The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.

A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

A semicrystalline polyphenylsulfone, has the structure Formula (I) wherein n and R are defined herein. The semicrystalline polyphenylsulfone, which exhibits a crystalline melting point in a range of 215 to 270° C., can be prepared from amorphous polyphenylsulfone using a solvent-induced crystallization method. An additive manufacturing method utilizing particles of the semicrystalline polyphenylsulfone is described.

The present invention relates to a method for producing a block copolymer of the poly-ethersulfone type containing a biosourced diol, to a block copolymer that can be obtained by said method, and to the use of said block copolymer for producing membranes.

The present invention relates to a method for producing a block copolymer of the poly-ethersulfone type containing a biosourced diol, to a block copolymer that can be obtained by said method, and to the use of said block copolymer for producing membranes.

An aromatic polyether containing a structural unit represented by the following formula (1), a structural unit represented by the following formula (2), and a structure represented by the following formula (3), wherein .sup.1H-NMR measurement, a ratio of a peak intensity of a peak having the largest peak intensity among peaks derived from the structure represented by the formula (3) appearing in the range of chemical shift 7.55 ppm to 7.65 ppm, relative to a peak intensity of a peak derived from the structural unit represented by the formula (2) appearing in the vicinity of chemical shift 7.35 ppm is 0.20 to 2.00%.

##STR00001##

A polyphenylene sulfone (PPSU) consisting essentially of benzophenone coupled phenylene sulfone segments A and B of formula (I) wherein segments A and B can be same or different and are of formula (II) wherein x is an integer of from 4.5 to 8.

##STR00001##

A polyphenylene sulfone (PPSU) consisting essentially of benzophenone coupled phenylene sulfone segments A and B of formula (I) wherein segments A and B can be same or different and are of formula (II) wherein x is an integer of from 4.5 to 8.

##STR00001##

Various examples are directed to a glucose sensor comprising a working electrode to support an oxidation reaction and a reference electrode to support a redox reaction. The reference electrode may comprise silver and silver chloride. The Glucose sensor may also comprise an anti-mineralization agent positioned at the reference electrode to reduce formation of calcium carbonate at the reference electrode.

The present invention relates to relates to a polymer formulation for three-dimensionally (3D) printing an article by stereolithography, the formulation comprising a functionalized polymer. The invention further relates to lithographic methods to form 3D objects that incorporate the aforementioned polymer formulation.