C08G77/20

Thermosetting silicone resin composition and die attach material for optical semiconductor device
11566132 · 2023-01-31 · ·

A thermosetting silicone resin composition contains the following components (A-1) to (D): (A-1) an alkenyl group-containing linear organopolysiloxane; (A-2) a branched organopolysiloxane shown by (R.sup.1.sub.3SiO.sub.1/2).sub.a(R.sup.2.sub.3SiO.sub.1/2).sub.b(SiO.sub.4/2).sub.c (1); (B-1) a branched organohydrogenpolysiloxane shown by (HR.sup.2.sub.2SiO.sub.1/2).sub.d(R.sup.2.sub.3SiO.sub.1/2).sub.e(SiO.sub.4/2).sub.f (2); (B-2) a linear organohydrogenpolysiloxane shown by (R.sup.2.sub.3SiO.sub.1/2).sub.2(HR.sup.2SiO.sub.2/2).sub.x(R.sup.2.sub.2SiO.sub.2/2).sub.y (3); (C) an adhesion aid which is an epoxy group-containing branched organopolysiloxane; and (D) a catalyst containing a combination of a zero-valent platinum complex with a divalent platinum complex and/or a tetravalent platinum complex. This provides a thermosetting silicone resin composition which causes little contamination at a gold pad portion and has excellent adhesiveness to a silver lead frame.

Plastic Films

The invention relates to plastic films and a silicone containing polymer blend composition that can be used in the production of the plastic films which is a polymer composition obtainable from, per 100 parts by weight of the composition, 99.99 to 90 parts by weight of a polyolefin polymer (P) and 0.01 to 10 parts by weight of a masterbatch (M).

Plastic Films

The invention relates to plastic films and a silicone containing polymer blend composition that can be used in the production of the plastic films which is a polymer composition obtainable from, per 100 parts by weight of the composition, 99.99 to 90 parts by weight of a polyolefin polymer (P) and 0.01 to 10 parts by weight of a masterbatch (M).

SILICONE PARTICLES WITH A CROSS-LINKED CORE AND PREPARATION THEREOF
20230029365 · 2023-01-26 · ·

Particles P and methods of making the same. The particles P are composed of a core K comprising crosslinked silicone elastomer composition X and of a shell H of silica S. Where the core K includes a reinforcing filler F which is selected from pyrogenic or precipitated hydrophobic silicas having DIN 66131 BET surface areas of at least 50 m.sup.2/g and also from carbon blacks and activated carbons and silicone resins.

EIGHT-ARM STAR-SHAPED THERMOPLASTIC ELASTOMER COPOLYMER AND PREPARATION METHOD THEREFOR
20230025095 · 2023-01-26 ·

An eight-arm star-shaped thermoplastic elastomer copolymer and a preparation method therefor; a polystyrene-polyisoprene lithium compound and a polystyrene/diphenylethylene-polyisoprene lithium compound are synthesized by using active anionic polymerization, and the compounds are used for a coupling reaction with octenyl polyhedral oligomeric silasesquioxane to obtain the copolymer. The method has the characteristics of convenient operation, high reaction efficiency, mild reaction conditions, and few side reactions. The structure and molecular weight of the prepared eight-arm star-shaped polymer are controllable, and the molecular weight distribution is narrow. A polymer segment obtained by the copolymerization of diphenylethylene (DPE) and styrene (St) is used as a hard segment, which enables the eight-arm star-shaped thermoplastic elastomer copolymer to have more outstanding mechanical properties. At the same time, a polymer segment composed of DPE and St units has a higher glass transition temperature than polystyrene, which increases the upper limit usage temperature of the eight-arm star-shaped copolymer.

STYRENE DERIVATIVE AND PREPARATION METHOD THEREOF, AND MODIFIED ORGANIC SILICONE RESIN AND PREPARATION METHOD AND USE THEREOF
20230025924 · 2023-01-26 ·

The present disclosure provides a styrene derivative and a preparation method thereof, and a modified organic silicone resin and a preparation method and use thereof, and belongs to the technical field of back coating solutions. The styrene derivative is specifically 2,3-difluoro-4-methoxystyrene. A fluorine atom is introduced into a benzene ring structure, and the obtained styrene derivative contains a C—F bond with a relatively high chemical bond energy, such that the styrene derivative has a relatively high thermal stability. The styrene derivative can be introduced into an organic silicone resin to make the obtained modified organic silicone resin have a higher thermal stability. The modified organic silicone resin can be used as a back coating solution to effectively improve a heat resistance of barcode thermal transfer ribbons.

STYRENE DERIVATIVE AND PREPARATION METHOD THEREOF, AND MODIFIED ORGANIC SILICONE RESIN AND PREPARATION METHOD AND USE THEREOF
20230025924 · 2023-01-26 ·

The present disclosure provides a styrene derivative and a preparation method thereof, and a modified organic silicone resin and a preparation method and use thereof, and belongs to the technical field of back coating solutions. The styrene derivative is specifically 2,3-difluoro-4-methoxystyrene. A fluorine atom is introduced into a benzene ring structure, and the obtained styrene derivative contains a C—F bond with a relatively high chemical bond energy, such that the styrene derivative has a relatively high thermal stability. The styrene derivative can be introduced into an organic silicone resin to make the obtained modified organic silicone resin have a higher thermal stability. The modified organic silicone resin can be used as a back coating solution to effectively improve a heat resistance of barcode thermal transfer ribbons.

Addition-curing silicone resin for producing heat-shielding film, method for forming heat-shielding film on inner surface of combustion chamber of engine by means of addition-curing silicone resin, heat-shielding film, and heat shielding method for reducing or preventing heat dissipation from combustion chamber of engine to outside by means of heat-shielding film

In a heat-shielding film formed of addition-curing silicone resin containing organopolysiloxane, organopolysiloxane includes the combination of a plurality of units including at least a R.sup.1SiO.sub.3/2 unit (a T unit), a R.sup.2R.sup.3SiO.sub.2/2 unit (a D unit), and a R.sup.4R.sup.5R.sup.6SiO.sub.1/2 unit (a M unit) (in each unit, R.sup.1 to R.sup.6 is aliphatic hydrocarbon or hydrogen), and the molar ratio of the T unit, the D unit, and the M unit among all structural units is T:33.3 mol % to 71.4 mol %, D:11.1 mol % to 42.9 mol %, and M:7.0 mol % to 42.9 mol %.

Addition-curing silicone resin for producing heat-shielding film, method for forming heat-shielding film on inner surface of combustion chamber of engine by means of addition-curing silicone resin, heat-shielding film, and heat shielding method for reducing or preventing heat dissipation from combustion chamber of engine to outside by means of heat-shielding film

In a heat-shielding film formed of addition-curing silicone resin containing organopolysiloxane, organopolysiloxane includes the combination of a plurality of units including at least a R.sup.1SiO.sub.3/2 unit (a T unit), a R.sup.2R.sup.3SiO.sub.2/2 unit (a D unit), and a R.sup.4R.sup.5R.sup.6SiO.sub.1/2 unit (a M unit) (in each unit, R.sup.1 to R.sup.6 is aliphatic hydrocarbon or hydrogen), and the molar ratio of the T unit, the D unit, and the M unit among all structural units is T:33.3 mol % to 71.4 mol %, D:11.1 mol % to 42.9 mol %, and M:7.0 mol % to 42.9 mol %.

CURABLE SILICONE-(METH)ACRYLATE COMPOSITION AND METHODS FOR ITS PREPARATION AND USE
20230227700 · 2023-07-20 ·

A curable silicone-(meth)acrylate pressure sensitive composition is curable via hydrosilylation reaction to form a silicone-(meth)acrylate pressure sensitive adhesive with an initial adhesion. When the silicone-(meth)acrylate pressure sensitive adhesive is exposed to actinic radiation, the resulting silicone-(meth)acrylate adhesive has a subsequent adhesion, which is higher than the initial adhesion.