Patent classifications
C08F220/42
Toner
A toner is provided, which has a toner particle that contains a binder resin, and organosilicon polymer particle on a surface of the toner particle. A methanol concentration a (vol %) of the organosilicon polymer particle in a wettability test and a methanol concentration b (vol %) of the toner particle in a wettability test satisfy Expression (I) below:
|a−b|≤25 (I), and an adhesion index of the organosilicon polymer particle on a polycarbonate film, calculated on the basis of Expression (II) below, is not more than 3.5:
Adhesion index=area ratio c of the organosilicon polymer particle having migrated to the polycarbonate film/coverage ratio d of the organosilicon polymer particle on the surface of the toner particle×100 (II).
Toner
A toner is provided, which has a toner particle that contains a binder resin, and organosilicon polymer particle on a surface of the toner particle. A methanol concentration a (vol %) of the organosilicon polymer particle in a wettability test and a methanol concentration b (vol %) of the toner particle in a wettability test satisfy Expression (I) below:
|a−b|≤25 (I), and an adhesion index of the organosilicon polymer particle on a polycarbonate film, calculated on the basis of Expression (II) below, is not more than 3.5:
Adhesion index=area ratio c of the organosilicon polymer particle having migrated to the polycarbonate film/coverage ratio d of the organosilicon polymer particle on the surface of the toner particle×100 (II).
Method of preparing copolymer
Provided is a method of preparing a copolymer which includes 1) initiating polymerization by batch-adding an aromatic vinyl-based monomer and a vinyl cyan-based monomer to a reactor; and 2) performing polymerization by continuously adding an aromatic vinyl-based monomer to the reactor at a predetermined rate after the initiation of polymerization, wherein the continuous addition of the aromatic vinyl-based monomer is initiated when a polymerization conversion rate is 10% or less and terminated when a polymerization conversion rate is between 80 and 90%, and step 2) includes a first temperature phase and a second temperature phase, each of which maintains a constant temperature, wherein a temperature of the second temperature phase is higher than that of the first temperature phase, and thereby a copolymer with a small standard deviation for a vinyl cyan-based unit composition and excellent transparency may be prepared.
POLYMERIC COMPOSITION, AQUEOUS ACRYLIC RESIN HAVING HIGH SOLVENT RESISTANCE, AND METHOD FOR MANUFACTURING THE SAME
A polymeric composition, aqueous acrylic resin having high solvent resistance and a method for manufacturing the same, are provided. The polymeric composition includes an acrylic monomer polymer, an epoxy-containing silane and a reactive emulsifier. A weight ratio of the acrylic monomer polymer, the epoxy-containing silane and the reactive emulsifier is 100:1:3. The epoxy-containing silane is 1 to 3 wt % of (3-glycidoxypropyl) trimethoxy silane and/or 1 to 3 wt % of (3-glycidoxy propyl) methyl diethoxy silane.
SELF-DISINFECTING GLOVE COMPOSITION AND METHOD OF PRODUCTION THEREOF
A method for manufacturing a self-disinfecting glove, the method comprising dissolving an elastomer in a solvent to form a solution, wherein the elastomer is selected from the group consisting of synthetic rubber, natural rubber, and nitrile. Adding of a photosensitizer to the elastomer solvent solution and evaporating the solvent solution to form a film, wherein the photosensitizer is selected from the group consisting of methylene blue, hypericin and titanium dioxide. Next hot pressing of the film above elastomer's melting point to form a sheet. Finally cutting, stacking and hot pressing the sheet again to enable even spread of the photosensitizer throughout the sheet.
SELF-DISINFECTING GLOVE COMPOSITION AND METHOD OF PRODUCTION THEREOF
A method for manufacturing a self-disinfecting glove, the method comprising dissolving an elastomer in a solvent to form a solution, wherein the elastomer is selected from the group consisting of synthetic rubber, natural rubber, and nitrile. Adding of a photosensitizer to the elastomer solvent solution and evaporating the solvent solution to form a film, wherein the photosensitizer is selected from the group consisting of methylene blue, hypericin and titanium dioxide. Next hot pressing of the film above elastomer's melting point to form a sheet. Finally cutting, stacking and hot pressing the sheet again to enable even spread of the photosensitizer throughout the sheet.
Energy storage device
An energy storage device includes an anode, a cathode, and a separator disposed between the anode and the cathode. At least one of the anode, cathode and separator includes a copolymer functioning as a non-aqueous adhesive and/or solid-state electrolyte for the energy storage device. The copolymer is a copolymer or a derivative thereof, which is produced by polymerization of monomers containing conductive ion group and/or olefinic monomers in the presence of 2-propenenitrile. Therefore, the energy storage device which the copolymer is used therein has excellent charging and discharging performance to therefore effectively enhance the efficiency and extend the service life of the energy storage device.
Energy storage device
An energy storage device includes an anode, a cathode, and a separator disposed between the anode and the cathode. At least one of the anode, cathode and separator includes a copolymer functioning as a non-aqueous adhesive and/or solid-state electrolyte for the energy storage device. The copolymer is a copolymer or a derivative thereof, which is produced by polymerization of monomers containing conductive ion group and/or olefinic monomers in the presence of 2-propenenitrile. Therefore, the energy storage device which the copolymer is used therein has excellent charging and discharging performance to therefore effectively enhance the efficiency and extend the service life of the energy storage device.
Nitrile group-containing highly saturated copolymer rubber
The present invention provides a nitrile group-containing highly saturated copolymer rubber comprising an α,β-ethylenically unsaturated nitrile monomer unit in a content of 15 wt % or more and less than 28 wt %, an α,β-ethylenically unsaturated monocarboxylic acid ester monomer unit (b) in a content of 10 to 50 wt %, and a conjugated diene monomer unit (c) in a content of 22 to 75 wt %, and having an iodine value of 120 or less, wherein the conjugated diene monomer unit (c) is at least partially hydrogenated, and a proportion of an isoprene unit in the conjugated diene monomer unit (c) is 33 wt % or more.
Nitrile group-containing highly saturated copolymer rubber
The present invention provides a nitrile group-containing highly saturated copolymer rubber comprising an α,β-ethylenically unsaturated nitrile monomer unit in a content of 15 wt % or more and less than 28 wt %, an α,β-ethylenically unsaturated monocarboxylic acid ester monomer unit (b) in a content of 10 to 50 wt %, and a conjugated diene monomer unit (c) in a content of 22 to 75 wt %, and having an iodine value of 120 or less, wherein the conjugated diene monomer unit (c) is at least partially hydrogenated, and a proportion of an isoprene unit in the conjugated diene monomer unit (c) is 33 wt % or more.