C08G81/024

BLOCK POLYMER COMPOSITE MEMBRANES

A highly permeable sorbent platform based on polysulfone and polystyrene-b-poly(acrylic acid) composite membranes. The membranes possess a fully interconnected network of poly(acrylic acid)-lined pores, which enables the surface chemistry to be tailored through sequential attachment of polyethyleneimine moieties and metal-binding terpyridine ligands. The polyethyleneimine moieties increase the saturation capacity, while the addition of terpyridine enables high-affinity binding to a diversity of transition metal ions. This membrane platform removes such metal contaminants from solution. The metal capture performance of the functionalized membranes persists even in high concentrations of competitive ions. Also, fluorescence quenching of the terpyridine moiety upon metal ion complexation offers an in-situ probe to monitor the extent of sorbent saturation. The permeability, capacity, and affinity of these membranes, with high-density display of a metal-binding ligand, offer a chemically tailored platform to address the challenges that arise in ensuring clean water.

POLYMERIC ADHESIVE FOR ANCHORING COMPLIANT MATERIALS TO ANOTHER SURFACE

Methods, compositions, and kits for adhering polymers and other materials to another material, and in particular to bone or bone-like structures or surfaces. A composition of matter includes a urethane dimethacrylate-methyl methacrylate copolymer with a plurality of first polymer regions based on urethane dimethacrylate and a plurality of second polymer regions based on methyl methacrylate. The method includes placing an orthopedic joint implant having an attachment surface in a joint space, applying a first non-urethane-containing precursor, a second urethane-containing precursor, and a initiator to the attachment surface; contacting the first and second precursors and the initiator with the joint surface; and copolymerizing the first and second precursors and forming an adhesive copolymer and attaching the implant to the joint.

Methods and compositions relating to carnitine-derived materials
11103588 · 2021-08-31 · ·

Zwitterionic monomers, carnitine-derived zwitterionic polymers, carnitine ester cationic monomers, carnitine ester cationic polymers, conjugate compositions including a carnitine-derived zwitterionic polymer, and related compositions' and methods are provided which have various uses including as coatings, pharmaceuticals, diagnostics, encapsulation materials, and antifouling materials, among other utilities.

Alkoxylated dispersing agents

Described herein are alkoxylated polymers suitable for use in primers, inks or coating compositions. The alkoxylated polymers derive from a polyalkylene glycol polymer or copolymer backbone having one or more alkoxylated sites in a non-reactive form and at least one reactive terminal end, and one or more polyfunctional monomers or oligomers having two or more functional polar groups with an active hydrogen, or mixtures thereof, wherein the alkoxylated polymer is polymerized in a one step process. Primers, inks or coating compositions are further described.

Hydrogenated polymers with a radial structure having a core based on calixarenes and use thereof in lubricant compositions

Hydrogenated polymers with a radial structure having a core made up of calixarenes of the general formula (I), to the core of which is linked a number P of hydrogenated linear polymer segments selected from: —hydrogenated homopolymers or co-polymers of conjugated dienes; or—hydrogenated co-polymers of said conjugated dienes and monoalkenyl arenes, and—mixtures thereof said formula (I) in which: —R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently selected from hydrogen; a group containing carbon and hydrogen; a group also containing heteroatoms in addition to carbon and hydrogen; a group also containing silicon in addition to carbon, hydrogen and heteroatoms; —one of the two substituents R.sub.5 and R.sub.6 is hydrogen, while the other may be hydrogen or alkyl, with a number of carbon atoms between 1 and 6, preferably methyl and ethyl; —n is an integer in the range between 4 and 16. ##STR00001##

THERMORESPONSIVE FDM PRINTER FILAMENT FOR FORMING VASCULAR CHANNELS IN HYDROGELS
20210292489 · 2021-09-23 ·

Provided arm biocompatible polymer compositions, and methods of printing such polymer compositions using a fused deposition modelling printer to form a solid scaffold. In particular, the disclosed compositions may include a thermoresponsive polymer, and the printed scaffold may be used as a sacrificial template providing a three-dimensional vascular structure upon temperature-dependent disintegration. The present compositions and methods may be particularly useful for engineering thick tissues.

Aqueous dispersions containing polymerizates produced in multiple stages with polyurethanes as well as coating agent compositions containing same

Aqueous dispersions including multistage-prepared polymers of mixtures of olefinically unsaturated compounds are disclosed. The aqueous dispersions include at least one polyurethane containing olefinically unsaturated groups. Production and use of the aqueous dispersions, particularly in the field of automotive finishing, is disclosed. The disclosure further relates to an aqueous basecoat material including the multistage-prepared polymers, and also to a method for producing a multicoat paint system using the aqueous basecoat material.

Block copolymer and surface treatment agent using same

The present invention addresses the problem of providing a block copolymer which is useful as a surface treatment agent for cell culture substrates, said surface treatment agent enabling cell separation in a short period of time. The above-mentioned problem is solved by a block copolymer that includes the following blocks (A), (B) and (C): (A) a temperature-responsive polymer block that has a lower critical solution temperature (LCST) within the range of from 0° C. to 50° C. with respect to water (B) a hydrophilic polymer block that does not have an LCST within the range of from 0° C. to 50° C., while having an HLB value within the range of from 9 (inclusive) to 20 (exclusive) (C) a hydrophobic polymer block that does not have an LCST within the range of from 0° C. to 50° C., while having an HLB value within the range of from 0 (inclusive) to 9 (exclusive).

FUNCTIONALIZED POLY(DIALLYLPIPERIDINIUM) AND ITS COPOLYMERS FOR USE IN ION CONDUCTING APPLICATIONS
20210178340 · 2021-06-17 ·

The invention relates to membranes, monomers and polymers. The monomers can form polymers, which can be used for membranes. The membranes can be used in alkaline fuel cells, for water purification, for electrolysis, for flow batteries, and for anti-bacterial membranes and materials, as well as membrane electrode assemblies for fuel cells. In addition to the membranes, polymers and monomers and methods of using the membranes, the present invention also relates to methods of making the membranes, monomers and polymers.

AQUEOUS RESIN COMPOSITION, COATING AGENT, AND ARTICLE
20210189131 · 2021-06-24 · ·

Provided is an aqueous resin composition having a composite resin (ABC) dissolved or dispersed in an aqueous medium, and further containing a plasticizer (D), the composite resin (ABC) having a polysiloxane segment (B) and a polysiloxane segment (C) which are bonded through a silicon-oxygen bond, wherein the polysiloxane segment (B) is present in a composite resin (AB) having a polymer segment (A) having a neutralized acid group and the polysiloxane segment (B), which are chemically bonded to each other, and the polysiloxane segment (C) is derived from a condensation product (c) of an alkyltrialkoxysilane having an alkyl group having 1 to 3 carbon atoms, wherein the content of the total of the polysiloxane segment (B) and the polysiloxane segment (C) in the composite resin (ABC) is 15 to 85% by mass. The aqueous resin composition can form a coating film which is excellent in appearance of the coating film.