The present disclosure provides a modified polyvinyl alcohol-based polymer, which comprises a modifying monomer unit represented by Formula

##STR00001##

wherein, X is a moiety comprising an alkenyl group, and the modified polyvinyl alcohol-based polymer has a saponification degree of 67 mol % to 78 mol % and a modification rate of 0.02 mol % to 1.5 mol %. The modified polyvinyl alcohol-based polymer is suitable to be used as a dispersant for suspension polymerization, to make the obtained polyvinyl chloride-based resin have reduced particle diameter and few coarse particles.

In an embodiment, a composition comprises a plurality of reactive particles; wherein at least a first portion of the reactive particles comprises a first reactive monomer located in a first matrix polymer; wherein the first reactive monomer comprises a self-reactive monomer or wherein the first reactive monomer can polymerize with a second reactive monomer located in a second matrix polymer of a second portion of the reactive particles to form a coating polymer. In another embodiment, a method of making the plurality of reactive particles, comprises polymerizing a first matrix monomer in the presence of the first reactive monomer; or polymerizing the first matrix monomer to form a plurality of particles and swelling the plurality of particles with the first reactive monomer. In another embodiment, a method comprises cold spraying the plurality of reactive particles.

In an embodiment, a composition comprises a plurality of reactive particles; wherein at least a first portion of the reactive particles comprises a first reactive monomer located in a first matrix polymer; wherein the first reactive monomer comprises a self-reactive monomer or wherein the first reactive monomer can polymerize with a second reactive monomer located in a second matrix polymer of a second portion of the reactive particles to form a coating polymer. In another embodiment, a method of making the plurality of reactive particles, comprises polymerizing a first matrix monomer in the presence of the first reactive monomer; or polymerizing the first matrix monomer to form a plurality of particles and swelling the plurality of particles with the first reactive monomer. In another embodiment, a method comprises cold spraying the plurality of reactive particles.

Disclosed is a coating material comprising (B) an aqueous emulsion obtainable by polymerizing (b) a polymerizable unsaturated monomer in the presence of (A) a copolymer having a carboxyl group, wherein the polymerizable unsaturated monomer (b) comprises (b1) a (meth)acrylic acid ester, and the content of the (meth)acrylic acid ester (b1) is more than 95 parts by mass based on 100 parts by mass of the total mass of the polymerizable unsaturated monomer (b).

Disclosed is a coating material comprising (B) an aqueous emulsion obtainable by polymerizing (b) a polymerizable unsaturated monomer in the presence of (A) a copolymer having a carboxyl group, wherein the polymerizable unsaturated monomer (b) comprises (b1) a (meth)acrylic acid ester, and the content of the (meth)acrylic acid ester (b1) is more than 95 parts by mass based on 100 parts by mass of the total mass of the polymerizable unsaturated monomer (b).

Provided is a hydrogel-forming composition capable of forming a sterilized hydrogel having a high mechanical strength. Also provided are a hydrogel using the hydrogel-forming composition, and a method for producing the hydrogel-forming composition. The hydrogel-forming composition contains a vinyl alcohol polymer having an ethylenically unsaturated group and having a polymerization degree of 450 or more, in which the ethylenically unsaturated group introduction ratio is 0.01 to 10 mol % in all the structural units constituting the vinyl alcohol polymer, and in which no microorganisms detectable by the sterility test method (direct method) specified in the general test methods of the Japanese Pharmacopoeia are present.

Provided is a hydrogel-forming composition capable of forming a sterilized hydrogel having a high mechanical strength. Also provided are a hydrogel using the hydrogel-forming composition, and a method for producing the hydrogel-forming composition. The hydrogel-forming composition contains a vinyl alcohol polymer having an ethylenically unsaturated group and having a polymerization degree of 450 or more, in which the ethylenically unsaturated group introduction ratio is 0.01 to 10 mol % in all the structural units constituting the vinyl alcohol polymer, and in which no microorganisms detectable by the sterility test method (direct method) specified in the general test methods of the Japanese Pharmacopoeia are present.

A preparation method of a crosslinking-type aqueous binder for lithium-ion batteries. An organic carboxylic group-, amino group- or hydroxyl group-containing hydrophilic polymer, and a hydroxyl group-, amine group- or carboxyl group-containing water-soluble small-molecule crosslinker, both serve as starting materials of the aqueous binder, and can be crosslinked by esterification or amidation under coating and drying conditions of lithium-ion battery electrode slurry. The preparation method of the crosslinking-type aqueous binder is simple, without the need of modifying the current process or conditions for lithium-ion battery manufacture. The obtained electrodes have excellent binding capacity, flexibility, and elasticity.

An interlayer film for laminated glass of the present invention has an average storage modulus (G′) at 110 to 150° C. measured at a frequency of 1 Hz in a shear mode of 15000 Pa or less, and has an adhesive strength of 0.3 N/mm.sup.2 or more as measured in a cross peeling test performed under the following conditions on a cross peeling test sample produced by a predetermined method. Cross peeling test: A maximum load (N) when the polycarbonate plate glass is peeled from the clear float plate glass in a direction perpendicular to an adhesive surface at a rate of 10 mm/min at 23° C. is measured, and that measured maximum load (N) is taken as the adhesive strength.

An interlayer film for laminated glass of the present invention has an average storage modulus (G′) at 110 to 150° C. measured at a frequency of 1 Hz in a shear mode of 15000 Pa or less, and has an adhesive strength of 0.3 N/mm.sup.2 or more as measured in a cross peeling test performed under the following conditions on a cross peeling test sample produced by a predetermined method. Cross peeling test: A maximum load (N) when the polycarbonate plate glass is peeled from the clear float plate glass in a direction perpendicular to an adhesive surface at a rate of 10 mm/min at 23° C. is measured, and that measured maximum load (N) is taken as the adhesive strength.