A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described. ##STR00001##

Provided is a method that can stably produce polyaryletherketone that has a high degree of polymerization and can be easily recovered. The method for producing polyaryletherketone includes: a polycondensation step of carrying out desalting polycondensation in a reaction solvent; and a cooling step of cooling a reaction mixture after desalting polycondensation is completed. When the method is implemented, the polycondensation step is carried out in a hydrophilic solvent under pressurized conditions, and the polymerization temperature in the polycondensation step is at or above the boiling point of the hydrophilic solvent at ambient pressure. In addition, the polymer content in terms of monomers at the time of cooling in the cooling step is from 1 part by mass to 50 parts by mass, per 100 parts by mass of the hydrophilic solvent in the reaction mixture.

Provided is a method that can stably produce polyaryletherketone that has a high degree of polymerization and can be easily recovered. The method for producing polyaryletherketone includes: a polycondensation step of carrying out desalting polycondensation in a reaction solvent; and a cooling step of cooling a reaction mixture after desalting polycondensation is completed. When the method is implemented, the polycondensation step is carried out in a hydrophilic solvent under pressurized conditions, and the polymerization temperature in the polycondensation step is at or above the boiling point of the hydrophilic solvent at ambient pressure. In addition, the polymer content in terms of monomers at the time of cooling in the cooling step is from 1 part by mass to 50 parts by mass, per 100 parts by mass of the hydrophilic solvent in the reaction mixture.

A process including: the provision of a semicrystalline or crystallizable composition, having a glass transition temperature T.sub.g, including at least one polyaryletherketone; the provision of a compression forming means including: a mold, the mold having at least one cavity; the preparation of the composition in the molten state in said at least one cavity, the mold having a temperature T.sub.0 at the end of the preparation stage; the compression and the cooling of the composition in the molten state, the mold being cooled from the temperature T.sub.0 down to a final temperature T.sub.fof less than or equal to (T.sub.g+30)° C., to form a compression-formed article; and the removal of the compression-formed article from the mold; in which the composition has a melting point strictly of less than 340° C.

Provided are a polytrimethylene ether glycol and a preparation method thereof, wherein various by-products and oligomers may be effectively removed from a polytrimethylene ether glycol product without exposing to a high temperature for a long period of time, and therefore, a molecular weight variation may be reduced due to the removal of various by-products and low molecular weight oligomers.

Provided are a polytrimethylene ether glycol and a preparation method thereof, wherein various by-products and oligomers may be effectively removed from a polytrimethylene ether glycol product without exposing to a high temperature for a long period of time, and therefore, a molecular weight variation may be reduced due to the removal of various by-products and low molecular weight oligomers.

A substantially biobased prepolymer mixture including 31.80 to 67.95 percent biogenic carbon content by weight, wherein the mixture is a combination of: an isocyanate; and a cleaned biobased polyoxyalkylene glycol polyol, wherein the cleaned biobased polyoxyalkylene glycol polyol is completely primary hydroxyl-tipped or primary hydroxyl end-grouped, further wherein said cleaned biobased polyoxyalkylene glycol polyol is polymerized from 100% biobased ethylene oxide, further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 15 ppm sodium and potassium metals, and further wherein the cleaned biobased polyoxyalkylene glycol polyol comprises less than 0.5% water by weight.

A poly(arylene ether) copolymer wherein the poly(arylene ether) copolymer is a product of oxidative copolymerization of monomers comprising a first monohydric phenol; a second monohydric phenol different from the first monohydric phenol; a siloxane oligomer; and optionally, at least one terminal functional group.

A method of making a PEEK-PEoEK copolymer having R.sub.PEEK and RPEoEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEoEK ranging from 95/5 to 45/55, the PEEK-PEoEK copolymer obtained from the method and the polymer composition including the PEEK-PEoEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.

A method of making a PEEK-PEoEK copolymer having R.sub.PEEK and RPEoEK repeat units in a molar ratio R.sub.PEEK/R.sub.PEoEK ranging from 95/5 to 45/55, the PEEK-PEoEK copolymer obtained from the method and the polymer composition including the PEEK-PEoEK copolymer, at least one reinforcing filler, at least one additive, or a combination thereof, shaped articles including the polymer composition, polymer-metal junctions including the polymer composition. Also described are methods of making the polymer composition, methods of making the shaped articles, and methods of making the polymer-metal junctions.