Provided are a photosensitive resin composition which has excellent pattern processabilities (high sensitivity and high resolution) and is excellent in chemical resistance and thermal resistance after thermally treated; a heat-resistant resin or heat-resistant resin precursor used for the composition; and a diamine compound which is a raw material of the resin and the precursor. The diamine compound is a diamine compound represented by a general formula (1).

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A plastic bearing material of a bearing may include a block copolymer. The block copolymer may include structural blocks of two or more different polymers. A first polymer may include at least one of polyamide-imide and polybenzimidazole. A second polymer may include at least one of polydimethylsiloxane, methyl vinyl ether and polyisobutene. A method for manufacturing a plastic bearing material may include synthesizing a structural block of a first polymer and a structural block of a second polymer to define a block copolymer via a condensation reaction.

A plastic bearing material of a bearing may include a block copolymer. The block copolymer may include structural blocks of two or more different polymers. A first polymer may include at least one of polyamide-imide and polybenzimidazole. A second polymer may include at least one of polydimethylsiloxane, methyl vinyl ether and polyisobutene. A method for manufacturing a plastic bearing material may include synthesizing a structural block of a first polymer and a structural block of a second polymer to define a block copolymer via a condensation reaction.

A composite polymer solution comprising a homogeneous mixture of a first polymer solution comprising a first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein i) the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole; and ii) the plurality of acid monomers include those having a structure of
Cl—CO—Ar.sub.1—CO—Cl and Cl—CO—Ar.sub.2—CO—Cl wherein Ar.sub.1 is a para-oriented aromatic group and Ar.sub.2 is a meta-oriented aromatic group, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing Ar.sub.2; and a second polymer solution comprising a second polymer having a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride.

A composite polymer solution comprising a homogeneous mixture of a first polymer solution comprising a first polymer having a structure derived from the reaction of one or more amine monomers and a plurality of acid monomers, wherein i) the one or more amine monomers includes at least 60 mole percent 5(6)-amino-2-(p-aminophenyl)benzimidazole; and ii) the plurality of acid monomers include those having a structure of
Cl—CO—Ar.sub.1—CO—Cl and Cl—CO—Ar.sub.2—CO—Cl wherein Ar.sub.1 is a para-oriented aromatic group and Ar.sub.2 is a meta-oriented aromatic group, and wherein the plurality of acid monomers has at least 50 mole percent of the monomer containing Ar.sub.2; and a second polymer solution comprising a second polymer having a structure derived from the reaction of metaphenylene diamine and isophthaloyl chloride.

A black-color polymer composite film comprising a phthalocyanine compound dispersed in a polymer selected from the group consisting of polyimide, polyamide, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, and combinations thereof, wherein the phthalocyanine compound occupies a weight fraction of 0.1% to 50% based on the total polymer composite weight. Preferably, the phthalocyanine compound is selected from copper phthalocyanine, zinc phthalocyanine, tin phthalocyanine, iron phthalocyanine, lead phthalocyanine, nickel phthalocyanine, vanadyl phthalocyanine, fluorochromium phthalocyanine, magnesium phthalocyanine, manganous phthalocyanine, dilithium phthalocyanine, aluminum phthalocyanine chloride, cadmium phthalocyanine, chlorogallium phthalocyanine, cobalt phthalocyanine, silver phthalocyanine, a metal-free phthalocyanine, or a combination thereof.

A black-color polymer composite film comprising a phthalocyanine compound dispersed in a polymer selected from the group consisting of polyimide, polyamide, polyoxadiazole, polybenzoxazole, polybenzobisoxazole, polythiazole, polybenzothiazole, polybenzobisthiazole, poly(p-phenylene vinylene), polybenzimidazole, polybenzobisimidazole, and combinations thereof, wherein the phthalocyanine compound occupies a weight fraction of 0.1% to 50% based on the total polymer composite weight. Preferably, the phthalocyanine compound is selected from copper phthalocyanine, zinc phthalocyanine, tin phthalocyanine, iron phthalocyanine, lead phthalocyanine, nickel phthalocyanine, vanadyl phthalocyanine, fluorochromium phthalocyanine, magnesium phthalocyanine, manganous phthalocyanine, dilithium phthalocyanine, aluminum phthalocyanine chloride, cadmium phthalocyanine, chlorogallium phthalocyanine, cobalt phthalocyanine, silver phthalocyanine, a metal-free phthalocyanine, or a combination thereof.

A family of new and novel molecules for mechanically superior two-dimensional (2D) polymers is described herein. By combining stiff carbon-containing cyclic polymer nodal units with more compliant linear polymer bridge units in an ordered, 2D repeating molecular structure it is possible to tailor the mechanical properties of 2D polymers and their assemblies to provide high stiffness, strength, and toughness. Furthermore, the inherent dimensionality of 2D polymers and their ability to be stacked into ordered and chemically interactive ensembles gives them inherent benefits in a variety of barrier and structural applications over current stiff and strong linear polymer technologies.

A family of new and novel molecules for mechanically superior two-dimensional (2D) polymers is described herein. By combining stiff carbon-containing cyclic polymer nodal units with more compliant linear polymer bridge units in an ordered, 2D repeating molecular structure it is possible to tailor the mechanical properties of 2D polymers and their assemblies to provide high stiffness, strength, and toughness. Furthermore, the inherent dimensionality of 2D polymers and their ability to be stacked into ordered and chemically interactive ensembles gives them inherent benefits in a variety of barrier and structural applications over current stiff and strong linear polymer technologies.

Spun ABPBI fibers and a process for the preparing spun ABPBI fibers using a high molecular weight ABPBI dope solution suitable for spinning are provided. A process for preparing the high molecular weight ABPBI dope solution suitable for spinning is also provided. The spun ABPBI fibers can be used in the preparation of high temperature thermally resistant articles.