Provided is a polymer particle comprising (a) a core polymer comprising (i) polymerized units of one or more Si-containing monomers; (ii) polymerized units of one or more monovinyl acrylic monomers (ii); and (iii) polymerized units of one or more graftlinkers that have no silicon atoms; (b) a shell polymer comprising polymerized units of one or more acrylic monomers. Also provided is a composition comprising polyvinyl chloride and a plurality of the polyer particles.

Provided is a polymer particle comprising (a) a core polymer comprising (i) polymerized units of one or more Si-containing monomers; (ii) polymerized units of one or more monovinyl acrylic monomers (ii); and (iii) polymerized units of one or more graftlinkers that have no silicon atoms; (b) a shell polymer comprising polymerized units of one or more acrylic monomers. Also provided is a composition comprising polyvinyl chloride and a plurality of the polyer particles.

Provided are polymer compositions made by a process comprising: (a) providing a first reactive composition containing: (i) a polymerization initiator that is capable, upon a first activation, of forming two or more free radical groups, at least one of which is further activatable by subsequent activation; (ii) one or more ethylenically unsaturated compounds; and (iii) a crosslinker; (b) subjecting the first reactive composition to a first activation step such that the first reactive composition polymerizes therein to form a crosslinked substrate network containing a covalently bound activatable free radical initiator, (c) combining the crosslinked substrate network with a second reactive composition containing one or more ethylenically unsaturated compounds; and (d) activating the covalently bound activatable free radical initiator of the crosslinked substrate network such that the second reactive composition polymerizes therein with the crosslinked substrate network to form a grafted polymeric network and a byproduct polymer. Also provided are precursors to the polymer compositions, processes for preparation of the polymer compositions, and methods of using the polymer compositions, for instance in medical devices.

An aqueous dispersion of a polymer additive having a weight average molecular weight of from 2,000 to 25,000 g/mol and comprising, by weight based on the weight of the polymer additive, (i) from 20% to 85% of structural units of an ethylenically unsaturated siloxane monomer; (ii) from 0.1% to 10% of structural units of an ethylenically unsaturated functional monomer carrying at least one functional group selected from an amide, ureido, carboxyl, carboxylic anhydride, hydroxyl, phosphorus acid, or sulfonic acid group, a salt thereof, or mixtures thereof; and (iii) from 5% to 79.9% of structural units of an additional ethylenically unsaturated nonionic monomer. The aqueous dispersion has a coagulum content less than 2,000 ppm after filtration through a 44 micron sieve. A coating composition comprises the aqueous dispersion of the polymer additive can provide coatings with anti-corrosion and/or stain removal properties.

A light-curable dental impression material comprising (a) a polymerizable polysiloxane resin composition comprising compounds of formula (I)
E−(L.sup.1−Z).sub.n−L.sup.2−E   (I)
(b) a particulate filler; and
(c) a photoinitiator.

The disclosure generally relates to omniphobic compatibilizers, which include a polymerization reaction product between a first vinyl monomer, optionally a second vinyl crosslinking monomer, and a functionalized omniphobic polymer. The functionalized omniphobic polymer can include two or more vinyl functional groups or at least one free radical initiator functional group such that the reaction product forming the omniphobic compatibilizer can be a vinyl or free-radical polymerization product. The omniphobic compatibilizer can be incorporated into a UV-curable or a non-UV-curable thermoset omniphobic composition. The UV-curable composition can be a crosslinked polymerization reaction product between the omniphobic compatibilizer, a third vinyl monomer, and a fourth polyvinyl crosslinking monomer. The non-UV-curable composition can be a crosslinked polymerization reaction product between the omniphobic compatibilizer, a first thermosetting component, and a second thermosetting component. The thermoset omniphobic composition can be a coating on a substrate in a corresponding coated article.

The disclosure generally relates to omniphobic compatibilizers, which include a polymerization reaction product between a first vinyl monomer, optionally a second vinyl crosslinking monomer, and a functionalized omniphobic polymer. The functionalized omniphobic polymer can include two or more vinyl functional groups or at least one free radical initiator functional group such that the reaction product forming the omniphobic compatibilizer can be a vinyl or free-radical polymerization product. The omniphobic compatibilizer can be incorporated into a UV-curable or a non-UV-curable thermoset omniphobic composition. The UV-curable composition can be a crosslinked polymerization reaction product between the omniphobic compatibilizer, a third vinyl monomer, and a fourth polyvinyl crosslinking monomer. The non-UV-curable composition can be a crosslinked polymerization reaction product between the omniphobic compatibilizer, a first thermosetting component, and a second thermosetting component. The thermoset omniphobic composition can be a coating on a substrate in a corresponding coated article.

The present invention provides a vinyl acetate-silicone copolymer resin obtained by graft polymerization of vinyl acetate (B) onto an organopolysiloxane (A) represented by a specific general formula, wherein a weight ratio of the organopolysiloxane (A) to the vinyl acetate (B) is (A):(B)=10:90 to 95:5, a method for producing the same, and a vinyl acetate-silicone copolymer resin composition. The vinyl acetate-silicone copolymer resin of the present invention has slidability, substrate adhesiveness, and organic solvent solubility, and is suitably used for coating agents for various substrates, adhesive agents, exterior and interior paints for structures and building materials and the like, and cosmetics and the like.

The present invention provides a vinyl acetate-silicone copolymer resin obtained by graft polymerization of vinyl acetate (B) onto an organopolysiloxane (A) represented by a specific general formula, wherein a weight ratio of the organopolysiloxane (A) to the vinyl acetate (B) is (A):(B)=10:90 to 95:5, a method for producing the same, and a vinyl acetate-silicone copolymer resin composition. The vinyl acetate-silicone copolymer resin of the present invention has slidability, substrate adhesiveness, and organic solvent solubility, and is suitably used for coating agents for various substrates, adhesive agents, exterior and interior paints for structures and building materials and the like, and cosmetics and the like.

A dispersion liquid contains an inorganic oxide particle surface-treated with at least one of a compound represented by Formula Si(R.sup.A1)(X.sup.A1).sub.3 or a compound represented by Formula Si(R.sup.A2)(R.sup.A20)(X.sup.A2).sup.2, polysiloxane having at least one of a T unit represented by Formula [R.sup.B1SiO.sub.3/2] or a D unit represented by Formula [R.sup.B2R.sup.B20SiO], and an organic solvent, where a content of the polysiloxane is 0.5% to 39% by mass with respect to a total amount of the inorganic oxide particle and the polysiloxane, in which in the formula, R.sup.A1, R.sup.A2, R.sup.B1, and R.sup.B2 represent a functional group, X.sup.A1 and X.sup.A2 represent a hydroxyl group or a hydrolyzable group, and R.sup.A20 and R.sup.B20 represent an alkyl group or an aryl group.