Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.

Described herein are polymer compositions having a poly(ether sulfone) polymer and (i) a polysulfone polymer or (ii) a poly(phenyl sulfone) polymer. In some embodiments, the polymer compositions can optionally include one or more additives. It has been surprisingly found that the aforementioned polymer compositions have outstanding anti-stick properties with respect to proteins.

A poly(biphenyl ether sulfone) resin substantially comprising a repeating structure of the following formula (1), wherein a polystyrene equivalent mass average molecular weight Mw and a melt viscosity μ at a temperature of 350° C. satisfy formulas (6) and (7),

##STR00001## wherein n represents an integer of 1 or more,

60,000≤Mw≤90,000   (6)

0.0906×Mw−4,930≤μ≤3,500   (7).

A poly(biphenyl ether sulfone) resin substantially comprising a repeating structure of the following formula (1), wherein a polystyrene equivalent mass average molecular weight Mw and a melt viscosity μ at a temperature of 350° C. satisfy formulas (6) and (7),

##STR00001## wherein n represents an integer of 1 or more,

60,000≤Mw≤90,000   (6)

0.0906×Mw−4,930≤μ≤3,500   (7).

A method for producing a nonwoven fabric is provided. The method includes spinning a molten aromatic polysulfone resin from a nozzle and extending it with a high temperature fluid ejected at high speed, thereby obtaining the aromatic polysulfone resin in a fibrous form, and collecting the aromatic polysulfone resin obtained in a fibrous form on a moving collecting member. The aromatic polysulfone resin has a melt mass flow rate of 130 g/10 min or more under conditions of a test temperature of 400° C. and a nominal load of 2.16 kg, which is determined based on ASTM D 1238. A distance from the nozzle to the collecting member is set to 30 mm or less.

A method for producing a nonwoven fabric is provided. The method includes spinning a molten aromatic polysulfone resin from a nozzle and extending it with a high temperature fluid ejected at high speed, thereby obtaining the aromatic polysulfone resin in a fibrous form, and collecting the aromatic polysulfone resin obtained in a fibrous form on a moving collecting member. The aromatic polysulfone resin has a melt mass flow rate of 130 g/10 min or more under conditions of a test temperature of 400° C. and a nominal load of 2.16 kg, which is determined based on ASTM D 1238. A distance from the nozzle to the collecting member is set to 30 mm or less.

The present invention relates to a poly(biphenyl ether sulfone) resin substantially comprising a repeating structure of the following formula (1), and having a spin-lattice relaxation time T.sub.IL of a long component of 24 s or more, which is calculated from decay of a signal intensity I (τ) corresponding to a chemical shift of 129 ppm by acquiring a .sup.13C-NMR spectrum by a Torchia pulse sequence using an NMR device for solid sample measurement and changing a value of a waiting time τ in the pulse sequence,

##STR00001## wherein n represents an integer of 1 or more.

The present invention relates to functionalized poly(aryl ether sulfones) polymers. The invention further relates to polymer compositions including the functionalized poly(aryl ether sulfone) polymers. Still further, the invention relates to lithographic methods to form three-dimensional (3D) objects that incorporate the aforementioned polymer compositions.

The present invention relates to functionalized poly(aryl ether sulfones) polymers. The invention further relates to polymer compositions including the functionalized poly(aryl ether sulfone) polymers. Still further, the invention relates to lithographic methods to form three-dimensional (3D) objects that incorporate the aforementioned polymer compositions.

The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.