Disclosed herein are methods and formulations for the microencapsulation of aminosiloxanes, for example for use as an additive in protective material formulations such as those used in the protection and/or joining of metal substrates. The additives may be used in conjunction with a second reactant that may or may not be similarly microencapsulated for self-healing (and associated corrosion resistance) or delayed cure applications, or they may be used alone or in conjunction with other corrosion inhibitors for protective formulations with improved corrosion resistance on appropriate substrates.

Photo-protected microcapsules containing a photopolymer composition are dispersed in an epoxy coating to form an autonomic self-healing material. The capsule shell wall is formulated to protect the photopolymer composition from electromagnetic radiation exposure prior to rupture of the capsule shell, so that the photopolymer composition (e.g., a UV curable epoxy resin) remains active until triggered by damage to the capsule shell. Carbon black pigment is a suitable UV protector for the capsules. Upon sufficient damage to a region of the coating, the capsules will rupture and the photopolymer composition will fill and cure in and/or around the damaged region in the presence of electromagnetic radiation, achieving autonomic healing of the damaged coating.

Curable compositions containing thiol-terminated polythioethers and encapsulated polyepoxy curing agents are disclosed. The compositions exhibit extended pot life.

Nanocomposite microcapsules for self-healing of composites. The nanocomposite microcapsules comprise a urea-formaldehyde shell encompassing a liquid core of polymerizable healing agent. The microcapsules further comprise nanoparticulates encompassed in the core and also present on the outer surface of the microcapsule shell. Self-healing composites with the nanocomposite microcapsules embedded in the composite polymer matrix are also described. Methods of making and using the same are also disclosed.

The present invention provides a method with which curing can be carried out in a short time without a heat load on an adherend and a cured product having stable quality can be obtained. The resin composition curing method in accordance with the present invention includes the step (a) of directly and/or indirectly irradiating, with laser light, a resin composition (A) which contains (i) an epoxy resin, (ii) an encapsulated curing agent including a core that contains a curing agent and a shell that covers the core, (iii) a filler, and (iv) a color material.

The present invention provides a resin composition which can be cured in a short time without a heat load on an adherend and with which a cured product having stable quality can be obtained. The resin composition in accordance with the present invention contains (i) a bisphenol A epoxy resin, (ii) an encapsulated curing agent including a core that contains a curing agent and a shell that covers the core, (iii) a filler, and (iv) a color material.

Methods and compositions, and components comprising the compositions, are disclosed relating to improved resin-based adhesives comprising encapsulating at least a catalyst compound. Further methods and compositions are disclosed relating to encapsulated catalysts in uncured resin-based adhesives, said encapsulated catalysts configured to release the catalyst compound and cure the uncured resin-based adhesive on-demand.

Disclosed is a sealant composition. The sealant composition is composed of an epoxy resin having an active group, -cyanoacrylate, an initiator wrapped with an inert sheathing material, a thermal curing agent, a filler, a coupling agent and an epoxy resin having no active groups. In the invention, a method for initiating sealant curing via a chemical initiator is employed, thus the UV irradiation process may be avoided, the cell alignment process may be simplified, and the cost of UV process and UV Mask, etc., may be saved; additionally, the sealant cure effect is uniform and controllable, and the risk of sealant break and liquid crystal pollution may be avoided.

The present invention is directed to a curable composition including: an isocyanate-functional prepolymer; an epoxy-containing component present in an amount of at least 10 percent by weight of the composition; and a latent curing agent having an ability to react with at least one of the isocyanate-functional prepolymer and the epoxy-containing component upon exposure to an external energy source. The present invention is also directed to methods of making the compositions, methods of coating a substrate, methods of adhering substrates and coated substrates.