and greatly improves the performance of the semi-solid state battery. The semi-solid state battery prepared is based on the existing lithium-ion battery processing technology, has good processing performance and electrochemical performance, and has certain application prospects.

Provided are a polymer electrolyte and a lithium-ion battery including the polymer electrolyte. A preparation method of a polymer electrolyte includes: (1) dissolving a functional polymer with an organic solvent, and uniformly mixing to obtain a system A, where the functional polymer has a mass ratio of 0.2%-30% in the system A; (2) uniformly mixing the A system, a lithium salt, and a functional additive to obtain a mixed solution; (3) subjecting the mixed solution to in-situ polymerizing to obtain the polymer electrolyte. The polymer electrolyte has better affinity with anions of the lithium salt and relatively high electrical conductivity, and greatly improves the performance of the semi-solid state battery. The semi-solid state battery prepared is based on the existing lithium-ion battery processing technology, has good processing performance and electrochemical performance, and has certain application prospects.

Recording a volume Bragg grating is effectuated by a recording medium formed from a matrix polymer precursor including a controlled radical reactive group, a photoactive base monomer, and a photoinitiator system more reactive with the photoactive base monomer than the controlled radical reactive group in the presence of an excitation source, and a photoredox catalyst. The medium is cured thereby forming a support matrix from the matrix polymer precursor. Exposure to the excitation source through a pattern causes the photoinitiator to polymerize the base monomer, forming a latent grating of the Bragg grating. The latent grating has bright and dark fringes determined by the pattern. The concentration of polymerized base polymer is higher in the bright fringes than in the dark fringes. The exposing causes a portion of the matrix to diffuse into the dark fringes. The support matrix has a lower refractive index than the polymerized photoactive base monomer.

Recording a volume Bragg grating is effectuated by a recording medium formed from a matrix polymer precursor including a controlled radical reactive group, a photoactive base monomer, and a photoinitiator system more reactive with the photoactive base monomer than the controlled radical reactive group in the presence of an excitation source, and a photoredox catalyst. The medium is cured thereby forming a support matrix from the matrix polymer precursor. Exposure to the excitation source through a pattern causes the photoinitiator to polymerize the base monomer, forming a latent grating of the Bragg grating. The latent grating has bright and dark fringes determined by the pattern. The concentration of polymerized base polymer is higher in the bright fringes than in the dark fringes. The exposing causes a portion of the matrix to diffuse into the dark fringes. The support matrix has a lower refractive index than the polymerized photoactive base monomer.

To provide a powder coating material capable of forming a coating film excellent in impact resistance, flexibility and adhesion to substrate and excellent in surface smoothness even when formed under low temperature film-forming conditions. The powder coating material of the present invention is a powder coating material comprising a fluorinated polymer having units based on a fluoroolefin, units based on a monomer represented by the formula X—Z and units based on a monomer represented by the formula CHR.sup.21═CR.sup.22 (CH.sub.2).sub.nCOOH, wherein the content of the units based on a monomer represented by the formula X—Z is from 5 to 20 mol % to all units in the fluorinated polymer, and the fluorinated polymer has a melt viscosity at 170° C. of from 20 to 100 Pa.Math.s (in the formulae, X is a specific monovalent polymerizable group, Z is a specific alkyl group, a specific cycloalkyl group or a specific aryl group, R.sup.21 and R.sup.22 are each independently a hydrogen atom or a specific alkyl group, and n is an integer of from 0 to 12.

To provide a powder coating material capable of forming a coating film excellent in impact resistance, flexibility and adhesion to substrate and excellent in surface smoothness even when formed under low temperature film-forming conditions. The powder coating material of the present invention is a powder coating material comprising a fluorinated polymer having units based on a fluoroolefin, units based on a monomer represented by the formula X—Z and units based on a monomer represented by the formula CHR.sup.21═CR.sup.22 (CH.sub.2).sub.nCOOH, wherein the content of the units based on a monomer represented by the formula X—Z is from 5 to 20 mol % to all units in the fluorinated polymer, and the fluorinated polymer has a melt viscosity at 170° C. of from 20 to 100 Pa.Math.s (in the formulae, X is a specific monovalent polymerizable group, Z is a specific alkyl group, a specific cycloalkyl group or a specific aryl group, R.sup.21 and R.sup.22 are each independently a hydrogen atom or a specific alkyl group, and n is an integer of from 0 to 12.

Provided herein are processes for the generation of composite polymer materials utilizing a single resin. The processes utilize diffusion between a region undergoing a polymerization reaction preferentially polymerizing one monomer component and an unreactive region. Diffusion and subsequent/concurrent polymerization results in a higher concentration of the more reactive monomer component in the reacting region and a higher concentration of the less reactive monomer components in the unreactive region. The unreactive region may be later polymerized. In embodiments, photopolymerization is used and the regions are generated by a mask or other mechanism to pattern the light.

Provided herein are processes for the generation of composite polymer materials utilizing a single resin. The processes utilize diffusion between a region undergoing a polymerization reaction preferentially polymerizing one monomer component and an unreactive region. Diffusion and subsequent/concurrent polymerization results in a higher concentration of the more reactive monomer component in the reacting region and a higher concentration of the less reactive monomer components in the unreactive region. The unreactive region may be later polymerized. In embodiments, photopolymerization is used and the regions are generated by a mask or other mechanism to pattern the light.

An object of the present invention is to provide a mixture of cyclophosphazenes suitably substituted with phenoxy having a polymerizable functional group, such as allyl, on the phenyl ring and a production method for the mixture. The invention relates to a mixture of cyclophosphazene compounds that each contain a plurality of constituent units linked to each other, each constituent unit being represented by formula (I): ##STR00001##
wherein R.sup.1 and R.sup.2 are identical or different and represent C.sub.1-4 alkyl or the like, the mixture containing cyclophosphazene compounds in which 3, 4, and 5 constituent units represented by formula (I) are linked, wherein the cyclophosphazene compound containing 3 linked constituent units is cyclophosphazene compound (I-A) with a specific structure, compound (I-A) includes cyclophosphazene compounds (I-A2) and (I-A3) having a specific structure, and compounds (I-A2) and (I-A3) are present in an amount of 80 wt % or more in total in cyclophosphazene compound (I-A).

An object of the present invention is to provide a mixture of cyclophosphazenes suitably substituted with phenoxy having a polymerizable functional group, such as allyl, on the phenyl ring and a production method for the mixture. The invention relates to a mixture of cyclophosphazene compounds that each contain a plurality of constituent units linked to each other, each constituent unit being represented by formula (I): ##STR00001##
wherein R.sup.1 and R.sup.2 are identical or different and represent C.sub.1-4 alkyl or the like, the mixture containing cyclophosphazene compounds in which 3, 4, and 5 constituent units represented by formula (I) are linked, wherein the cyclophosphazene compound containing 3 linked constituent units is cyclophosphazene compound (I-A) with a specific structure, compound (I-A) includes cyclophosphazene compounds (I-A2) and (I-A3) having a specific structure, and compounds (I-A2) and (I-A3) are present in an amount of 80 wt % or more in total in cyclophosphazene compound (I-A).