Patent classifications
C08F297/04
Block copolymers and polymer modified bitumen therefrom
Disclosed herein are linear block copolymers of formula A-B-A′ or A-B*B-A′, wherein blocks A and A′ are polystyrene blocks, block B is a poly(conjugated diene) block and * is a coupling agent having a vinyl content of from 10-60 mol %. The block copolymers have a polystyrene content of from 20-35 wt. %, relative to the overall weight of the block copolymer, and a molecular weight of from 200,000-300,000 g/mol. The block copolymers can be used with a wide variety of asphalt grades, and are valuable for producing homogeneous polymer modified asphalt compositions having an effective combination of performance properties, such as acceptable viscosity, good elastic response to an applied stress, and a low non-recoverable creep compliance. The combination of vinyl content and polymerization technology allows a high solution concentration during polymerization without excessive processing viscosity.
Binder composition for non-aqueous secondary battery, slurry composition for non-aqueous secondary battery functional layer, functional layer for non-aqueous secondary battery, battery component for non-aqueous secondary battery, and non-aqueous secondary battery
Provided is a binder composition for a non-aqueous secondary battery with which it is possible to form a slurry composition for a non-aqueous secondary battery functional layer having excellent viscosity stability and a functional layer for a non-aqueous secondary battery having excellent pressability. The binder composition for a non-aqueous secondary battery contains water and a particulate polymer formed by a polymer including a block region composed of an aromatic vinyl monomer unit. The particulate polymer has a surface acid content of not less than 0.05 mmol/g and not more than 0.9 mmol/g.
Method for preparing block copolymer composition, and asphalt composition comprising block copolymer composition prepared thereby
A method of preparing a block copolymer composition is provided. The method includes: adding an aromatic vinyl monomer and a compound represented by Chemical Formula 1 to a hydrocarbon-based solvent and performing stirring to prepare a first mixed solution; adding a polymerization initiator to the first mixed solution and performing polymerization to prepare a second mixed solution; adding a conjugated diene-based monomer to the second mixed solution and performing polymerization to prepare a third mixed solution; and adding a coupling agent to the third mixed solution to perform a coupling reaction, An asphalt composition including the block copolymer composition prepared therefrom, is also provided.
WATERPROOFING SHEET FOR CIVIL ENGINEERING USE
To provide a waterproof sheet for civil engineering, having sufficient strength and elongation even at a low temperature of about −10° C. and having excellent adhesiveness to a structure such as a tunnel. Disclosed is a waterproof sheet for civil engineering, which has a layer (A) including a composition containing an ethylene-vinyl acetate copolymer (a1) and a thermoplastic resin (a2) other than the ethylene-vinyl acetate copolymer (a1), and a silica-containing layer containing silica, wherein the content of the ethylene-vinyl acetate copolymer (a1) in the composition is 30 to 95% by mass, the content of the thermoplastic resin (a2) is 5 to 70% by mass, and the absolute value of the difference between the SP value of the ethylene-vinyl acetate copolymer (a1) and the SP value of the thermoplastic resin (a2) is less than 0.70 (cal/cm.sup.3).sup.1/2.
WATERPROOFING SHEET FOR CIVIL ENGINEERING USE
To provide a waterproof sheet for civil engineering, having sufficient strength and elongation even at a low temperature of about −10° C. and having excellent adhesiveness to a structure such as a tunnel. Disclosed is a waterproof sheet for civil engineering, which has a layer (A) including a composition containing an ethylene-vinyl acetate copolymer (a1) and a thermoplastic resin (a2) other than the ethylene-vinyl acetate copolymer (a1), and a silica-containing layer containing silica, wherein the content of the ethylene-vinyl acetate copolymer (a1) in the composition is 30 to 95% by mass, the content of the thermoplastic resin (a2) is 5 to 70% by mass, and the absolute value of the difference between the SP value of the ethylene-vinyl acetate copolymer (a1) and the SP value of the thermoplastic resin (a2) is less than 0.70 (cal/cm.sup.3).sup.1/2.
SULFUR-CONTAINING POLYMERS AND METHODS OF MAKING THE SAME
The present disclosure relates to a composition having a structure defined by
##STR00001##
, where symbolizes a covalent bond to a neighboring atom, R.sub.2 is a functional group derived from at least one of a homocyclic molecule, a heterocyclic molecule, a polycyclic molecule, an aliphatic molecule, and/or an organo-phosphorous molecule, 1 ≤ x ≤ 1000, and 2 ≤ z ≤ 1000.
Sulfonated block copolymers and uses thereof
Disclosed herein is a styrenic block copolymer [A1-B1-C1], consisting essentially of polymer blocks A1, B1 and C1. A1 is a poly(para-alkylstyrene) block having a molecular weight from 1,000 to 60,000 g/mol. B1 is a hydrogenated polyisoprene block or a hydrogenated polybutadiene block having a molecular weight from 1,000 to 100,000 g/mol. C1 is a polystyrene block having a molecular weight from 1,000 to 100,000 g/mol; or a polymer block consisting essentially of polymerized styrene units, and hydrogenated butadiene and/or isoprene units, and having a molecular weight from 1,000 to 100,000 g/mol. Prior to hydrogenation, the block B1 has a vinyl content of 5-75 mol %; and the block C1 forms 1-80 wt % of the overall weight of the block copolymer. The selectively sulfonated forms of the copolymers are useful as high dielectric materials.
Sulfonated block copolymers and uses thereof
Disclosed herein is a styrenic block copolymer [A1-B1-C1], consisting essentially of polymer blocks A1, B1 and C1. A1 is a poly(para-alkylstyrene) block having a molecular weight from 1,000 to 60,000 g/mol. B1 is a hydrogenated polyisoprene block or a hydrogenated polybutadiene block having a molecular weight from 1,000 to 100,000 g/mol. C1 is a polystyrene block having a molecular weight from 1,000 to 100,000 g/mol; or a polymer block consisting essentially of polymerized styrene units, and hydrogenated butadiene and/or isoprene units, and having a molecular weight from 1,000 to 100,000 g/mol. Prior to hydrogenation, the block B1 has a vinyl content of 5-75 mol %; and the block C1 forms 1-80 wt % of the overall weight of the block copolymer. The selectively sulfonated forms of the copolymers are useful as high dielectric materials.
Sulfonated block copolymers and uses thereof
Disclosed herein is a styrenic block copolymer [A1-B1-C1], consisting essentially of polymer blocks A1, B1 and C1. A1 is a poly(para-alkylstyrene) block having a molecular weight from 1,000 to 60,000 g/mol. B1 is a hydrogenated polyisoprene block or a hydrogenated polybutadiene block having a molecular weight from 1,000 to 100,000 g/mol. C1 is a polystyrene block having a molecular weight from 1,000 to 100,000 g/mol; or a polymer block consisting essentially of polymerized styrene units, and hydrogenated butadiene and/or isoprene units, and having a molecular weight from 1,000 to 100,000 g/mol. Prior to hydrogenation, the block B1 has a vinyl content of 5-75 mol %; and the block C1 forms 1-80 wt % of the overall weight of the block copolymer. The selectively sulfonated forms of the copolymers are useful as high dielectric materials.
Multiblock copolymer films, methods of making same, and uses thereof
A method for forming an isoporous graded film comprising multiblock copolymers and isoporous graded films. The films have a surface layer and a bulk layer. The surface layer can have at least 1×10.sup.14 pores/m.sup.2 and a pore size distribution (d.sub.max/d.sub.min)) of less than 3. The bulk layer has an asymmetric structure. The films can be used in filtration applications.