Disclosed herein are copolymers formed by cationic polymerfization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

Disclosed herein are copolymers formed by cationic polymerfization of one or more cyclic dienes and a comonomer selected from the group consisting of a monoterpene, a branched styrene, and combinations thereof, in the presence of a catalyst. Random copolymers having repeat units derived from a cyclic conjugated diene, such as 1,3-cyclohexadiene, and a comonomer such as a monoterpene, can be prepared as soluble products in hydrocarbon solvents. The copolymers can be crosslinked with various crosslinking agents to form materials having good oxidative stability and fire retardancy. The uncrosslinked and crosslinked copolymers have useful properties such as a low dissipation factor, low dielectric constants, and a good balance of thermomechanical and electrical properties that make them valuable in electronic applications.

In a method for the manufacture of a hydrocarbon resin made of at least one cyclic diolefin component and at least one ethylenically unsaturated aromatic component having 8 to 13 carbon atoms, the monomer mixture is heated to a polymerisation temperature of at least 180° C. at a heating speed of 0.5 to 10° C./second to obtain a hydrocarbon resin with a reduced amount of by-products, wherein the monomer mixture is essentially liquid in a single phase during the heating to at least 180° C. and during polymerisation, and the subsequently hydrogenated hydrocarbon resin has good compatibility with other components of hot-melt adhesives.

In a method for the manufacture of a hydrocarbon resin made of at least one cyclic diolefin component and at least one ethylenically unsaturated aromatic component having 8 to 13 carbon atoms, the monomer mixture is heated to a polymerisation temperature of at least 180° C. at a heating speed of 0.5 to 10° C./second to obtain a hydrocarbon resin with a reduced amount of by-products, wherein the monomer mixture is essentially liquid in a single phase during the heating to at least 180° C. and during polymerisation, and the subsequently hydrogenated hydrocarbon resin has good compatibility with other components of hot-melt adhesives.

In a method for the manufacture of a hydrocarbon resin made of at least one cyclic diolefin component and at least one ethylenically unsaturated aromatic component having 8 to 13 carbon atoms, the monomer mixture is heated to a polymerisation temperature of at least 180° C. at a heating speed of 0.5 to 10° C./second to obtain a hydrocarbon resin with a reduced amount of by-products, wherein the monomer mixture is essentially liquid in a single phase during the heating to at least 180° C. and during polymerisation, and the subsequently hydrogenated hydrocarbon resin has good compatibility with other components of hot-melt adhesives.

The present invention provides an antifouling film that is excellent in antifouling properties, rubbing resistance, and adhesion. The antifouling film includes: a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light, the polymer layer being a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active components, 30 to 80 wt % of a polyfunctional acrylate, 10 to 30 wt % of a monofunctional amide monomer, 0.5 to 10 wt % of a fluorine-based release agent, and 5 to 30 wt % of a vinyl-based polymer containing a repeat unit represented by a predetermined formula.

The present invention provides an antifouling film that is excellent in antifouling properties, rubbing resistance, and adhesion. The antifouling film includes: a substrate; and a polymer layer disposed on a surface of the substrate and including on a surface thereof an uneven structure provided with projections at a pitch not longer than a wavelength of visible light, the polymer layer being a cured product of a polymerizable composition, the polymerizable composition containing, in terms of active components, 30 to 80 wt % of a polyfunctional acrylate, 10 to 30 wt % of a monofunctional amide monomer, 0.5 to 10 wt % of a fluorine-based release agent, and 5 to 30 wt % of a vinyl-based polymer containing a repeat unit represented by a predetermined formula.

Provided is a method for producing a hydrogenated petroleum resin having good compatibility with a base polymer and a good hue under a hydrogen pressure of 4 MPaG or less.

A method for producing a hydrogenated petroleum resin, includes a hydrogenation step of hydrogenating a polymerization product of dicyclopentadiene and a vinyl aromatic compound in the presence of a catalyst, in which the hydrogenation step is performed under conditions (A) to (C) below: (A) an amount of the catalyst used: 0.125 to 0.4 parts by mass relative to 100 parts by mass of a resin in the polymerization product; (B) a reaction pressure: 4 MPaG or less; and (C) a reaction temperature: 240 C. or higher.

Disclosed is a propylene-diene copolymer resin having excellent melt tension, with improved melt strength, high molecular weight and broad molecular weight distribution by using a specific metallocene catalyst system. The present invention provides a propylene-diene copolymer resin produced by polymerizing propylene and a diene compound of C4-C20 by using a metallocene catalyst system, wherein the propylene-diene copolymer resin has the melt index (2.16 kg load at 230 C.) of 0.1-100 g/10 min and the melt tension (advanced rheometric expansion system (ARES)) of 5-100 g.

Disclosed is a propylene-diene copolymer resin having excellent melt tension, with improved melt strength, high molecular weight and broad molecular weight distribution by using a specific metallocene catalyst system. The present invention provides a propylene-diene copolymer resin produced by polymerizing propylene and a diene compound of C4-C20 by using a metallocene catalyst system, wherein the propylene-diene copolymer resin has the melt index (2.16 kg load at 230 C.) of 0.1-100 g/10 min and the melt tension (advanced rheometric expansion system (ARES)) of 5-100 g.