The present invention relates to a process for preparing a polyaryl ether by reacting components (a1) and (a2) in the presence of a carbonate compound (C) to obtain a salt-containing polymer (SP) comprising the polyaryl ether and a salt (S). After the reaction, the salt (S) is extracted from the salt-containing polymer (SP) to obtain a desalinated polymer (DP) comprising the polyaryl ether.

Provided is a method that can stably produce polyaryletherketone that has a high degree of polymerization and can be easily recovered. The method for producing polyaryletherketone includes: a polycondensation step of carrying out desalting polycondensation in a reaction solvent; and a cooling step of cooling a reaction mixture after desalting polycondensation is completed. When the method is implemented, the polycondensation step is carried out in a hydrophilic solvent under pressurized conditions, and the polymerization temperature in the polycondensation step is at or above the boiling point of the hydrophilic solvent at ambient pressure. In addition, the polymer content in terms of monomers at the time of cooling in the cooling step is from 1 part by mass to 50 parts by mass, per 100 parts by mass of the hydrophilic solvent in the reaction mixture.

Provided is a method that can stably produce polyaryletherketone that has a high degree of polymerization and can be easily recovered. The method for producing polyaryletherketone includes: a polycondensation step of carrying out desalting polycondensation in a reaction solvent; and a cooling step of cooling a reaction mixture after desalting polycondensation is completed. When the method is implemented, the polycondensation step is carried out in a hydrophilic solvent under pressurized conditions, and the polymerization temperature in the polycondensation step is at or above the boiling point of the hydrophilic solvent at ambient pressure. In addition, the polymer content in terms of monomers at the time of cooling in the cooling step is from 1 part by mass to 50 parts by mass, per 100 parts by mass of the hydrophilic solvent in the reaction mixture.

Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

Process for densification of a poly(arylene ether ketone) (PAEK) powder or of a mixture of poly(arylene ether ketone) (PAEK) powders, the process being mixing the powder or the mixture of powders, in a mixer equipped with a rotary stirrer including at least one blade, for a period of between 30 minutes and 120 minutes, preferably of between 30 and 60 minutes, at a blade-tip speed of between 30 m/s and 70 m/s, preferably of between 40 and 50 m/s.

A method for the manufacture of polyether ketone ketone (PEKK), including the steps of: reacting 1,4-bis(4-phenoxybenzoylbenzene) and/or diphenylether with at least one difunctional aromatic acyl chloride, in a reaction solvent and in presence of a Lewis acid, to obtain a product mixture including a PEKK-Lewis acid complex; contacting the obtained product mixture with a protic solvent, so as to form a dispersion that includes a liquid phase including Lewis acid and a second phase, e.g., a solid phase, including PEKK; and separating the second phase from the liquid phase by centrifugal filtration, so as to recover a crude PEKK and a effluent containing Lewis acid, wherein step (iii) includes a step of centrifugal filtration.

A method for the manufacture of polyether ketone ketone (PEKK), including the steps of: reacting 1,4-bis(4-phenoxybenzoylbenzene) and/or diphenylether with at least one difunctional aromatic acyl chloride, in a reaction solvent and in presence of a Lewis acid, to obtain a product mixture including a PEKK-Lewis acid complex; contacting the obtained product mixture with a protic solvent, so as to form a dispersion that includes a liquid phase including Lewis acid and a second phase, e.g., a solid phase, including PEKK; and separating the second phase from the liquid phase by centrifugal filtration, so as to recover a crude PEKK and a effluent containing Lewis acid, wherein step (iii) includes a step of centrifugal filtration.

Provided are a method for preparing a polyetherketoneketone and a polyetherketoneketone prepared thereby, wherein, at the time of a polymerization reaction, nitrogen gas is blown into a liquid reaction medium while stirring, thereby quickly removing hydrochloric acid, which is a by-product generated during the reaction, and preventing aggregation of resin particles, thus suppressing the generation of scales.

Provided are a method for preparing a polyetherketoneketone and a polyetherketoneketone prepared thereby, wherein, at the time of a polymerization reaction, nitrogen gas is blown into a liquid reaction medium while stirring, thereby quickly removing hydrochloric acid, which is a by-product generated during the reaction, and preventing aggregation of resin particles, thus suppressing the generation of scales.

A phenylene ether oligomer composition is disclosed comprising, a phenylene ether oligomer having an external amine content of less than or equal to 1.5 weight percent; and a residual solvent in an amount of 10 to 10000 parts per million by weight, based on the weight of the phenylene ether oligomer composition; wherein the phenylene ether oligomer composition has an intrinsic viscosity of 0.03 to 0.13 deciliter per gram; a glass transition temperature of 135 to 175 C., or a combination thereof