C08F255/023

Composition and an article of manufacture comprising the same
10590279 · 2020-03-17 · ·

The invention provides a composition comprising the following A)-C): A) one or more monomers and/or oligomers; B) at least one chlorinated olefin-based polymer and/or at least one functionalized chlorinated olefin-based polymer; and C) at least one styrene-based block copolymer or derivative. The invention also provides a composition comprising the following D)-F): D) at least one compound selected from the following i) through v): i) Z.sup.1(CR.sup.1R.sup.2OC(O)CR.sup.3CH.sub.2).sub.2 (Formula 1, as described herein); ii) Z.sup.2.sub.(4-x)C[CR.sup.4R.sup.5(R.sup.6).sub.yOC(O)CR.sup.7CH.sub.2].sub.x (Formula 2, as described herein); iii) Z.sup.3.sub.(3-x)CR.sup.8[CR.sup.9R.sup.10(R.sup.11).sub.yOC(O)CR.sup.12CH.sub.2].sub.x (Formula 3, as described herein); iv) O{CR.sup.13R.sup.14C(Z.sup.4.sub.(3-x))[CR.sup.15R.sup.16(R.sup.17).sub.yOC(O)CR.sup.18CH.sub.2)].sub.x}.sub.2 Formula 4, as described herein); v) a combination of two or more from Formulas 1 through 4 above; E) at least one chlorinated olefin-based polymer and/or at least one functionalized chlorinated olefin-based polymer; and F) at least one styrene-based block copolymer or derivative thereof.

CURABLE RESIN COMPOSITION FOR OPTICAL FILMS, OPTICAL FILM AND METHOD FOR PRODUCING SAME
20200056051 · 2020-02-20 · ·

A curable resin composition for optical films comprises an active-energy-ray-curable component (A) and a chlorinated polyolefin (B). It is preferred that the chlorinated polyolefin (B) has a chlorine content of 25 to 50% by weight. It is also preferred that a ratio by weight of the active-energy-ray-curable component (A) to the chlorinated polyolefin (B) is from 100/1 to 100/40.

CURABLE RESIN COMPOSITION FOR OPTICAL FILMS, OPTICAL FILM AND METHOD FOR PRODUCING SAME
20200056051 · 2020-02-20 · ·

A curable resin composition for optical films comprises an active-energy-ray-curable component (A) and a chlorinated polyolefin (B). It is preferred that the chlorinated polyolefin (B) has a chlorine content of 25 to 50% by weight. It is also preferred that a ratio by weight of the active-energy-ray-curable component (A) to the chlorinated polyolefin (B) is from 100/1 to 100/40.

Process for production of cross-linked polyethylene articles

A method of producing a sliane cross-linked polyethylene is disclosed which includes maleating a polyethylene polymer to form a maleated polyethylene and reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene. The method further includes treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked polyethylene.

PREPARATION METHODS OF SOLVENT-FREE SELF-EMULSIFYING WATER-SOLUBLE CHLORINATED POLYPROPYLENE

A preparation method of solvent-free self-emulsifying water-soluble chlorinated polypropylene is provided. By uniformly mixing chlorinated polypropylene, an acrylic acid/ester mixture and a cosolvent, initiating the chlorinated polypropylene to generate free radicals by using an initiator, further initiating free radical polymerization of the acrylic acid/ester mixture, then adding an isocyanate-terminal carboxyl hyperbranched polyester adduct, reacting, then neutralizing with amine, emulsifying, and diluting with deionized water, the solvent-free self-emulsifying water-soluble chlorinated polypropylene with a solid content of 30-45% may be obtained. The process of the present invention is simple, and easy to industrialize, and the product has the advantages of low VOC content, no organic solvent, water dilution, excellent stability, etc., and is expected to be widely used in the fields of water-soluble paints, surface modification of non-polar or low-polar plastics and the like.

REACTIVE FUNCTIONALIZATION OF CARBON-CARBON BACKBONE POLYMERS AND RELATED COMPOSITIONS
20240132651 · 2024-04-25 ·

The disclosure relates to the functionalization of a carbon-carbon backbone (CCB) polymer using a (cyclic) grafting agent, an initiator, and optionally a reversible radical trapping agent. The grafting agent and/or initiator can be particularly selected in terms of their surface energy and/or half-life, respectively, to limit or control undesirable effects associated with reactive melt-processing, such as excessive crosslinking, chain scission, or grafting agent homopolymerization, as well as to improve or control desirable effects associated with reactive melt-processing, such as improved relative graft uniformity or homogeneity on the CCB polymer. In some cases, the grafting agent can further include a functional group to impart some additional or new chemical or physical property to the CCB polymer. In some cases, the reactively melt-processed mixture includes two or more different polymers that are compatibilized via the grafting agent.

MODIFIED POLYOLEFIN RESIN

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B).

Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an ,-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an ,-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller.

Resin (B): a polyolefin resin or a modified product thereof.

MODIFIED POLYOLEFIN RESIN

Provided is a modified polyolefin resin that is excellent in adhesion to nonpolar substrates such as a polyolefin substrate, and excellent in stability in an alcohol solvent. In the modified polyolefin resin, the following polymer (A) is grafted on the following resin (B).

Polymer (A): a polymer including at least one constitutional unit selected from the group consisting of a constitutional unit derived from an ,-unsaturated carboxylic acid and a constitutional unit derived from a derivative of an ,-unsaturated carboxylic acid, and having a hydroxyl value in a range of 10 mgKOH/g or larger and 200 mgKOH/g or smaller.

Resin (B): a polyolefin resin or a modified product thereof.

Low dielectric resin composition, molded article, film, multilayer film and flexible printed wiring board

The present disclosure provides a low dielectric resin composition having good melt processability and excellent low dielectric characteristics in a high frequency band as compared to low dielectric materials such as liquid crystal polymers. A molded article and a film, each of which is formed from the low dielectric resin composition, a multilayer film obtained by superposing a metal foil on at least one main surface of the film, and a flexible printed wiring board which includes the film are also provided. The present disclosure includes, as a low dielectric resin composition, a resin composition which contains (A) a liquid crystal polymer and (B) a graft-modified polyolefin having a polar group. The low dielectric resin composition has a dielectric constant of 2.80 or less at a frequency of 10 GHz and a dielectric loss tangent of 0.0025 or less at a frequency of 10 GHz.

STRONG CATION EXCHANGE CHROMATOGRAPHIC MATRIX AND METHOD FOR USING SAME
20190217285 · 2019-07-18 · ·

A cation exchange chromatographic matrix comprising a base material, and a copolymer with one monomer unit having at least a sulfonic acid group, the copolymer being immobilized on the base material, wherein: the copolymer forms substantially no cross-linked structure, and the copolymer comprises neither acrylamide nor an acrylamide derivative as a monomer unit, or comprises acrylamide or an acrylamide derivative as a monomer unit in a range which has no substantial influence; the ratio of the mass of the copolymer to the mass of the base material is 5% or more and 200% or less; and the density of the sulfonic acid group is higher than 30 mmol/L and 200 mmol/L or lower.