The present invention relates to a one-component system comprising a) at least one polyurethane prepolymer based on at least one di- and/or polyisocyanate and at least one di- and/or polyol, wherein at least one di- or polyol is a polyalkylene glycol having a number-average molecular weight of 900 to 2150 g/mol, wherein all unconverted isocyanate groups are blocked with at least one malonic ester and b) at least one di and/or polyamine;
to a process for its production, to its use and to processes employing it for producing artificial leather and (artificial) leather coatings.

Disclosed herein are polyurethane compositions and methods for reprocessing cross-linked polyurethane compositions. The polyurethane composition comprises a network polymer and a poluyurethane exchange catalyst permeated within the network polymer. The network polymer comprises a dynamic network formed from an isocyanate constitutional unit and a second constitution unit having a hydroxyl group capable of reacting with an isocyanate group of the isocyanate constitutional unit to form a urethane bond. The catalyst comprises a metal atom and a ligand coordinated to the metal atom.

Disclosed herein are polyurethane compositions and methods for reprocessing cross-linked polyurethane compositions. The polyurethane composition comprises a network polymer and a poluyurethane exchange catalyst permeated within the network polymer. The network polymer comprises a dynamic network formed from an isocyanate constitutional unit and a second constitution unit having a hydroxyl group capable of reacting with an isocyanate group of the isocyanate constitutional unit to form a urethane bond. The catalyst comprises a metal atom and a ligand coordinated to the metal atom.

A method for producing a polyurethane resin includes a reaction step of obtaining a primary product by reacting a polyisocyanate component containing a bis(isocyanatomethyl)cyclohexane with a polyol component containing a low molecular weight polyol having a number average molecular weight of 400 or less and a high molecular weight polyol having an average molecular weight of 2500 or more and 4000 or less under the presence of a bismuth catalyst, and a heat treatment step of heat treating the primary product to obtain a polyurethane resin. The bismuth catalyst content in the polyurethane resin is 0.1 ppm or more and 1000 ppm or less, and the heat treatment conditions in the heat treatment step are 50 C. or more and 100 C. or less and three days or more and ten days or less.

A method for producing a polyurethane resin includes a reaction step of obtaining a primary product by reacting a polyisocyanate component containing a bis(isocyanatomethyl)cyclohexane with a polyol component containing a low molecular weight polyol having a number average molecular weight of 400 or less and a high molecular weight polyol having an average molecular weight of 2500 or more and 4000 or less under the presence of a bismuth catalyst, and a heat treatment step of heat treating the primary product to obtain a polyurethane resin. The bismuth catalyst content in the polyurethane resin is 0.1 ppm or more and 1000 ppm or less, and the heat treatment conditions in the heat treatment step are 50 C. or more and 100 C. or less and three days or more and ten days or less.

The present invention addresses the problem of providing a surface protection film having superior oil resistance. Provided is a surface protection film having a coating layer obtained by curing an isocyanate compound, on one surface of a protection layer formed of a polyurethane.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

A process of: providing a polyfunctional compound selected from polyisocyanate, polyacrylate, and polyepoxy; and reacting the polyfunctional compound with a hydroxyl- or amine-terminated silyl-containing compound. The polyfunctional compound and the silyl-containing compound are at least difunctional. A thermoset made by this process.

The present invention relates to a process for removing ketazine from polyurethane dispersions by means of distillation below the boiling point of ketazine.

The present invention relates to a process for removing ketazine from polyurethane dispersions by means of distillation below the boiling point of ketazine.