A silicone-containing polyester polyol can include a reaction product prepared from reactants including: a diol; a polyol having at least three hydroxyl groups; a dimer of a fatty acid having two carboxylic acid groups, or an anhydride or ester thereof; and a silicone component having siloxane linkages and at least two reactive functional groups selected from hydroxyl groups, amino groups, thiol groups, carboxylic acid groups, anhydride groups, or combinations thereof. A coating composition for preparing an anti-fingerprinting, soft touch coating can include the silicone-containing polyester polyol and a crosslinker reactive with the silicone-containing polyester polyol.

An adhesive composition, an adhesive film comprising the same, a backplate film comprising the adhesive film, and a plastic organic light emitting display comprising the adhesive film are provided. The adhesive composition includes a (meth)acrylate-based resin, and a polymer having a melting temperature (Tm) of 35 C. or higher, wherein the polymer is a copolymer of a monofunctional polysiloxane and two or more types of monomers.

An overmolded thermoplastic article includes a substrate portion molded from a thermoplastic resin compound and an overmold portion molded from a thermoplastic elastomer compound. The thermoplastic resin compound includes thermoplastic polymer resin. The thermoplastic elastomer compound includes thermoplastic elastomer and polysiloxane as a mold release agent, and is free of wax. The overmold portion is bonded onto the substrate portion with a peel strength at least comparable to that of an overmolded thermoplastic elastomer compound containing wax as a mold release agent instead of the polysiloxane. Undesirable effects observed with the use of wax as a mold release agent in overmolded thermoplastic elastomer compounds such as blooming and ease of scratching/marring can be reduced, while desirable properties such as silky feel of the surface of the overmold portion and good bonding of the overmold portion onto the substrate portion can be at least maintained.

An overmolded thermoplastic article includes a substrate portion molded from a thermoplastic resin compound and an overmold portion molded from a thermoplastic elastomer compound. The thermoplastic resin compound includes thermoplastic polymer resin. The thermoplastic elastomer compound includes thermoplastic elastomer and polysiloxane as a mold release agent, and is free of wax. The overmold portion is bonded onto the substrate portion with a peel strength at least comparable to that of an overmolded thermoplastic elastomer compound containing wax as a mold release agent instead of the polysiloxane. Undesirable effects observed with the use of wax as a mold release agent in overmolded thermoplastic elastomer compounds such as blooming and ease of scratching/marring can be reduced, while desirable properties such as silky feel of the surface of the overmold portion and good bonding of the overmold portion onto the substrate portion can be at least maintained.

An object of the present invention is to provide a polyorganosiloxane-containing graft copolymer powder capable of providing a resin composition and a molded article which are excellent in balance between colorability and mechanical properties such as impact resistance. The polyorganosiloxane-containing graft copolymer powder according to the present invention is a graft copolymer powder obtained by graft-polymerizing a mixture (B) of a vinyl monomer (b1) having an epoxy group and another vinyl monomer (b2) to a rubber (A) containing a polyorganosiloxane, wherein the content of the polyorganosiloxane (A1) contained in the rubber (A) is 12 to 50% by mass, the mass average particle diameter of the polyorganosiloxane-containing graft copolymer powder is 300 to 2000 nm, and the epoxy equivalent of the polyorganosiloxane-containing graft copolymer powder is 2500 to 7800 g/eq.

A polysiloxane-polyester block copolymer is provided, which comprises: (i) a siloxane resin block comprising: a siloxane unit represented by the formula: R.sup.1SiO.sub.3/2, wherein R.sub.1 is a monovalent hydrocarbon group, and comprising optionally a siloxane unit represented by the formula: SiO.sub.4/2; (ii) a siloxane linear block represented by the formula: (R.sup.2.sub.2SiO.sub.2/2).sub.n, wherein each R.sup.2 is independently a monovalent hydrocarbon group, and n is a positive number of at least 5; and (iii) a polyester block. The polysiloxane-polyester block copolymer can be used for a protective coating on a substrate which is made of aluminum, stainless steel, iron, plastics or glass to provide durable heat-resistance, hot hardness, release and anti-graffiti properties.

A polysiloxane-polyester block copolymer is provided, which comprises: (i) a siloxane resin block comprising: a siloxane unit represented by the formula: R.sup.1SiO.sub.3/2, wherein R.sub.1 is a monovalent hydrocarbon group, and comprising optionally a siloxane unit represented by the formula: SiO.sub.4/2; (ii) a siloxane linear block represented by the formula: (R.sup.2.sub.2SiO.sub.2/2).sub.n, wherein each R.sup.2 is independently a monovalent hydrocarbon group, and n is a positive number of at least 5; and (iii) a polyester block. The polysiloxane-polyester block copolymer can be used for a protective coating on a substrate which is made of aluminum, stainless steel, iron, plastics or glass to provide durable heat-resistance, hot hardness, release and anti-graffiti properties.

Provided is a utensil including a support having two opposite faces, at least one of which is provided with a sol-gel coating including at least one sol-gel layer that is present in the form of a continuous film of a sol-gel material including a matrix of at least one metal polyalkoxylate. Said utensil additionally includes a hybrid sol-gel coating including at least one screen-printed sol-gel layer completely or partially covering said sol-gel coating, said first hybrid sol-gel layer consisting of a hybrid sol-gel material including a matrix formed from a first hybrid sol-gel composition including at least one silicone resin and at least one silane and/or at least one metal alkoxide. Also provided is a process for producing such a utensil.

An object of the present invention is to provide a coating composition capable of forming a coating film which can maintain its appearance and gloss over a long period and which has high film hardness and high flexibility and exhibits excellent adhesion with respect to an epoxy resin anticorrosive coating film. An acrylic polysiloxane resin coating composition of the invention includes (A) a silicone resin, (B) a compound having one or more functional groups capable of undergoing Michael addition reaction with an unsaturated double bond in an acryloyloxy group, and having one or more alkoxy groups bonded to silicon, (C) a trifunctional or polyfunctional aliphatic urethane acrylate oligomer having a cyclic structure, and (D) a bifunctional acrylate monomer having no ether structures (except an ether structure in an acryloyloxy group) and no aromatic rings, the mass ratio of the total amount of (A) and (B) to the total amount of any acrylate oligomer(s) and any acrylate monomer(s) being 40:60 to 70:30.

A water swellable cross-linked elastomer and method of preparation is provided. The elastomer can advantageously be included in skin treatment compositions. Swellable elastomers in accordance with the invention are particularly well suited for inclusion in skin tightening cosmetic products. The elastomers can be formulated to form a film. When applied to skin, an elastomer in accordance with preferred embodiments of the invention can adhere to the skin and shrink as it dries. This can provide a skin tightening, lifting and wrinkle smoothening effect upon drying. This effect can temporarily mask the appearance of wrinkles.