C08F297/08

Olefin-block copolymers and their use in elastomeric articles

An elastomeric article comprising an olefin-block copolymer comprising within a range from 4 to 40 mol % of C4 to C12 -olefin derived units, the remainder being ethylene-derived units, wherein the melting point temperature (T.sub.m2) is within a range from 92 C. to 120 C., and having an M.sub.w/M.sub.n value of less than 2.5. The olefin-block copolymer is desirably generated by combining ethylene, C4 to C12 -olefins, a single site catalyst, preferably a fluxional catalyst, and an activator. The elastomeric article may be an elastic hygiene garment, especially a garment comprising a waistband, stretch ear panels and/or belly bands.

Olefin-block copolymers and their use in elastomeric articles

An elastomeric article comprising an olefin-block copolymer comprising within a range from 4 to 40 mol % of C4 to C12 -olefin derived units, the remainder being ethylene-derived units, wherein the melting point temperature (T.sub.m2) is within a range from 92 C. to 120 C., and having an M.sub.w/M.sub.n value of less than 2.5. The olefin-block copolymer is desirably generated by combining ethylene, C4 to C12 -olefins, a single site catalyst, preferably a fluxional catalyst, and an activator. The elastomeric article may be an elastic hygiene garment, especially a garment comprising a waistband, stretch ear panels and/or belly bands.

POLYPROPYLENE RESIN FOR INSULATING ELECTRIC CABLES
20200339723 · 2020-10-29 ·

An ethylene-propylene block copolymer resin is provided that is suitable as an insulation layer of an electric power cable. The ethylene-propylene block copolymer is obtained by polymerization of a propylene homopolymer or an ethylene-propylene random copolymer with an ethylene-propylene rubber copolymer in stages in reactors in the presence of a Ziegler-Natta catalyst obtained using two internal electron donors, wherein one of the two internal electron donors is a compound comprising an ester group and an alkoxy group, the ethylene-propylene block copolymer has a melting temperature of 150 to 160 C., the content of the solvent extract thereof when extracted at room temperature with xylene is 30 to 50% by weight, and the intrinsic viscosity of the solvent extract is 1.5 to 3.0 dl/g.

Olefin Polymerization Catalyst Component Having Carbonate Compounds
20200316575 · 2020-10-08 ·

The present invention relates to Ziegler-Natta catalyst components for olefin polymerization employing specific carbonate compounds as an element of solid catalyst composition in conjunction with at least one or more internal donor compounds, for producing polyolefins, particularly polypropylene and ethylene-propylene block co-polymer, which exhibits substantially high rubber content with higher stereo-regularity and hydrogen response.

Single Reactor Chain Shuttling Reactions for Ethylene/Vinylarene Multiblock Interpolymers

A process to form a composition comprising an ethylene/vinylarene multiblock interpolymer, said process comprising polymerizing, in a single reactor, a mixture comprising ethylene, a vinylarene, and optionally an alpha-olefin, in the presence of at least the following a)-c): a) a first metal complex selected from the following Formula (A), as described herein: b) a second metal complex selected from the following Formula (B), as described herein, and c) a chain shuttling agent selected from the following: a dialkyl zinc, a trialkyl aluminum, or a combination thereof. A composition comprising an ethylene/vinylarene multiblock interpolymer comprising at least one polymer structure selected from: -(AR)-(AP)-(AR)-(AP)- (Structure 1), or (AR)-(AP)-(AR)-(AP) (Structure 2); where each (AR) segment independently comprises, in polymerized form, ethylene, >10 mol % of the vinylarene and optionally an alpha-olefin, and wherein each (AP) segment independently comprises, ethylene, optionally 10 mol % vinylarene and optionally the alpha-olefin.

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CROSS-LINKED FOAMS MADE FROM INTERPOLYMERS OF ETHYLENE/ALPHA-OLEFINS

Foam compositions comprise at least an ethylene/-olefin interpolymer. The ethylene/-olefin interpolymers of the present disclosure are multi-block copolymers comprising at least one soft block and at least one hard block. The foam compositions can further comprise a blowing agent and a cross-linking agent. Methods of making the foam compositions and foamed articles made from the foam compositions are also described.

MULTI-BLOCK COPOLYMER COMPOSITION OBTAINED BY MODIFICATION TREATMENT, AND FILM

A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as small tension set. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.

MULTI-BLOCK COPOLYMER COMPOSITION OBTAINED BY MODIFICATION TREATMENT, AND FILM

A main purpose of the present invention is to provide a multi-block copolymer composition having good elasticity and excellent stress relaxation properties, as well as small tension set. The present invention achieves the purpose by providing a multi-block copolymer composition obtained by a modification treatment, the composition including a block copolymer B formed by introducing a functional group capable of forming a non-covalent bond to a block copolymer A; wherein the block copolymer A includes a block copolymer A1 having a specific primary structure and a block copolymer A2 having a specific primary structure, and the mass ratio (A1/A2) of the block copolymer A1 and the block copolymer A2 is 100/0 to 50/50.

CATALYST SYSTEM FOR MULTI-BLOCK COPOLYMER FORMATION

The present disclosure relates to a catalyst system for use in forming a multi-block copolymer, said copolymer containing therein two or more segments or blocks differing in chemical or physical properties, a polymerization process using the same, and the resulting polymers, wherein the composition comprises the admixture or reaction product resulting from combining: (A) a first olefin polymerization procatalyst, (B) a second olefin polymerization procatalyst capable of preparing polymers differing in chemical or physical properties from the polymer prepared by procatalyst (A) under equivalent polymerization conditions, and (C) a chain shuttling agent.

High-performance tyre

A (iso-styrene/trans-butadiene): diene-terminated copolymer is described which includes (i) a polymeric block of styrene-butadiene consisting of a random sequence of butadiene in trans conformation and styrene in isotactic configuration, and (ii) a terminal polymeric block consisting of a sequence of one or more dienic monomers.