A thermoplastic resin composition of the present invention is characterized by comprising: a base resin containing a rubber-modified vinyl-based graft copolymer, a large-diameter rubber polymer having an average particle size of about 3 to about 8 μm, and an aromatic vinyl-based copolymer resin; and polyorganosilsesquioxane fine particles having an average particle size of about 0.1 to about 10 μm. The thermoplastic resin composition is excellent in low gloss, weather resistance, and the like.

A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.

A thermoplastic resin composition includes a resin component (A) in an amount of 97 to 80 parts by mass; and a hitting sound reducing material (B) in an amount of 3 to 20 parts by mass. The hitting sound reducing material (B) is a hydrogenated copolymer derived from hydrogenation of a copolymer formed of a block portion (I) primarily including structural units derived from an aromatic vinyl-based compound, and a random portion (II) primarily including structural units derived from an aromatic vinyl-based compound and derived from butadiene. The structural units derived from an aromatic vinyl-based compound in the block portion (I) and derived from an aromatic vinyl-based compound in the random portion (II) are present in a total content of 55 to 80 mass % relative to a 100 total mass % of the copolymer, and the hydrogenated copolymer has a primary dispersion peak of tan δ at 0° C. or greater.

The present disclosure relates to a thermoplastic resin composition including a styrene-based copolymer comprising a (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a maleimide-based monomer; a first graft copolymer including an acrylic-based rubber polymer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer; and a second graft copolymer comprising an acrylic-based rubber polymer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer, wherein the styrene-based copolymer has a residual oligomer content of 0.37% by weight or less, and the acrylic-based rubber polymer of the first graft copolymer and the acrylic-based rubber polymer of the second graft copolymer have different average particle diameters. A method of preparing the thermoplastic resin composition, and a molded article including the thermoplastic resin composition are also disclosed.

The present disclosure relates to a thermoplastic resin composition including a styrene-based copolymer comprising a (meth)acrylate-based monomer, an aromatic vinyl-based monomer, and a maleimide-based monomer; a first graft copolymer including an acrylic-based rubber polymer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer; and a second graft copolymer comprising an acrylic-based rubber polymer, an aromatic vinyl-based monomer, and a vinyl cyanide-based monomer, wherein the styrene-based copolymer has a residual oligomer content of 0.37% by weight or less, and the acrylic-based rubber polymer of the first graft copolymer and the acrylic-based rubber polymer of the second graft copolymer have different average particle diameters. A method of preparing the thermoplastic resin composition, and a molded article including the thermoplastic resin composition are also disclosed.

The present invention relates to a thermoplastic resin composition and a molded product produced therefrom, the thermoplastic resin composition including, based on 100 parts by weight of a base resin including (A1) 20 to 40 wt % of a butadiene-based rubber-modified aromatic vinyl-vinyl cyanide graft copolymer, (A2) 30 to 75 wt % of an aromatic vinyl-vinyl cyanide copolymer, and (B) 5 to 40 wt % of a polyamide resin, (C) 1 to 15 parts by weight of a polyether ester amide block copolymer, and (D) 0.5 to 10 parts by weight of an N-substituted maleimide-aromatic vinyl-maleic anhydride copolymer.

The present invention relates to a flame retardant resin composition having excellent flame retardancy and improved thermal deformation properties, and a flame retardant resin molded article manufactured therefrom, and provides a flame retardant resin composition including a) a base resin including a polyarylene ether-based polymer; an aromatic vinyl-based polymer and a copolymer of vinylcyan monomer-conjugated diene monomer-aromatic vinyl monomer; b) an organophosphorus-based flame retardant; c) a hypophosphite compound; and d) a sulfur-containing compound including at least two sulfur atoms, wherein b) the organophosphorus-based flame retardant, c) the hypophosphite compound and d) the sulfur-containing compound are included in a weight ratio of 15 to 24:2 to 4:2 to 5.

The present invention relates to a method of preparing a heat-resistant resin, a heat-resistant resin, and a heat-resistant ABS resin. According to the preparation method of the present invention, the heat-resistant resin can be prepared at a high polymerization conversion rate within a shortened polymerization time, and the amount of polymerized coagulum and the content of fine particles upon coagulation are decreased. Accordingly, a heat-resistant resin and a heat-resistant ABS resin composition with enhanced heat deflection temperature and processability are provided.

The present invention relates to a method of preparing a heat-resistant resin, a heat-resistant resin, and a heat-resistant ABS resin. According to the preparation method of the present invention, the heat-resistant resin can be prepared at a high polymerization conversion rate within a shortened polymerization time, and the amount of polymerized coagulum and the content of fine particles upon coagulation are decreased. Accordingly, a heat-resistant resin and a heat-resistant ABS resin composition with enhanced heat deflection temperature and processability are provided.

The present invention relates to a method for preparing a diene-based rubber polymer having relatively low gel content and high swelling index while having high polymerization conversion rate, a diene-based rubber polymer prepared therefrom and an acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the same as a core. Accordingly, the method for preparing a diene-based rubber polymer and the acrylonitrile-butadiene-styrene graft copolymer with a core-shell structure comprising the diene-based rubber polymer prepared therefrom can be easily applied to the industries requiring them, in particular, an impact reinforcing agent industry.