An unsaturated polycarbonate has the structure: ##STR00001## wherein X and Y are each an OH group; a transition metal and an OH group; an OH group and a COOH group; or one or both of X and Y is independently —NH2, —SH, C═C, N3, C—C triple bond, C═C, an o-tosylate, or a halogen; m is 0 to 30,000 and n is 1 to 30,000, and (m+n) is 2 or greater; R.sup.1 is a C.sub.3-C.sub.20 group chosen from particular groups; R.sup.2 is H or a second similar C.sub.3-C.sub.20 group, and R.sup.3 is optionally a third C.sub.3-C.sub.20 group having one or more C═C terminal and/or internal double bonds; and R.sup.4 is optionally H or a fourth similar C.sub.3-C.sub.20 group optionally having one or more C═C terminal and/or internal double bonds; or R.sup.3 and R.sup.4 form a ring structure having one or more C═C double bonds and having 4 to 20 carbon atoms.

The present invention is directed to a polymerizable composition comprising (A) a reaction product of: (a) diethyleneglycol bischloroformate, ethyleneglycol bischloroformate, or combinations thereof; (b) allyl alcohol; (c) optionally, a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups; and (B) an organic peroxide comprising at least three peroxide groups. A polymerizate and/or an optical article comprising the polymerizable compositions of the invention are also provided.

A method for preparing polyoxyalkylene monomers, comprising the step of the reaction of one or more H-functional starter substance(s), one or more alkylene oxides and carbon dioxide in the presence of a DMC catalyst is characterized in that at least one of the H-functional starter substance(s) comprises a carbon-carbon double bond, wherein the carbon-carbon double bond is part of a cyclic structure. The macromonomers obtained can be used in a method for preparing polyoxyalkylene brush polymers, wherein this method comprises the step of the reaction with an olefin metathesis catalyst. The polyoxyalkylene brush polymers obtained may subsequently be crosslinked.

An exemplary polymerizable thermosetting composition includes the reaction product of (a) allyl alcohol; (b) a cyclic polyol selected from the group consisting of a cycloaliphatic polyol having at least one secondary hydroxyl group, a heterocyclic polyol having primary and/or secondary hydroxyl groups, and mixtures thereof; (c) ethyleneglycol bischloroformate; and (d) optionally, at least one linear or branched aliphatic polyol having two to six hydroxyl groups. The allyl alcohol (a) is present in an amount of 0.4 to 1.99 equivalents of OH to 1 equivalent chloroformate, and the cyclic polyol (b) is present in an amount of 0.01 to 0.6 equivalents of OH to 1 equivalent of chloroformate. A reaction product, a polymerizate including the polymerizable thermosetting composition, and an optical article including the polymerizable thermosetting composition are also provided.

A polycarbonate polyfunctional-vinyl ether molecule of formula (I):

##STR00001##

The present technology provides a heteroatom-containing polycarbonate polyfunctional-vinyl ether molecule of formula (I) and processes of preparing thereof. The present technology further provides a heteroatom-containing acrylate molecule of formula (II). An ink or coating formulation including an energy curable high reactivity heteroatom-containing polycarbonate polyfunctional-vinyl ether molecule of formula (I) or an energy curable high reactivity heteroatom-containing acrylate molecule of formula (II) is provided. ##STR00001##

A resin composition, the resin composition comprising a prepolymer (209) and optionally one or more diluent(s) (FIG. 3A), the prepolymer (209) comprising repeating units having at least one carbonate linkage and at least one unsaturated side-chain, the at least one optional diluent(s) comprising at least one unsaturated side-chain, wherein either or both of the prepolymer (209) and the at least one optional diluent(s) comprises at least one OCN linkage, preferably a urethane linkage.

The present invention relates to a double metal cyanide catalyst comprising a polyether compound, a metal salt, a metal cyanide salt, and an organic complexing agent having an acetate group or a tartrate group; a preparation method therefor; and a method for preparing a polycarbonate polyether polyol by copolymerizing carbon dioxide and an epoxy compound in the presence of the catalyst. According to the present invention, the double metal cyanide catalyst has excellent in catalytic activity and has a short catalytic activity induction time, according to an embodiment of the present invention, the process for preparing the catalyst of the present invention is eco-friendly and simple in process, since an amount of the organic complexing agent to be used is small, and has a simple process.

The present invention relates to the use of one or more specific organic peroxides for the polymerization of an allylic monomer and/or at least one allylic copolymer.

The invention also relates to a composition comprising at least one allylic monomer and/or at least one allylic copolymer and at least one specific organic peroxide.

The invention also relates to the use of the composition as defined above for the manufacture of an organic glass, preferably an ophthalmic lens, possibly optionally being tinted by means of pigments and/or organic dyes.

In one aspect, the present invention encompasses compositions of sustainable polycarbonate polymers, methods of producing such polymers, and methods for evaluating whether certain constituents of a polymer chain are derived from biomass or a fossil carbon source.