A method for the reuse of PEKK-based carbon fiber reinforced polymer composites is provided. Chips obtained by comminuting the carbon fiber-reinforced PEKK composite material are melt mixed with a virgin poly(aryletherketone) polymer to provide carbon fiber-reinforced poly(aryletherketone) compositions. Molded articles having good mechanical properties can be prepared from the carbon fiber-reinforced poly(aryletherketone) compositions.

A method for the reuse of PEKK-based carbon fiber reinforced polymer composites is provided. Chips obtained by comminuting the carbon fiber-reinforced PEKK composite material are melt mixed with a virgin poly(aryletherketone) polymer to provide carbon fiber-reinforced poly(aryletherketone) compositions. Molded articles having good mechanical properties can be prepared from the carbon fiber-reinforced poly(aryletherketone) compositions.

A process for producing polyarylene ether nitrile, in which an N-methylpyrrolidone solvent can be efficiently recovered. The process includes the following steps: mixing N-methylpyrrolidone, potassium carbonate, 2,6-dichlorobenzonitrile, dihydric phenol and toluene, and carrying out a dehydration reaction and a polymerization reaction in sequence to obtain a high-viscosity polyarylene ether nitrile solution; then pelletizing and conveying polyarylene ether nitrile particles together with methanol to a primary vibrating screen to complete a primary replacement of N-methylpyrrolidone; then using a secondary vibrating screen to complete a secondary replacement of the solvent; subsequently, grinding the polyarylene ether nitrile particles and carrying out an extraction with methanol, and then centrifuging, washing with water and drying to obtain purified polyarylene ether nitrile powder; and finally distilling replacement liquid and centrifugation liquid to separate methanol from N-methylpyrrolidone.

A process for producing polyarylene ether nitrile, in which an N-methylpyrrolidone solvent can be efficiently recovered. The process includes the following steps: mixing N-methylpyrrolidone, potassium carbonate, 2,6-dichlorobenzonitrile, dihydric phenol and toluene, and carrying out a dehydration reaction and a polymerization reaction in sequence to obtain a high-viscosity polyarylene ether nitrile solution; then pelletizing and conveying polyarylene ether nitrile particles together with methanol to a primary vibrating screen to complete a primary replacement of N-methylpyrrolidone; then using a secondary vibrating screen to complete a secondary replacement of the solvent; subsequently, grinding the polyarylene ether nitrile particles and carrying out an extraction with methanol, and then centrifuging, washing with water and drying to obtain purified polyarylene ether nitrile powder; and finally distilling replacement liquid and centrifugation liquid to separate methanol from N-methylpyrrolidone.

Disclosed is a method for synthesizing dihydroxyl-terminated polyphenylene oxide oligomer. The method for synthesizing dihydroxyl-terminated polyphenylene oxide oligomer, comprising oxidatively copolymerizing monohydric phenol and dihydric phenol in the presence of a metal-polyethyleneimine complex as a catalyst, to obtain the dihydroxyl-terminated polyphenylene oxide oligomer. The synthesizing method of the present disclosure uses a metal-polyethyleneimine complex as a catalyst, which has a milder catalytic activity, can effectively promote the reaction between the dihydric phenol and the monohydric phenol, increases the hydroxyl content of the product, meanwhile reduces the amount of the residual dihydric phenol monomer in the product, so that the quality of the product can be improved. The dihydroxyl-terminated polyphenylene oxide oligomer prepared can be used as additive and copolymerization block in other thermoplastic plastics, thermoplastic elastomers and thermosetting materials, thereby improving the performances of the material, such as thermal performance, adhesion, mechanical property, chemical resistance, and electrical property.

A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

A fused filament fabrication filament, method and process, for layer-wise formation of a component, wherein the filament, method and process comprise feedstock material comprising a polyaryletherketone, PAEK and optionally, one or more filler means.

The present disclosure relates to a method for crystallizing highly functional polymer by post-processing and crystalline polymer produced by the method, and more specifically, is characterized by producing crystalline polyaryletherketone (PAEK) by heat treating polyaryletherketone (PAEK) provided in the form of pellets or powders at a temperature of glass transition temperature (Tg) to melting point (Tm).

The present disclosure relates to a method for crystallizing highly functional polymer by post-processing and crystalline polymer produced by the method, and more specifically, is characterized by producing crystalline polyaryletherketone (PAEK) by heat treating polyaryletherketone (PAEK) provided in the form of pellets or powders at a temperature of glass transition temperature (Tg) to melting point (Tm).

A method of manufacturing a semi-crystalline article from at least one pseudo-amorphous polymer including a poly aryl ether ketone, such as PEKK, including a softening step, wherein the at least one pseudo-amorphous polymer is heated to a temperature above its glass transition temperature to soften the polymer, and a crystallization step, wherein the at least one pseudo-amorphous polymer is heated to a temperature between its glass transition temperature and melting temperature, the pseudo-amorphous polymer being placed on a mold during either the softening step or the crystallization step before at least some crystallization takes place. The method results in articles demonstrating increased opacity, increased crystallinity, increased thermal resistance, improved chemical resistance, and improved mechanical properties over articles formed by traditional thermoforming processes.