Patent classifications
C08F290/04
MEMBER FOR FUEL CELL AND METHOD FOR MANUFACTURING SAME
A member for a fuel cell in which a lip 4b is directly fixed to the surface of a separator 5. In the member for a fuel cell, the lip 4b is a cross-linked body of a radically curable composition containing components (A) to (E) below at a specific ratio, and the glass transition temperature (Tg) of the cross-linked body is −30° C. or less. (A) (Meth)acrylic polymer having a (meth)acryloyl group at a molecular chain end. (B) Monofunctional (meth)acrylic monomer having a glass transition temperature (Tg) of 0° C. or more and having a polycyclic structure. (C) Monofunctional (meth)acrylic monomer except for component (B). (D) Polyfunctional (meth)acrylic monomer. (E) Radical polymerization initiator.
One method of producing polyether polymer dispersant and polyether polymer
The invention discloses one method of producing polyether polymer dispersant and polyether polymer, wherein the dispersant is a copolymer macromolecule prepared by the propylene oxide or ethylene oxide with an average molecular weight of 6000 to 20000, with containing at least one benzene ring group and one polymerizable carbon-carbon double or triple bond polymer. The preparation method of the dispersant is: synthesizing a basic polyether polyol, adding a cyclic dicarboxylic anhydride into the polyether polyol, then the polyether polyol is reacted with an epoxy compound with the polymerizable double bond, and capping with an epoxy compound to obtain the dispersant; preparing the polymer polyol by the basic polyol, an unsaturated vinyl monomer styrene and acrylonitrile, a polymerization initiator, the dispersant and an optional chain transfer agent; the basic polyether is a polyether polyol with a functionality of 3 to 8.
Actinic radiation curable polymeric mixtures, cured polymeric mixtures and related processes
The present disclosure is directed to actinic radiation curable polymeric mixtures, cured polymeric mixtures, tires and tire components made from the foregoing, and related processes.
Photocurable resin composition, fuel cell, and sealing method
The present invention was made in view of the foregoing problem and has an object to provide a photocurable resin composition which can be quickly cured by irradiation with active energy rays such as ultraviolet rays and achieves excellent adhesion to polyolefin such as PP having properties difficult to bond. Specifically, provided is a photocurable resin composition containing the following (A) and (B) ingredients: (A) ingredient: a polymer having a polyisobutylene backbone mainly containing a —[CH.sub.2C(CH.sub.3).sub.2]— unit, the polymer having one or more (meth)acryloyl groups per molecule; and (B) ingredient: a photo-radical initiator of hydrogen abstraction type.
Method for preparing biomass-based conductive hydrogel by 3D printing
A method for preparing a biomass-based conductive hydrogel by 3D printing is provided. Firstly, a cellulose-based macromonomer, a rosin-based monomer, an acrylic acid monomer and an initiator are mixed in a certain proportion, stirred, and dissolved at 25-70° C. Then, diisocyanate in an amount of 5-10 wt % of a total mass of the monomers is added to the mixed solution and mixed uniformly to prepare a 3D printing photosensitive resin solution. An SLA light-curing 3D printer is used to print a hydrogel precursor 1 with a complex shape. Next, the hydrogel precursor 1 is heated to obtain a hydrogel precursor 2 with a dual-curing network. Finally, the obtained hydrogel precursor 2 is swelled in a 1-15 wt % alkaline solution at 5-60° C. for 0.1-10 hours to obtain the biomass-based conductive hydrogel.
Method for preparing biomass-based conductive hydrogel by 3D printing
A method for preparing a biomass-based conductive hydrogel by 3D printing is provided. Firstly, a cellulose-based macromonomer, a rosin-based monomer, an acrylic acid monomer and an initiator are mixed in a certain proportion, stirred, and dissolved at 25-70° C. Then, diisocyanate in an amount of 5-10 wt % of a total mass of the monomers is added to the mixed solution and mixed uniformly to prepare a 3D printing photosensitive resin solution. An SLA light-curing 3D printer is used to print a hydrogel precursor 1 with a complex shape. Next, the hydrogel precursor 1 is heated to obtain a hydrogel precursor 2 with a dual-curing network. Finally, the obtained hydrogel precursor 2 is swelled in a 1-15 wt % alkaline solution at 5-60° C. for 0.1-10 hours to obtain the biomass-based conductive hydrogel.
Polymer and production method thereof, molding material and molded product
A molded product with excellent transparency can be obtained by using a polymer (D) obtained by suspension polymerization of a monomer mixture (1) containing (a) to (c) below: (a) 5-60 mass % of a specific macromonomer; (b) 5-60 mass % of the raw material monomer of a homopolymer (B) that has a solubility parameter that is different by 0.25 or more from the solubility parameter of the macromonomer (a); and (c) 10-80 mass % of the raw material monomer of a homopolymer (C) that has a solubility parameter that is different by less than 0.25 from the solubility parameter of macromonomer (a).
Grafted telechelic polyisobutylenes possessing reactive functionality, processes for preparing the same and curable compositions comprising the same
Disclosed are reactive functionalized, PIB grafted polymers having an architecture of one or more pendent polyisobutylene moieties grafted on to an organic backbone, wherein the backbone is not polyisobutylene and contains at least one telechelic, reactive functionality. Also a process for making the reactive functionalized, PIB grafted polymer s and curable compositions comprising the reactive functionalized, PIB grafted polymers.
Use of comb polymers for reducing fuel consumption
The present invention relates to the use of comb polymers comprising, in the main chain, repeat units which are derived from polyolefin-based macromonomers, and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, where the molar degree of branching is in the range of 0.1 to 10 mol % and the comb polymer comprises a total of at least 80% by weight, based on the weight of the repeat units, of repeat units which are derived from polyolefin-based macromonomers and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, for reducing the fuel consumption of vehicles.
Use of comb polymers for reducing fuel consumption
The present invention relates to the use of comb polymers comprising, in the main chain, repeat units which are derived from polyolefin-based macromonomers, and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, where the molar degree of branching is in the range of 0.1 to 10 mol % and the comb polymer comprises a total of at least 80% by weight, based on the weight of the repeat units, of repeat units which are derived from polyolefin-based macromonomers and repeat units which are derived from low molecular weight monomers selected from the group consisting of styrene monomers having 8 to 17 carbon atoms, alkyl (meth)acrylates having 1 to 10 carbon atoms in the alcohol group, vinyl esters having 1 to 11 carbon atoms in the acyl group, vinyl ethers having 1 to 10 carbon atoms in the alcohol group, (di)alkyl fumarates having 1 to 10 carbon atoms in the alcohol group, (di)alkyl maleates having 1 to 10 carbon atoms in the alcohol group and mixtures of these monomers, for reducing the fuel consumption of vehicles.