A water dispersible sulfopolymer for use as a material in the layer-wise additive manufacture of a 3D part made of a non water dispersible polymer wherein the water dispersible polymer is a reaction product of a metal sulfo monomer, the water dispersible sulfo-polymer being dispersible in water resulting in separation of the water dispersible polymer from the 3D part made of the non water dispersible polymer.

The subject matter described herein relates to methods for polymer xanthylation and the xanthylated polymers produced by such methods. Subsequent replacement of the xanthylate moiety allows facile entry into functionalized polymers.

The invention relates to a polyester film provided with a coating at least on one side, wherein the coating is the drying product of an aqueous dispersion, the composition of which comprises not only water but also at least one copolyester component and one silane component, where the copolyester component is formed to an extent of 3 to 35 mol % of a monomer unit bearing sulfonate groups, and is present in the dried coating in a proportion of 40-85% by weight, and the silane component bears vinyl groups or methacryloyl groups, and also alkoxy groups, and is present in the dried coating to an extent of 15-60% by weight. The invention further relates to a process for production thereof and to the use thereof.

A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following:

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The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.

A reaction system for forming a step-growth polymerized sulfur-containing polyester polyol includes at least one sulfur-containing component selected from the group of a sulfur-containing polyol or a sulfur-containing polycarboxylic acid, an amount of the at least one sulfur-containing component being from 1 wt % to 60 wt %, at least one aromatic component selected from the group of an aromatic multi-functional ester, an aromatic multi-functional carboxylic acid, and an aromatic anhydride, an amount of the at least one aromatic component being from 1 wt % to 60 wt %, at least one simple polyol that excludes sulfur and is different from the sulfur containing polyol, an amount of the at least one simple polyol being from 0 wt % to 60 wt %, and at least one polymerization catalyst. The reaction system for forming the sulfur-containing polyester polyol has a sulfur content that is from 2 wt % to 20 wt %.

A series of materials that exhibit a range of dilatant properties have been synthesized. The materials show good transparency and are chemically uniform, that is, they consist of a single chemical component. The dilatant properties likely are due to the presence of both aggregated and non-aggregated forms of the oligomers. The degree of dilatancy can be modified by adjusting the monomer composition. The range of dilatant properties, good transparency, and single chemical component nature of the dilatant samples make these materials of particular interest.

There is described an acrylic polyester resin, obtainable by grafting an acrylic polymer with a polyester material. The polyester material is obtainable by polymerizing (i) a polyacid component, with (ii) a polyol component, including a diol according to formula (I), as shown in claim 1; wherein R?1#191 and R?2#191 each independently represent a hydrogen radical, a lower alkyl radical or an aryl radical having 6 to 12 carbon atoms, and wherein at least one of R?1#191 or R?2#191 is a lower alkyl radical or an aryl radical having 6 to 12 carbon atoms. R?3#191 and R?4#191 each independently represent a lower alkyl radical or an aryl radical having 6 to 12 carbon atoms. At least one of the polyacid component and/or the polyol component comprises a functional monomer operable to impart functionality on to the polyester resin, such that an acrylic polymer may be grafted with the polyester material via the use of said functionality. Also provided is an aqueous coating composition comprising the acrylic polyester resin and a metal packaging containing coated with the composition.

Disclosed are compositions comprising polymeric nanoparticles and methods of using the same. The polymeric nanoparticles can be conjugated with a targeting ligand that is a substrate for a solid tumor-specific cell protein. The polymeric nanoparticles can also comprises an imaging compound and/or a therapeutic agent encapsulated in the hydrophobic interior of the nanoparticle. A cancer therapeutic composition comprising the nanoparticle is also disclosed. The disclosed nanoparticles can be used to target and deliver imaging and/or therapeutic compounds to cancer cells, thereby identifying and/or treating a solid tumor cell target. Methods for treating cancer, such as lung cancer, using the polymeric nanoparticles are also disclosed.

The invention relates to an oxidizing, ionic and short oil alkyd resin. The invention further relates to various compositions comprising the oxidizing, ionic and short oil alkyd resin, cured compositions derived upon curing of said compositions, objects comprising the various cured or uncured compositions as well as various uses of the oxidizing, ionic and short oil alkyd resin, and of the various compositions of the invention as well as of the various objects of the invention.

Method for obtaining biodegradable polyesteretheramide that has a stage of esterification and/or transesterification and amidation reaction, a stage of prepolycondensation, a stage of polycondensation, an optional stage of extraction, a stage of drying and a final stage of extrusion with additives. The method of obtaining PEEA enables better satisfaction of the needs of each client as regards viscosity, composition and additives. It enables reducing the amount of interface product that has lower commercial value and improves the colour of the product, while at the same time provides a more efficient process, ecologically cleaner and safer for all the operatives.