The present invention relates to a method for preparing a hollow covalent organic framework (COF) material and hollow COF material prepared by said method. Said method is characterized in including a monomer displacement step in the method, thereby obtaining the hollow COF material with a controllable particle size, wall thickness and/or specific surface area.

The present invention relates to a method for preparing a hollow covalent organic framework (COF) material and hollow COF material prepared by said method. Said method is characterized in including a monomer displacement step in the method, thereby obtaining the hollow COF material with a controllable particle size, wall thickness and/or specific surface area.

A temperature-curable aminoplastic adhesive resin that is a (poly)-condensate of: (i) at least one aminoplast-forming chemical; (ii) 5-hydroxymethylfurfural (5-HMF), its oligomers and/or its isomers; and, (iii) at the least one second (poly-)condensable chemical. Composite boards, such as wood-based panels, can be produced using this adhesive resin. The production of the aminoplastic adhesive resin includes the reaction of urea with 5-hydroxymethylfurfural (5-HMF) and glyoxal. The adhesive resin can be used in the production of wood-based panels such as particleboards, fiberboards and products usually called, among others, plywood and/or blockboards.

A highly branched polymer comprising repeating units which each have an acid group such as sulfo group, said repeating units being represented by formula [1] or the like, and a dispersant for carbon nanotubes (CNTs) which comprises the highly branched polymer can disperse CNTs in a medium such as an organic solvent to the individual sizes and can yield thin films having improved conductivity. ##STR00001##
In formula [1], any one of A.sup.1 to A.sup.5 is a sulfo group, and the others are each a hydrogen atom.

A highly branched polymer comprising repeating units which each have an acid group such as sulfo group, said repeating units being represented by formula [1] or the like, and a dispersant for carbon nanotubes (CNTs) which comprises the highly branched polymer can disperse CNTs in a medium such as an organic solvent to the individual sizes and can yield thin films having improved conductivity. ##STR00001##
In formula [1], any one of A.sup.1 to A.sup.5 is a sulfo group, and the others are each a hydrogen atom.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (IV) wherein each instance of R.sup.9 is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (IV) is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, and aryl. Each instance of R.sup.33 of Formula (IV) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (IV) is independently NH or a bond and each instance of R.sup.40 is independently NH or NHNH. Each instance of R.sup.42 of Formula (IV) is independently NH or a bond and each instance of R.sup.43 is independently NH or NHNH.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (IV) wherein each instance of R.sup.9 is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heteroaryl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (IV) is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, and aryl. Each instance of R.sup.33 of Formula (IV) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (IV) is independently NH or a bond and each instance of R.sup.40 is independently NH or NHNH. Each instance of R.sup.42 of Formula (IV) is independently NH or a bond and each instance of R.sup.43 is independently NH or NHNH.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.10, R.sup.11, R.sup.12, R.sup.13, and R.sup.14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R.sup.9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R.sup.33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (I) is independently NH or a bond and each instance of R.sup.40 is independently NH or NHNH.

Aspects of the present disclosure relate to Schiff base oligomers and uses thereof. In at least one aspect, an oligomer is represented by Formula (I) wherein each instance of R.sup.4, R.sup.5, R.sup.6, R.sup.7, R.sup.8, R.sup.10, R.sup.11, R.sup.12, R.sup.13, and R.sup.14 is independently selected from the group consisting of hydrogen, alkyl, cycloalkyl, alkoxyl, aryloxyl, ether, and heterocyclyl. Each instance of R.sup.9 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and ether. Each instance of R.sup.28 and R.sup.29 of Formula (I) is independently selected from the group consisting of hydrogen, alkyl, and aryl. Each instance of R.sup.33 of Formula (I) is independently selected from the group consisting of alkyl, cycloalkyl, aryl, heterocyclyl, and a bond. Each instance of R.sup.41 of Formula (I) is independently NH or a bond and each instance of R.sup.40 is independently NH or NHNH.

A method for preparing a semi-rigid melamine foam plastic, comprising Step (1): adding a formaldehyde solution and polyvinyl alcohol (PVA) to a reactor, heating the reactor, and adding alkali; Step (2): feeding solid melamine powder and a modifier 3-aminopropyltriethoxysilane (APTES) into the reactor, raising the temperature in the reactor to 75-85? C., adjusting the pH value of the solution of material by adding acid; heating the solution of material, performing a heat preservation reaction, and then adding alkali, Step (3): feeding a predetermined amount of foaming agent, emulsifier, auxiliary agent and curing agent into a stirring reactor to obtain a mixed auxiliary agent; pumping the mixed auxiliary agent and the semi-rigid modified melamine resin into an emulsifier; placing the emulsified resin into a microwave heating chamber for microwave foaming; Step (4): cutting the semi-rigid melamine foam plastic obtained in step (3) and then drying.