According to the present invention, a siliceous film forming composition, which is capable of filling trenches having narrow widths and high aspect ratios and forming a thick film, can be provided. A siliceous film forming composition comprising: (a) a block copolymer comprising a linear and/or cyclic block A having a polysilane skeleton comprising 5 or more silicon and a block B having a polysilazane skeleton comprising 20 or more silicon, and (b) a solvent.

Embodiments of the present disclosure provide a method of manufacturing a metal column using 3D printing technology. The method of manufacturing a metal column includes steps of: creasing a 3D-CAD design for printing the metal column; printing the metal column; pretreating the inner surface of a channel inside the metal column at low temperature; and coating the inner surface of the channel with a stationary phase so that the metal column is capable of separating a gas mixture into components.

A polysilazane composition comprising an organopolysilazane compound free of Si—H structure and an organoxysilane compound having at least two silicon atoms in the molecule does not release hazardous substances such as hydrogen or require reactive solvents.

The present invention relates to new coating compositions for the preparation of functional surface coatings on various base material substrates. The coating compositions are based on a silazane-containing polymer and a fluorine-containing polymer, wherein the fluorine-containing polymer comprises a first repeating unit U.sup.1 and a second repeating unit U.sup.2. The coating compositions provide improved physical and chemical surface properties and may be applied by user-friendly methods.

The present invention relates to new coating compositions for the preparation of functional surface coatings on various base material substrates. The coating compositions are based on a silazane-containing polymer and a fluorine-containing polymer, wherein the fluorine-containing polymer comprises a first repeating unit U.sup.1 and a second repeating unit U.sup.2. The coating compositions provide improved physical and chemical surface properties and may be applied by user-friendly methods.

The adhesive composition includes: a cyclic organosilazane compound of the following general formula (1):

##STR00001##

wherein R.sup.1s each independently represent a substituted or unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and p represents an integer of 3 to 8; and a hydrolyzable group-containing organosilicon compound containing an alkoxysilane

compound of the following general formula (2) and/or a partial hydrolytic condensate thereof:

R.sup.2.sub.x—Si(OR.sup.3).sub.4-x   (2)

wherein R.sup.2 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms and optionally having an oxygen atom, R.sup.3 represents an unsubstituted monovalent hydrocarbon group having 1 to 10 carbon atoms, and x represents an integer of 0 to 2.

Provided is a composition for forming a silica layer including a silicon-containing polymer, and a solvent, wherein the silicon-containing polymer has a weight average molecular weight (Mw) of 8,000 g/mol to 15,000 g/mol, and wherein a content of nitrogen atoms of the silicon-containing polymer measured by a kjeldahl titration method is 25 wt % to 30 wt % based on a total weight of the silicon-containing polymer.

Provided is a composition for forming a silica layer including a silicon-containing polymer, and a solvent, wherein the silicon-containing polymer has a weight average molecular weight (Mw) of 8,000 g/mol to 15,000 g/mol, and wherein a content of nitrogen atoms of the silicon-containing polymer measured by a kjeldahl titration method is 25 wt % to 30 wt % based on a total weight of the silicon-containing polymer.

A separator for a rechargeable lithium battery includes a porous substrate; and a coating layer on at least one surface of the porous substrate, wherein the coating layer is formed from a coating layer composition including an organosilazane compound, inorganic particles, an initiator, and a solvent, the coating layer includes a curable binder of the organosilazane compound and inorganic particles, the curable binder of the organosilazane compound includes a copolymer including a structural unit represented by Chemical Formula 1, a structural unit represented by Chemical Formula 2, and a structural unit represented by Chemical Formula 3, and a nitrogen (N) atom derived from Chemical Formula 1 is greater than about 0 at % and less than about 5 at % (atomic percent) in the coating layer, and a rechargeable lithium battery. Chemical Formula 1 to Chemical Formula 3 are as defined in the specification.

The present invention provides for a system comprising a static reactor vessel which requires no moving parts, and adapted for precise control of reaction processing parameters including temperature, pressure, and flow rate; a mechanism for settling of the product phase from the salt ammonia phase and removing a significant portion of the ammonium chloride waste material; a method for recovering essentially all of the process ammonia and a method for maintaining a reaction environment which is suitably ionic/acidic.