This disclosure provides a composition comprising a mixture of molecules of Formula (I): {RO—[CH(CH.sub.3)CH.sub.2O)].sub.b[CH.sub.2—CH.sub.2O].sub.a}.sub.mP(═O)(O.sup.−X.sup.+).sub.n (I), wherein R is chosen from linear or branched C.sub.10-C.sub.18 alkyl or alkenyl groups; a is 0 to 50, b is 0-30, and a+b>0; X.sup.+ is potassium, triethanolamine, or H, and m and n are each equal to 1 or 2, such that when m=1 then n=2, and when m=2 then n=1. Moreover, in the mixture some of the molecules have m=1 and n=2 and some of the molecules have m=2 and n=1, wherein the mole ratio of compounds where m=1 to compounds where m=2 is of from 1:1 to 3:1.

This disclosure provides a composition comprising a mixture of molecules of Formula (I): {RO—[CH(CH.sub.3)CH.sub.2O)].sub.b[CH.sub.2—CH.sub.2O].sub.a}.sub.mP(═O)(O.sup.−X.sup.+).sub.n (I), wherein R is chosen from linear or branched C.sub.10-C.sub.18 alkyl or alkenyl groups; a is 0 to 50, b is 0-30, and a+b>0; X.sup.+ is potassium, triethanolamine, or H, and m and n are each equal to 1 or 2, such that when m=1 then n=2, and when m=2 then n=1. Moreover, in the mixture some of the molecules have m=1 and n=2 and some of the molecules have m=2 and n=1, wherein the mole ratio of compounds where m=1 to compounds where m=2 is of from 1:1 to 3:1.

A method for the synthesis of a substituted poly(alkylene oxide) comprises reacting a substituted alcohol of formula (1) with an alkylene oxide of formula (2) in the presence of a catalyst and under conditions effective to provide the substituted poly(alkylene oxide) of formula (3) wherein in the foregoing formulas, each R is independently hydrogen, C.sub.1-60 alkyl, or C.sub.3-12 cycloalkyl, ring A is cyclohexane or phenyl, each R.sup.1 is independently hydrogen, methyl, ethyl, propyl, butyl, hexyl, decyl, dodecyl, tetradecyl, or hexadecyl, preferably hydrogen or methyl, and n is 2 to 60.

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A composition comprising: a bulk material; and at least one surface; the bulk material comprising ions of a metal M bonded to one another via linker groups; the surface comprising ions of a metal M′ bonded to one another via linker groups; the metals M and M′ being the same or different; the surface comprising at least one first site A and at least one second, different site B; the site A having a hydroxyl group bonded thereto; the site B being a Lewis acidic site; is described. Methods of forming the composition and the use of the composition as a catalyst, in particular to catalyse reactions in which CO.sub.2 is incorporated into the structure of a molecule, in particular a polymer, are also described.

The invention relates to a process for starting up a reactor for the continuous production process of polyether carbonate polyols by the addition of alkylene oxide and carbon dioxide in the presence of a DMC catalyst and/or a metal complex catalyst based on the metals cobalt and/or zinc to an H-functional starter substance, in which process: (α) a portion of the H-functional starter substance and/or a suspension medium which has no H-functional groups is mixed in a reactor with a DMC catalyst and/or a metal complex catalyst, the DMC catalyst and/or the metal complex catalyst having a concentration s in the mixture; and (γ), after step (α), the H-functional starter substance, alkylene oxide and DMC catalyst and/or a metal complex catalyst are continuously fed into the reactor during the addition process and the resulting reaction mixture is removed from the reactor, and a steady state is achieved.

A method for producing an ether esterol, preferably a polyether esterol, is provided. The method comprises reacting an H-functional starter substance (1) with a cyclic anhydride (2) in the presence of a catalyst (4), wherein the cyclic anhydride (2) contains a specific alkylsuccinic acid anhydride (2-1) and the catalyst (4) is an amine, a double metal cyanide (DMC) catalyst and/or a Bronsted acid. Ether esterols, preferably polyether esterols obtainable using the claimed method are also provided..

Processes for preparing a polymer polyol (PMPO) in which a base polyol is continuously produced in a continuous base polyol reactor, the base polyol is continuously discharged from the continuous base polyol reactor; the base polyol is continuously introduced to a continuous PMPO reactor, which is different from the continuous base polyol reactor, and PMPO is continuously removed from the PMPO reactor. Production plant configured to carry out such processes are also described.

The invention relates to vicinal diol ether derivatives of certain polyether polymers, compositions comprising the same, and methods of making the same via reaction with substituted or unsubstituted epoxides, and methods of using the same.

A polyrotaxane of high heat resistance contains a linear molecule, a cyclic molecule enclosing the linear molecule such that the cyclic molecule is skewered with the linear molecule, and 5 blocking groups disposed at both ends of the linear molecule. The cyclic molecule contains an aromatic ring having, on a side chain, a phenolic hydroxyl group. The polyrotaxane can be produced by dissolving, in a methanol-containing solvent, a linear molecule and a cyclic 10 molecule containing an aromatic ring having, on a side chain, a phenolic hydroxyl group, to yield a pseudo polyrotaxane in which the cyclic molecule encloses the linear molecule such that the cyclic molecule is skewered with the linear molecule; and dissolving the pseudo polyrotaxane and a blocking group 15 material in a solvent, to dispose blocking groups at both ends of the linear molecule.

This invention provides a polymer, which is preferably a polyether polymer. The polymer may be used in coating compositions. Containers and other articles comprising the polymer and methods of making such containers and other articles are also provided. The invention further provides compositions including the polymer (e.g., powder coatings), which have utility in a variety of coating end uses, including, for example, valve and pipe coatings.