Provided is a siloxane resin composition having excellent adhesion and fine patterning properties. The siloxane resin composition contains: a siloxane resin (A) including a structure represented by general formula (1), a structure represented by general formula (2), and a structure represented by general formula (3); a compound (B) having an unsaturated double bond; a photopolymerization initiator (C); and a solvent (D).

Novel compositions and systems for closure of wounds are disclosed. The compositions provide devices of improved flexibility and elasticity and are readily applied to wound sites or over wound closure devices. The present invention is also directed to a novel platinum catalyst for use in such compositions. The catalyst provides for rapid curing on topical surfaces such as skin and bonds to such surfaces in about 2-5 minutes.

The purpose of the present invention is to provide a weather-resistant hard coat composition for a glass-substitute substrate capable of efficiently forming a coating film excelling in weather resistance, scratch resistance, and toughness. The present invention provides: a weather-resistant hard coat composition for a glass-substitute substrate, the composition containing a polyorganosilsesquioxane having a constituent unit represented by Formula (1); a cured product thereof; and a laminate having a glass-substitute substrate and a coating film formed on at least one surface of the glass-substitute substrate. The coating film is a layer of a cured product of the weather-resistant hard coat composition for a glass-substitute substrate. [In formula (1), R.sup.1 represents a group containing an active energy ray-curable functional group.]

The purpose of the present invention is to provide a weather-resistant hard coat composition for a metal, the composition being capable of efficiently forming a coating film excelling in weather resistance, scratch resistance, and flexibility. The present invention provides: a weather-resistant hard coat composition for a metal, the composition containing a polyorganosilsesquioxane having a constituent unit represented by Formula (1); a cured product thereof; and a coated metal substrate having a metal substrate and a coating film formed on at least one surface of the metal substrate. The coating film is a layer of a cured product of the weather-resistant hard coat composition for a metal. [In Formula (1), R.sup.1 represents a group containing an active energy ray-curable functional group.]

[R.sup.1SiO.sub.3/2]  (1)

An ultraviolet curable organopolysiloxane composition which contains: (A) a linear or branched organopolysiloxane which contains, as monovalent substituents bonded to a silicon atom at an end of the molecular chain, at least three groups represented by formula (1) and/or formula (2) in each molecule, while having the main chain composed of repeated diorganosiloxane units ##STR00001##
(in the formulae, a represents a number of 1-3; and the broken line represents a bonding hand); (B) a linear or branched organopolysiloxane which contains at least two groups represented by formula (3) in each molecule, while having the main chain composed of repeated diorganosiloxane units
R.sup.1.sub.bR.sup.2.sub.3-bSi  (3)
(in the formula, R.sup.1 represents an alkenyl group; R.sup.2 represents a monovalent hydrocarbon group; and b represents a number of 1-3); and (C) a photoinitiator. With use of this ultraviolet curable organopolysiloxane composition, the hardness of a cured product obtained therefrom is easily controlled, and good surface curability and good curability in deep portions are achieved even in the presence of oxygen. Consequently, this ultraviolet curable organopolysiloxane composition enables the achievement of a silicone gel (a gel-like cured product) which has been cured at a substantially uniform crosslinking density (with a substantially uniform penetration) without depending on the irradiance of ultraviolet light (the amount of irradiation energy).

An ultraviolet curable organopolysiloxane composition which contains: (A) a linear or branched organopolysiloxane which contains, as monovalent substituents bonded to a silicon atom at an end of the molecular chain, at least three groups represented by formula (1) and/or formula (2) in each molecule, while having the main chain composed of repeated diorganosiloxane units ##STR00001##
(in the formulae, a represents a number of 1-3; and the broken line represents a bonding hand); (B) a linear or branched organopolysiloxane which contains at least two groups represented by formula (3) in each molecule, while having the main chain composed of repeated diorganosiloxane units
R.sup.1.sub.bR.sup.2.sub.3-bSi  (3)
(in the formula, R.sup.1 represents an alkenyl group; R.sup.2 represents a monovalent hydrocarbon group; and b represents a number of 1-3); and (C) a photoinitiator. With use of this ultraviolet curable organopolysiloxane composition, the hardness of a cured product obtained therefrom is easily controlled, and good surface curability and good curability in deep portions are achieved even in the presence of oxygen. Consequently, this ultraviolet curable organopolysiloxane composition enables the achievement of a silicone gel (a gel-like cured product) which has been cured at a substantially uniform crosslinking density (with a substantially uniform penetration) without depending on the irradiance of ultraviolet light (the amount of irradiation energy).

An object of the present invention is to provide an imprinting curable composition which includes a silicon-containing polymerizable compound such as polysiloxane, exhibits outstanding adhesion to a substrate and excellent demoldability from a fine pattern mold, and causes very little mold contamination. The object is attained by providing a photo-imprinting curable composition including a polymerizable compound (A) containing a silicon atom in the molecule, a photopolymerization initiator (B) and an additive (C), the additive (C) being a compound represented by the following formula (C1) or (C2):
R.sup.1OC.sub.2H.sub.4O.sub.nX.sup.1  (C1)
X.sup.2OC.sub.2H.sub.4O.sub.pC.sub.3H.sub.6O.sub.qC.sub.2H.sub.4O.sub.rX.s

An object of the present invention is to provide an imprinting curable composition which includes a silicon-containing polymerizable compound such as polysiloxane, exhibits outstanding adhesion to a substrate and excellent demoldability from a fine pattern mold, and causes very little mold contamination. The object is attained by providing a photo-imprinting curable composition including a polymerizable compound (A) containing a silicon atom in the molecule, a photopolymerization initiator (B) and an additive (C), the additive (C) being a compound represented by the following formula (C1) or (C2):
R.sup.1OC.sub.2H.sub.4O.sub.nX.sup.1  (C1)
X.sup.2OC.sub.2H.sub.4O.sub.pC.sub.3H.sub.6O.sub.qC.sub.2H.sub.4O.sub.rX.s

A reactive silicone composition including component (S) and component (T) below, the component (S): a reactive silicone compound including a condensation product of a diaryl silicate compound represented by Formula [1] and a silicon compound represented by Formula [2],

##STR00001##

(wherein Ar.sup.1 and Ar.sup.2 each independently represent a phenyl group optionally substituted by a C.sub.1-6 alkyl group and X represents a hydrolyzable reactive group), the component (T): modified titanium oxide-containing oxide colloidal particles produced by bonding an organosilicon compound to surfaces of titanium oxide-containing oxide colloidal particles (C) having an average particle diameter of from 2 to 100 nm and including, as a core, titanium oxide-containing metal oxide colloidal particles (A), surfaces of which are coated with a coating including silicon dioxide- and tin oxide-containing composite oxide colloidal particles (B).

Provided is a polymer functioning as a leveling agent that imparts high smoothness to a coating film without causing a defect on the surface of the coating film. Specifically, a silicone chain-containing polymer having a silicone chain on one terminal, in which the silicone chain has a number average molecular weight in a range of 2000 to 20000, and a polymerizable unsaturated group is not contained.