Patent classifications
C08G79/04
Phosphorus based co-monomer for polyamides
The present disclosure relates to a polyamide comprising at least one repeating unit of formula I: —[OC—Ar—O—P(═O)(—Ar)—O—Ar—CO—NH—R—NH]— Formula (I) wherein, Ar is independently selected from the group consisting of aryl, arylene, heteroaryl and carbocyclic group; R represents a covalent bond or a divalent hydrocarbon-based group selected from the group consisting of saturated or unsaturated aliphatics, saturated or unsaturated cycloaliphatics, aromatics, arylaliphatics, and alkylaromatics.
FLAME RETARDANT POLYMERS AND METHODS OF MAKING
Polymers useful for imparting flame resistance to fibers and textiles are provided herein. The polymers are water-soluble, phosphine oxide-containing polymers that may be reaction products of hydroxymethyl phosphonium salts or hydroxymethyl phosphines with linking monomers, wherein at least 20% of the phosphorous atoms of the polymer are present as phosphine oxides. Formulations including the polymers and methods of using the polymers to impart flame resistance to fibers and textiles are also disclosed.
FLAME RETARDANT POLYMERS AND METHODS OF MAKING
Polymers useful for imparting flame resistance to fibers and textiles are provided herein. The polymers are water-soluble, phosphine oxide-containing polymers that may be reaction products of hydroxymethyl phosphonium salts or hydroxymethyl phosphines with linking monomers, wherein at least 20% of the phosphorous atoms of the polymer are present as phosphine oxides. Formulations including the polymers and methods of using the polymers to impart flame resistance to fibers and textiles are also disclosed.
METHOD FOR RECYCLING RESIDUAL SOLUTIONS COMPRISING PHOSPHORUS AND DEVICE FOR SUCH A METHOD
A method and device for the purification of phosphoric acid contained in a residual solution is provided that includes undesirable volatilizable materials. The residual solution is mixed with a solution of enriched phosphoric acid and is sprayed into a flame of a combustion chamber in order to form a combustion solution P3 of phosphoric acid purified of the undesirable volatilizable materials. The combustion gases resulting from the combustion chamber are contacted with a feed solution in a gas-acid contactor in order to increase the temperature and concentration of P.sub.2O.sub.5 and thus to form the solution of enriched phosphoric acid. A portion of this solution is conveyed at a flow rate Qp into the combustion chamber. The remainder of the solution is conveyed into a recycle loop in order to be reintroduced into the gas/acid contactor at a flow rate Q2. The ratio of the flow rates, Qp/(Qp+Q2) is controlled at a predefined value.
IONIC POLYMERS COMPRISING BIOLOGICALLY ACTIVE COMPOUNDS
Compounds useful as biologically active compounds are disclosed. The compounds have the following structure (I): structure (I) or a stereoisomer, tautomer or salt thereof, wherein R.sup.1, R.sup.2, R.sup.3, L, L.sup.1, L.sup.2, L.sup.3, L.sup.4, M and n are as defined herein. Methods associated with preparation and use of such compounds are also provided.
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ORAL CARE COMPOSITIONS COMPRISING PHOSPHONO-PHOSPHATE AND ANIONIC GROUP CONTAINING POLYMERS
Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.
ORAL CARE COMPOSITIONS COMPRISING PHOSPHONO-PHOSPHATE AND ANIONIC GROUP CONTAINING POLYMERS
Disclosed are oral care compositions of novel phosphono-phosphate and anionic group containing polymer compositions that have targeted uses with divalent cations and surfaces having divalent cations. These compounds can be used to deliver anionic character to surfaces such as calcium hydroxyapatite for use in oral care applications.
Fire resistant phosphate cyanate esters
This invention describes resins with phosphate cores and a simple, three-step process for their synthesis. Preferred resins are cyanate ester resins with bridging phosphate groups. These resins can be cured to produce thermoset polymers having T.sub.gs of between 131 and >360 C. depending on the number of cyanate ester groups per phosphate and the substitution pattern of the aromatic rings. The high char yields of these resins, up to about 67%, coupled with the phosphate core means that these materials will have applications as fire-resistant polymers. Additionally, these materials can potentially be blended with conventional cyanate esters or other compatible thermosetting resins to improve the fire resistance of composite materials. Other applications may include use in fire-resistant circuit boards, or as surface coatings to reduce flammability of conventional composite materials or thermoplastics.
Fire resistant phosphate cyanate esters
This invention describes resins with phosphate cores and a simple, three-step process for their synthesis. Preferred resins are cyanate ester resins with bridging phosphate groups. These resins can be cured to produce thermoset polymers having T.sub.gs of between 131 and >360 C. depending on the number of cyanate ester groups per phosphate and the substitution pattern of the aromatic rings. The high char yields of these resins, up to about 67%, coupled with the phosphate core means that these materials will have applications as fire-resistant polymers. Additionally, these materials can potentially be blended with conventional cyanate esters or other compatible thermosetting resins to improve the fire resistance of composite materials. Other applications may include use in fire-resistant circuit boards, or as surface coatings to reduce flammability of conventional composite materials or thermoplastics.
PROGRAMMABLE POLYMERIC DRUGS
Compounds useful as biologically active compounds are disclosed. The compounds have the following structure (I): or a stereoisomer, tautomer or salt thereof, wherein R.sup.1, R.sup.2, R.sup.3, L, L.sup.1, L.sup.2, L.sup.3, M and n are as defined herein. Methods associated with preparation and use of such compounds is also provided.