A novel copolymer suitable for an optical film which is excellent in optical characteristics and has high retardation even in a thin film state, and an optical film containing the same are provided. A copolymer excellent in optical characteristics and easy to form a composite with a different polymer, and an optical film composed of the same are also provided.

A novel copolymer suitable for an optical film which is excellent in optical characteristics and has high retardation even in a thin film state, and an optical film containing the same are provided. A copolymer excellent in optical characteristics and easy to form a composite with a different polymer, and an optical film composed of the same are also provided.

The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.

The present invention relates to novel materials particularly useful for ophthalmic applications and methods for making and using the same. More particularly, the present invention relates to relatively soft, optically transparent, foldable, high refractive index materials particularly suited for use in the production of intraocular lenses, contact lenses, and other ocular implants and to methods for manufacturing and using the same.

Provided herein are processes for the generation of composite polymer materials utilizing a single resin. The processes utilize diffusion between a region undergoing a polymerization reaction preferentially polymerizing one monomer component and an unreactive region. Diffusion and subsequent/concurrent polymerization results in a higher concentration of the more reactive monomer component in the reacting region and a higher concentration of the less reactive monomer components in the unreactive region. The unreactive region may be later polymerized. In embodiments, photopolymerization is used and the regions are generated by a mask or other mechanism to pattern the light.

Provided herein are processes for the generation of composite polymer materials utilizing a single resin. The processes utilize diffusion between a region undergoing a polymerization reaction preferentially polymerizing one monomer component and an unreactive region. Diffusion and subsequent/concurrent polymerization results in a higher concentration of the more reactive monomer component in the reacting region and a higher concentration of the less reactive monomer components in the unreactive region. The unreactive region may be later polymerized. In embodiments, photopolymerization is used and the regions are generated by a mask or other mechanism to pattern the light.

Methods for fabricating orthodontic appliances are provided. In some embodiments, a method includes providing a polymerizable composition including a first polymerizable component and a second polymerizable component. The polymerizable composition can be characterized by an initial ratio of the first polymerizable component to the second polymerizable component. The method can include fabricating a portion of the orthodontic appliance from the polymerizable composition by forming a first region of the orthodontic appliance by exposing the polymerizable composition to radiation, the first region including a first ratio of the first polymerizable component to the second polymerizable component. The method can also include forming a second region of the orthodontic appliance, the second region including a second ratio of the first polymerizable component to the second polymerizable component. The initial ratio, the first ratio, and the second ratio can be different.

Methods for fabricating orthodontic appliances are provided. In some embodiments, a method includes providing a polymerizable composition including a first polymerizable component and a second polymerizable component. The polymerizable composition can be characterized by an initial ratio of the first polymerizable component to the second polymerizable component. The method can include fabricating a portion of the orthodontic appliance from the polymerizable composition by forming a first region of the orthodontic appliance by exposing the polymerizable composition to radiation, the first region including a first ratio of the first polymerizable component to the second polymerizable component. The method can also include forming a second region of the orthodontic appliance, the second region including a second ratio of the first polymerizable component to the second polymerizable component. The initial ratio, the first ratio, and the second ratio can be different.

Disclosed are high refractive index monomers for ceramic/metal 3D printing applications. The compositions disclosed herein have a higher refractive index and thus better resolution and lower scattering of the light when employed in a composition to deposit ceramic or metallic particles. The disclosed compositions also include low refractive cross-linkers selected for their good thermal decomposition and reactivity to provide good cohesion during the 3D printing.

Disclosed are high refractive index monomers for ceramic/metal 3D printing applications. The compositions disclosed herein have a higher refractive index and thus better resolution and lower scattering of the light when employed in a composition to deposit ceramic or metallic particles. The disclosed compositions also include low refractive cross-linkers selected for their good thermal decomposition and reactivity to provide good cohesion during the 3D printing.