C08G69/04

Production of polyamide powders by ester aminolysis
11066528 · 2021-07-20 · ·

A method for producing a polycondensate powder dispersion, characterised in that it includes at least one step of polycondensation: i) of at least one diester and at least one diamine, and/or ii) at least one amino ester, while stirring, in a solvent that can solubilise both the diamine and the diester and/or the amino ester but not the polyamide that forms during the polycondensation, at a temperature between 30° C. and the boiling temperature of the solvent, in order to produce a powder precipitate dispersed in the solvent.

STAIN-RESISTANT BRANCHED POLYAMIDES

The present disclosure provides a polyamide composition and method of making a polyamide composition. The polyamide composition includes branched chains to provide for greater fiber tenacity and residues of a salt of 5-sulfoisophthalic or 5-sulfoisophthalic acid to provide excellent stain resistance.

STAIN-RESISTANT BRANCHED POLYAMIDES

The present disclosure provides a polyamide composition and method of making a polyamide composition. The polyamide composition includes branched chains to provide for greater fiber tenacity and residues of a salt of 5-sulfoisophthalic or 5-sulfoisophthalic acid to provide excellent stain resistance.

CATIONIC POLYMER AND USE FOR BIOMOLECULE DELIVERY
20210238347 · 2021-08-05 ·

Provided is a polymer comprising a structure of Formula (1): (1) and a method of preparing said polymer. Also provided is a composition comprising the polymer and a nucleic acid and/or polypeptide, and a method of delivering a nucleic acid and/or polypeptide to a cell.

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CATIONIC POLYMER AND USE FOR BIOMOLECULE DELIVERY
20210238347 · 2021-08-05 ·

Provided is a polymer comprising a structure of Formula (1): (1) and a method of preparing said polymer. Also provided is a composition comprising the polymer and a nucleic acid and/or polypeptide, and a method of delivering a nucleic acid and/or polypeptide to a cell.

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PROCESS FOR POLYMERIZING CYCLIC OLIGOMERS OF POLYAMIDES
20210155753 · 2021-05-27 ·

A process for production of high molecular weight polyamide polymers, such as 6/66 copolymers, using a reactant stream that includes at least one lactam and cyclic oligomers. The stream is reacted with at least one diamine at an elevated temperature to ring-open the cyclic oligomers to produce amide pre-polymers that are end-capped with amine groups. The pre-polymers are then reacted with at least one diacid at an elevated temperature to form polyamide 6/66 copolymers. The cyclic oligomers may be formed as by-products during standard polymerization of polyamide polymers from monomers such as caprolactam, hexamethylene diamine and adipic acid.

STRONG BASE-INITIATED N-CARBOXYANYDRIDE RAPID RING-OPENING POLYMERISATION METHOD
20210155752 · 2021-05-27 ·

The present invention relates to a strong base-initiated N-carboxyanhydride rapid ring-opening polymerisation method. Specifically, the method comprises steps of: performing a polymerisation reaction with one or more amino acid N-carboxyanhydride monomers in an organic solvent in the presence of an initiator, so as to form an amino acid polymer, wherein the initiator is selected from the following group: LiHMDS, NaHMDS, KHMDS, or a combination thereof. The method significantly increases the speed of traditional NCA polymerisation and prepares a long-chain polymer, and the prepared amino acid polymer may be used as an anti-bacterial material, an anti-tumour material, a tissue engineering scaffold or a self-assembling material.

METHOD FOR INCREASING THE DIFFERENCE BETWEEN THE MELTING TEMPERATURE AND THE CRYSTALLIZATION TEMPERATURE OF A POLYAMIDE POWDER
20210107235 · 2021-04-15 · ·

A method for reducing the crystallization temperature and the melting temperature of a polyamide powder resulting from the polymerization of at least one predominant monomer, in which the reduction in the crystallization temperature is greater than the reduction in the melting temperature, the method including a step of polymerization of the at least one predominant monomer with at least one different minor comonomer polymerized according to the same polymerization process as the at least one predominant monomer, the at least one minor comonomer being chosen from aminocarboxylic acids, diamine/diacid pairs, lactams and/or lactones, and the at least one minor comonomer representing from 0.1% to 20% by weight of the total blend of the monomers(s) and comonomer(s), preferably from 0.5% to 15% by weight of the total blend, preferably from 1% to 10% by weight of the total blend.

METHOD FOR INCREASING THE DIFFERENCE BETWEEN THE MELTING TEMPERATURE AND THE CRYSTALLIZATION TEMPERATURE OF A POLYAMIDE POWDER
20210107235 · 2021-04-15 · ·

A method for reducing the crystallization temperature and the melting temperature of a polyamide powder resulting from the polymerization of at least one predominant monomer, in which the reduction in the crystallization temperature is greater than the reduction in the melting temperature, the method including a step of polymerization of the at least one predominant monomer with at least one different minor comonomer polymerized according to the same polymerization process as the at least one predominant monomer, the at least one minor comonomer being chosen from aminocarboxylic acids, diamine/diacid pairs, lactams and/or lactones, and the at least one minor comonomer representing from 0.1% to 20% by weight of the total blend of the monomers(s) and comonomer(s), preferably from 0.5% to 15% by weight of the total blend, preferably from 1% to 10% by weight of the total blend.

COMPOUND AND METHOD FOR PRODUCING THE SAME
20210130408 · 2021-05-06 ·

Disclosed is a method for producing a compound, the method including polymerizing an amino acid carboxyanhydride-based compound using a catalyst. The method for producing the compound may improve a polymerization reaction rate and provide a compound having a narrower molecular weight distribution and having a polymer ring structure bonded to the catalyst.