Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices.

Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices.

The invention relates to compositions containing at least one siloxane which comprises ethylenically unsaturated, radically polymerizing groups, and at least one hydrocarbon with ethylenically unsaturated, radically polymerizing groups, which have, when used as a separating coating, an improved barrier effect.

Provided is a thermoplastic resin composition and a molded article excellent in balance of color developability and low-temperature impact resistance, where a polyorganosiloxane-containing graft copolymer in which a rubber (A) containing a polyorganosiloxane (A1) and a vinyl polymer (A2) is grafted with a vinyl monomer (b), wherein the vinyl polymer (A2) includes 90 to 100% by mass of a monofunctional vinyl monomer (a1) and 10 to 0% by mass of a polyfunctional vinyl monomer (a2) with respect to 100% by mass of the vinyl polymer (A2), wherein the glass transition temperature of the homopolymer of the monofunctional vinyl monomer (a1) is 0° C. or higher, and the peak of tan δ of the polyorganosiloxane-containing graft copolymer is in the range of −125° C. to −90° C.

Provided is a thermoplastic resin composition and a molded article excellent in balance of color developability and low-temperature impact resistance, where a polyorganosiloxane-containing graft copolymer in which a rubber (A) containing a polyorganosiloxane (A1) and a vinyl polymer (A2) is grafted with a vinyl monomer (b), wherein the vinyl polymer (A2) includes 90 to 100% by mass of a monofunctional vinyl monomer (a1) and 10 to 0% by mass of a polyfunctional vinyl monomer (a2) with respect to 100% by mass of the vinyl polymer (A2), wherein the glass transition temperature of the homopolymer of the monofunctional vinyl monomer (a1) is 0° C. or higher, and the peak of tan δ of the polyorganosiloxane-containing graft copolymer is in the range of −125° C. to −90° C.

There is provided an insertion auxiliary tube having a tubular substrate a and a layer b disposed on at least one of an inside or an outside of the tubular substrate a. The layer b includes a polymer including a polysiloxane structure. The polymer includes an acrylic acid component, an acrylic acid ester component, an acrylamide component, or a styrene component and has a particular polar group in a molecule thereof. There are also provided a composition for an insertion auxiliary tube capable of providing the insertion auxiliary tube, a set of the insertion auxiliary tube and an endoscope, an endoscope apparatus including the insertion auxiliary tube and an endoscope, and a method for producing the insertion auxiliary tube.

There is provided an insertion auxiliary tube having a tubular substrate a and a layer b disposed on at least one of an inside or an outside of the tubular substrate a. The layer b includes a polymer including a polysiloxane structure. The polymer includes an acrylic acid component, an acrylic acid ester component, an acrylamide component, or a styrene component and has a particular polar group in a molecule thereof. There are also provided a composition for an insertion auxiliary tube capable of providing the insertion auxiliary tube, a set of the insertion auxiliary tube and an endoscope, an endoscope apparatus including the insertion auxiliary tube and an endoscope, and a method for producing the insertion auxiliary tube.

The problem to be addressed by the invention is to provide a polymerizable composition for three-dimensional modeling used for producing three-dimensional models having high flexural modulus and impact strength, as well as high dimensional accuracy, and a production method for the composition. In order to solve the problem, the polymerizable composition for three-dimensional modeling contains an inorganic filler with an aspect ratio of 5 or greater, a dispersant, a photopolymerizable compound, and a thermally polymerizable compound.

The invention discloses a preparation method of a polyimide film having a low dielectric constant and high fracture toughness; in the method an aromatic diamine solution is firstly prepared, and then a poly(5-norbornene-2,3-dicarboxylic anhydride-alt-maleimide isobutyl polyhedral oligomeric silsesquioxane) and aromatic dianhydride are ground, uniformly mixed, added to the aromatic diamine solution, and stirred to obtain a poly(5-norbornene-2,3-dicarboxylic anhydride-alt-maleimide isobutyl polyhedral oligomeric silsesquioxane)/polyamic acid solution; the solution is uniformly applied on a clean glass sheet, then placed in a vacuum drying oven, cooled to room temperature, and then a film is peeled off in water by ultrasonic and dried under vacuum to obtain the desired product. The dielectric constant of the film obtained by the invention is reduced to 2.2, and the elongation at break is increased by 272%, the tensile breaking energy is increased by 285%, showing greatly improved elongation at break and fracture energy, and good fracture toughness.

A (meth)acrylic silicone graft (co)polymer having a unit represented by the following formula (I), a structure represented by the following formula (III) at one terminal, and a structure represented by the following formula (IV) at the other terminal, ##STR00001##
wherein A is a group having a linear organopolysiloxane structure represented by the following formula (1) or a group having a dendritic organopolysiloxane structure represented by the following formula (2-1) or (2-2), X is a group as defined for A, ##STR00002##
wherein Z is a divalent organic group, Q is a group represented by the following formula (2), D is a (3.sup.c+1)-valent organopolysiloxanyl group which has a hierachial order of c, 3.sup.c means 3 raised to the power of c, c is an integer of from 1 to 8. ##STR00003##