A curable polymer composition containing: (A) a thermoset benzoxazine resin precursor component; (B) optionally, an aryl sulphone-containing benzoxazine component, and (C) a polyarylsulphone thermoplastic toughening agent, wherein in the absence of component (B), component (C) contains one or more benzoxazine pendant- and/or end-groups.

[Problem]

To provide such a composition for producing a sacrifice layer as has excellent properties in both heat resistance and storage stability, and also to provide a process for producing a semiconductor device using the composition.

[Solution]

Disclosed is a composition for producing a sacrifice layer. The composition comprises a solvent and a polymer having a repeating unit containing a nitrogen atom with a lone pair, and contains particular transition metals only in a very low content. Also disclosed is a process using the composition as a sacrificial material for producing a semiconductor device comprising a porous material.

A compound of the formula: (I) wherein: R.sup.1 is selected from H, an alkyl group, an aryl group, and combinations thereof; R.sup.2 is R.sup.f—Y—(CH.sub.2)X—; R.sup.3 is a reactive group; R.sup.f is a perfluorinated alkyl group; Y is selected from a bond, S(O).sub.2—N(CH.sub.3)—, —S(O).sub.2—N(CH.sub.2CH.sub.3)—, —S(O).sub.2—O— —S(O).sub.2— —C(O)—, —C(O)—S— —C(O)—O— —C(O)—NH—, —C(O)—N(CH.sub.3)—, —C(O)—N(CH.sub.2CH.sub.3)—, —(CH.sub.2CH.sub.2O)y-, —O—, and —O—C(O)—CH═CH—C(O)—O—; n is greater than 10; x is 2 to 20; and y is at least 1. ##STR00001##

At least a metallic part of a metal or metallized reinforcer, at least the surface of which is at least partially metallic, is coated with a polybenzoxazine, the repeat units of which comprise at least one unit corresponding to the formulae (I) or (II): ##STR00001##
in which Z.sub.1 represents an at least divalent, aliphatic, cycloaliphatic or aromatic bonding group comprising at least one carbon atom and optionally at least one heteroatom selected from O, S, N and P; X.sub.1 and X.sub.2, which are identical or different, represent O or S; Ar.sub.1 and Ar.sub.2, which are identical or different, represent a substituted or unsubstituted phenylene group; and Z.sub.2 represents O or (S).sub.n, the symbol “n” representing an integer equal to 1 or greater than 1. Such a reinforcement can be used for the reinforcement of a rubber article, in particular a motor vehicle tyre.

A biocompatible, covalently cross-linked, polymer that is obtained by reacting an electrophilically activated polyoxazoline (EL-PDX) with a nucleophilic cross-linking agent is disclosed. The EL-PDX comprises m electrophilic groups; and the nucleophilic cross-linking agent comprises n nucleophilic groups, wherein the m electrophilic groups are capable of reacting with the n nucleophilic groups to form covalent bonds; wherein m≧2, n≧2 and m+n≧5; wherein at least one of the m electrophilic groups is a pendant electrophilic group and/or wherein m≧3; and wherein the EL-PDX comprises an excess amount of electrophilic groups relative to the amount of nucleophilic groups contained in the nucleophilic cross-linking agent. Biocompatible medical products and kits comprising the cross-linked PDX-polymers are also disclosed.

In one aspect, adhesives for use with a 3D printer are described herein. In some embodiments, an adhesive for use with a 3D printer comprises a first polymeric component comprising a poly(vinyl alcohol) and a second polymeric component. The poly(vinyl alcohol), in some embodiments, comprises amorphous poly(vinyl alcohol). In some embodiments, the second polymeric component comprises a water-soluble polymer. Further, in some embodiments, an adhesive described herein further comprises a solvent, a surfactant, and/or a preservative.

An environment-friendly impregnation solution includes in percentage by weight: 1-15% of blocked isocyanate, 0.5-10% of special amino resin, 10-50% of rubber latex, 1-5% of auxiliaries, and the balance of water, wherein the sum of the weight percentage of each component is 100%. A method for preparing the environment-friendly impregnation solution includes adding blocked isocyanate and auxiliary A into water and stirring uniformly to obtain Composition 1; adding auxiliary B into Composition 1 and stirring uniformly to obtain Composition 2; adding special amino resin into Composition 2 and stirring uniformly, then subjecting the same to grinding to obtain Composition 3; adding rubber latex into Composition 3 and stirring uniformly to obtain the environment-friendly impregnation solution, followed by packaging. The impregnation solution of the invention does not contain toxic and harmful substances such as formaldehyde and resorcinol, and the preparation method thereof is simple.

A bifunctional polymer is functionalized at one end with an azlactone end group to conjugate biomolecules of interest, and is functionalized at another end with an azide anchor group to attach the polymer to a substrate. Methods of making the bifunctional polymer are also provided. A coated substrate includes the bifunctionalized polymers on the surface of a substrate. Methods of making the coated substrate are also provided. A microarray includes a plurality of discrete regions, each region including the coated substrate.

A demulsifier composition comprises an oxyalkylated polybenzoxazine having repeating units of Formula (I): ##STR00001##
wherein R.sub.1 is hydrogen, a C.sub.1-30 alkyl, a C.sub.3-30 cycloalkyl, a C.sub.6-30 aryl, a C.sub.7-30 alkylarylene, a C.sub.7-30 arylalkyl, a C.sub.5-30 heteroaryl, or a C.sub.3-30 heterocycloalkyl; R.sub.2 is a C.sub.1-30 alkyl, a C.sub.3-30 cycloalkyl, a C.sub.6-30 aryl, a C.sub.7-30 alkylarylene, a C.sub.7-30 arylalkyl, a C.sub.5-30 heteroaryl, or a C.sub.3-30 heterocycloalkyl; R.sub.3 is hydrogen or a C.sub.1-10 alkyl; each occurrence of R.sub.4 is independently hydrogen or a C.sub.1-5 alkyl; and p is at least 1.

Disclosed herein are amphiphilic polymers and hierarchical structures (e.g., emulsions) comprising said polymer. Also disclosed herein are methods of using the polymers and hierarchical structure disclosed herein.