The present invention provides a highly dispersible metallic acrylate composition containing specific content of a graphene, a flake graphite or a combination thereof as a thermally conductive powder, and thus has better stability and dispersivity, which leads to advantages of low adhesion to the metal surface and ease of mixing in resin. Moreover, the metallic acrylate composition can be applied to resin composition as an auxiliary crosslinking coagent for enhancing mechanical strength and good uniformity of cell dispersion in the foamed product, such that the foamed products can be used as architectural materials, materials of daily commodities, vehicle materials, damping and cushioning materials, packing materials, sport pad materials, or shoe materials.

A method of producing a silane cross-linked polyethylene is disclosed which includes maleating a polyethylene polymer to form a maleated polyethylene and reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene. The method further includes treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked polyethylene.

A method of producing a silane cross-linked polyethylene is disclosed which includes maleating a polyethylene polymer to form a maleated polyethylene and reacting the maleated polyethylene with a primary or secondary amino silane to form a silane-grafted polyethylene. The method further includes treating the silane-grafted polyethylene in a moisture curing process to form the silane cross-linked polyethylene.

Disclosed is an ethylene-α-olefin-nonconjugated polyene copolymer rubber satisfying the following requirements (A) and (B): (A) A proportion of a cyclohexane insoluble component at 25° C. is from 0.3% to 50% by mass with respect to a mass of the ethylene-α-olefin-nonconjugated polyene copolymer rubber; and (B) A tan δ ratio calculated by the following equation:

tan δ ratio=tan δ (100° C., 5 cpm)/tan δ (100° C., 1000 cpm)

is from 3.0 to 20. The tan δ (100° C., 5 cpm) and tan δ (100° C., 1000 cpm) are a loss tangent at 100° C. and a frequency of 5 cpm and a loss tangent at 100° C. and a frequency of 1000 cpm, respectively.

Disclosed is an ethylene-α-olefin-nonconjugated polyene copolymer rubber satisfying the following requirements (A) and (B): (A) A proportion of a cyclohexane insoluble component at 25° C. is from 0.3% to 50% by mass with respect to a mass of the ethylene-α-olefin-nonconjugated polyene copolymer rubber; and (B) A tan δ ratio calculated by the following equation:

tan δ ratio=tan δ (100° C., 5 cpm)/tan δ (100° C., 1000 cpm)

is from 3.0 to 20. The tan δ (100° C., 5 cpm) and tan δ (100° C., 1000 cpm) are a loss tangent at 100° C. and a frequency of 5 cpm and a loss tangent at 100° C. and a frequency of 1000 cpm, respectively.

The present invention provides a modified polyolefin resin composition including a modified polyolefin resin (X) formed by modifying an acid-modified polyolefin resin (A) with a modification component comprising an alcohol (B), in which the modified polyolefin resin composition satisfies the following (I) to (III) and also provides applications of the modified polyolefin resin composition.

(I) The resin (A) is a resin formed by modifying a polyolefin (a) with an α,β-unsaturated carboxylic acid and a derivative (b) of the α,β-unsaturated carboxylic acid having a structure (b1) derived from at least one carboxy group.

(II) A residual ratio of the structure (b1) in the resin (X) is more than 0% to 50% or less.

(III) A content of the alcohol in the composition is 1.0 mol to 5.0 mol relative to 1.0 mol of the structure (b1) that the resin (A) has.

The present invention provides a modified polyolefin resin composition including a modified polyolefin resin (X) formed by modifying an acid-modified polyolefin resin (A) with a modification component comprising an alcohol (B), in which the modified polyolefin resin composition satisfies the following (I) to (III) and also provides applications of the modified polyolefin resin composition.

(I) The resin (A) is a resin formed by modifying a polyolefin (a) with an α,β-unsaturated carboxylic acid and a derivative (b) of the α,β-unsaturated carboxylic acid having a structure (b1) derived from at least one carboxy group.

(II) A residual ratio of the structure (b1) in the resin (X) is more than 0% to 50% or less.

(III) A content of the alcohol in the composition is 1.0 mol to 5.0 mol relative to 1.0 mol of the structure (b1) that the resin (A) has.

Provided are a method for preparing a graft copolymer and a graft copolymer prepared thereby, the method comprising: preparing a reaction solution comprising a copolymer comprising a unit derived from a diene-based monomer and a unit derived from an alkene-based monomer, an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and a reaction solvent; and adding the reaction solution to perform primary bulk polymerization at 100 to 110° C., wherein the copolymer comprises the unit derived from a diene-based monomer in an amount of 5 to 10 wt %, and the graft copolymer has an average rubber particle size of 2 to 5μm.

Provided are a method for preparing a graft copolymer and a graft copolymer prepared thereby, the method comprising: preparing a reaction solution comprising a copolymer comprising a unit derived from a diene-based monomer and a unit derived from an alkene-based monomer, an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and a reaction solvent; and adding the reaction solution to perform primary bulk polymerization at 100 to 110° C., wherein the copolymer comprises the unit derived from a diene-based monomer in an amount of 5 to 10 wt %, and the graft copolymer has an average rubber particle size of 2 to 5μm.

Provided are a method for preparing a graft copolymer and a graft copolymer prepared thereby, the method comprising: preparing a reaction solution comprising a copolymer comprising a unit derived from a diene-based monomer and a unit derived from an alkene-based monomer, an aromatic vinyl-based monomer, a vinyl cyan-based monomer, and a reaction solvent; and adding the reaction solution to perform primary bulk polymerization at 100 to 110° C., wherein the copolymer comprises the unit derived from a diene-based monomer in an amount of 5 to 10 wt %, and the graft copolymer has an average rubber particle size of 2 to 5μm.