A one-part low modulus room temperature vulcamsable (RTV) silicone composition comprising a titanate and/or zirconate catalyst which cures to a low modulus silicone elastomer which has a good adhesion profile and may be used as a non-staining (clean) sealant having high movement capability which compositions contains an aminosilane adhesion promoter having two hydroxyl or hydrolysable groups per molecule in an amount of 0.1-3.75% by weight of the composition.

Foam control compositions along with formulations thereof and their use in various applications, including a method for making a foam control composition comprising a cross-linked polyorganosiloxane material including a dispersed silica filler, including the steps of: A) preparing a hydrosilylation reaction mixture by combining the following components: (i) silica filler, (ii) a polyorganosiloxane having at least two reactive substituents capable of addition reaction with component (iii) via hydrosilylation, (iii) a polyorganosiloxane having at least three reactive substituents capable of addition reaction with component (ii) via hydrosilylation, and (iv) a hydrosilylation catalyst; B) conducting a hydrosilylation reaction of components (ii) and (iii) until the reaction mixture at least partially gels to form a hydrosilylation reaction product; C) shearing the hydrosilylation reaction product of step B); and D) combining the hydrosilylation reaction product of step C) with a (v) silicone resin and an (vi) condensation catalyst to form a condensation reaction mixture and conducting a condensation reaction between the (v) silicone resin and the hydrosilylation reaction product of step C) to form a condensation reaction product.

Foam control compositions along with formulations thereof and their use in various applications, including a method for making a foam control composition comprising a cross-linked polyorganosiloxane material including a dispersed silica filler, including the steps of: A) preparing a hydrosilylation reaction mixture by combining the following components: (i) silica filler, (ii) a polyorganosiloxane having at least two reactive substituents capable of addition reaction with component (iii) via hydrosilylation, (iii) a polyorganosiloxane having at least three reactive substituents capable of addition reaction with component (ii) via hydrosilylation, and (iv) a hydrosilylation catalyst; B) conducting a hydrosilylation reaction of components (ii) and (iii) until the reaction mixture at least partially gels to form a hydrosilylation reaction product; C) shearing the hydrosilylation reaction product of step B); and D) combining the hydrosilylation reaction product of step C) with a (v) silicone resin and an (vi) condensation catalyst to form a condensation reaction mixture and conducting a condensation reaction between the (v) silicone resin and the hydrosilylation reaction product of step C) to form a condensation reaction product.

A method of preparing an alkoxy-functional organosilicon compound is provided. The method comprises reacting (A) an initial organosilicon compound and (B) an alcohol component in the presence of (C) a catalyst, thereby preparing the alkoxy-functional organosilicon compound. The initial organosilicon compound (A) comprises at least one alkoxysilyl group. The alcohol component (B) comprises an organic alcohol. The catalyst (C) comprises (C1) an ammonium carboxylate compound or (C2) a titanate compound. A reaction product comprising an alkoxy-functional organosilicon compound prepared in accordance with the method, and a composition comprising the reaction product, are also provided. The alkoxy-functional organosilicon compound, and the reaction product and composition comprising the same, are prepared in increased purity under functional group-tolerant conditions.

A method of preparing an alkoxy-functional organosiloxane compound is provided. The method comprises reacting (A) an initial organosiloxane compound and (B) an alcohol component in the presence of (C) a catalyst and, optionally, (D) an organosilicon compound, thereby preparing the alkoxy-functional organosiloxane compound. The initial organosiloxane compound (A) comprises at least one silanol group. The alcohol component (B) comprises an organic alcohol. The catalyst (C) comprises an ammonium carboxylate compound. The organosilicon compound (D), when utilized, comprises at least one alkoxysilyl group. A reaction product comprising an alkoxy-functional organosiloxane compound prepared in accordance with the method, and compositions comprising the reaction product and the alkoxy-functional organosiloxane compound are also provided. The alkoxy-functional organosiloxane compound, and the reaction product and composition comprising the same, are prepared in increased purity low cyclic content from depolymerization.

The modified graphene includes a structure represented by the following formula (I), wherein the modified graphene has a ratio (g/d) of an intensity “g” of a G band to an intensity “d” of a D band of 1.0 or more in a Raman spectroscopy spectrum thereof.

Gr1-Ar1-X1-(Y1).sub.n1  (I)

in the formula (I), Gr1 represents a single-layer graphene or a multilayer graphene, Ar1 represents an arylene group having 6 to 18 carbon atoms, X1 represents a single bond, a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms, or a group obtained by substituting at least one carbon atom in a linear, branched, or cyclic alkylene group having 1 to 20 carbon atoms with at least one structure selected from the group consisting of —O—, —NH—,

##STR00001##

—CO—, —COO—, —CONH—, and an arylene group.

An epoxy-curable silicone release coating composition and methods for its preparation and use are provided. The composition contains an inhibited Lewis acid catalyst. Releasing the Lewis acid catalyst from the inhibitor allows the Lewis acid to catalyze cure of the epoxy-groups. The composition can be coated on various substrates and cured to form a release liner.

Provided is a polymer of the formula: ##STR00001##
and compositions comprising the same. The polymers comprise a cyclic unsaturated group (Z.sup.3) within the siloxane polymer backbone. The polymers have been found to exhibit good thermal conductivity and may find utility in a variety of applications.

Provided is a polymer of the formula: ##STR00001##
and compositions comprising the same. The polymers comprise a cyclic unsaturated group (Z.sup.3) within the siloxane polymer backbone. The polymers have been found to exhibit good thermal conductivity and may find utility in a variety of applications.

Processes are described for purifying acidic, preferably superacidic, in particular trifluoromethanesulfonic acid-acidified, end-equilibrated acetoxysiloxanes, wherein the acidic, preferably superacidic, in particular trifluoromethanesulfonic acid-acidified, acetic anhydride-containing and optionally acetic acid-containing equilibrated, preferably end-equilibrated acetoxysiloxane, which is optionally dissolved in an inert solvent, is contacted with a base, the precipitate is filtered off thereafter and then the filtrate obtained is optionally purified by distillation.