A polishing pad includes: a polishing layer having a polyurethane sheet containing substantially spherical cells, wherein E′(90%)/E′(30%) falls within a range of 0.4 to 0.7, where E′(90%) represents a storage modulus of the polyurethane sheet that has been exposed to an environment with a temperature of 23° C. and a relative humidity of 90%, as measured in a tension mode at 40° C. with an initial load of 148 g, a strain range of 0.1%, and a measurement frequency of 1.6 Hz, and E′(30%) represents a storage modulus of the polyurethane sheet that has been exposed to an environment with a temperature of 23° C. and a relative humidity of 30%, as measured in a tension mode at 40° C. with an initial load of 148 g, a strain range of 0.1%, and a measurement frequency of 1.6 Hz. Also provided is a method for manufacturing the polishing pad.

A thermoplastic polyurethane (TPU) foam product with high flatness, and a preparation method and a use thereof are provided. The TPU foam product is prepared by processing aliphatic thermoplastic polyurethane (ATPU) beads with a melting range of 20° C. to 50° C. and a melting point of 90° C. to 160° C. by a physical gas foaming process to obtain foamed ATPU beads and heating the foamed ATPU beads with a heat source to make the foamed ATPU beads fused. The TPU foam product with high flatness has a density of 0.08 g/cm.sup.3 to 0.8 g/cm.sup.3 and a flatness value of less than 2 mm, and the flatness value is determined by a fixed-length ruler. The TPU foam product not only has high flatness such that diversified designs are allowed for a surface of the product, but also has high resilience.

The present disclosure relates to a method for making a non-isocyanate polyurethane (NIPU) foam, where the method includes decomposing a blowing agent having at least one of an amine carbamate salt and/or an amine bicarbonate salt to form a diamine and CO.sub.2 in the presence of a molecule comprising a plurality of cyclic carbonate functional groups and reacting the diamine with at least a portion of the cyclic carbonate functional groups to form the NIPU foam. In some embodiments of the present disclosure, the reacting and the decomposing may occur at substantially the same rate.

Foamable waterborne dispersions which form stable flexible foams under ambient cure conditions are disclosed, said foamable waterborne dispersions comprising: a polyurethane polymer formed from one or more aliphatic or cycloaliphatic polyisocyanate and at least two different polymeric polyol components selected from polyether polyol, polyester polyol, and polycarbonate polyol; wherein the ambient cure conditions include a temperature of from 4° C. to 32° C., and a humidity of 0% relative humidity to 90% relative humidity. Also disclosed are the flexible foams produced from the foamable waterborne dispersions, as well as methods of providing a space filling layer or space filling volume adjacent to or on a surface, said methods comprising applying to said surface a foamed sample of the foamable waterborne dispersions, and allowing the foamed sample of foamable waterborne dispersion to dry under ambient conditions to yield a stable flexible foam.

A flexible foam composition comprising a flexible foam structure comprising a plurality of struts, and a plurality of fibers, where a majority of the fibers are associated with the struts. The fibers may be thermally conductive fibers. The fibers include, but are not necessarily limited to, homopolymer and/or copolymer fibers having a glass transition temperature (Tg) of −50° C. (−58° F.) or greater, carbon fibers, animal-based fibers, plant-based fibers, metal fibers, and combinations thereof. The presence of fibers can impart to the flexible foam composition greater indentation force deflection (IFD), greater static thermal conductivity, improved compression set, improved height retention or durability, and/or a combination of these improvements. The flexible foam composition may be polyurethane foam, latex foam, polyether polyurethane foam, viscoelastic foam, high resilient foam, polyester polyurethane foam, foamed polyethylene, foamed polypropylene, expanded polystyrene, foamed silicone, melamine foam, among others.

A process for producing rigid PUR/PIR foams via the reaction of a reaction mixture comprising A1 an isocyanate-reactive component, A2 a flame retardant, A3 a blowing agent, A4 a catalyst, and A5 optionally auxiliaries and additives with B an organic polyisocyanate component. Component A1 comprises a diurethane diol A1.1 and a compound A1.2 selected from the group consisting of polyether polyol, polyester polyol, polyether carbonate polyol, and polyether ester polyol. Also disclosed is a rigid PUR/PIR foam, an insulating material, a composite element, and a mixture.

A flexible foam composition comprising a flexible foam structure comprising a plurality of struts, and a plurality of fibers, where a majority of the fibers are associated with the struts. The fibers may be thermally conductive fibers. The fibers include, but are not necessarily limited to, homopolymer and/or copolymer fibers having a glass transition temperature (Tg) of −50° C. (−58° F.) or greater, carbon fibers, animal-based fibers, plant-based fibers, metal fibers, and combinations thereof. The presence of fibers can impart to the flexible foam composition greater indentation force deflection (IFD), greater static thermal conductivity, improved compression set, improved height retention or durability, and/or a combination of these improvements. The flexible foam composition may be polyurethane foam, latex foam, polyether polyurethane foam, viscoelastic foam, high resilient foam, polyester polyurethane foam, foamed polyethylene, foamed polypropylene, expanded polystyrene, foamed silicone, melamine foam, among others.

In the present invention, there is provided an urethane resin composition containing an urethane resin (A), water (B), and a surfactant (C) having no aromatic ring, and having a hydrophobic portion having 10 or more carbon atoms, wherein the urethane resin composition has a carbonate structure (X) and an oxyalkylene structure (Y) derived from the urethane resin (A). Further, the present invention provides a foamed urethane sheet which is formed from the urethane resin composition, wherein the foamed urethane sheet has a density of 200 to 1,000 kg/m.sup.3. The urethane resin composition according to claim 1, wherein the mass ratio of the carbonate structure (X) to the oxyalkylene structure (Y) [X/Y] is in the range of from 10/90 to 90/10.

A polyurethane composition is provided. The polyurethane composition comprises (A) one or more polyurethane-prepolymers prepared by reacting at least one polyisocyanate compound with a first polyol component; and (B) a second polyol component; wherein at least one of the first polyol component and the second polyol component comprises an ester/ether block copolymer polyol synthesized by reacting a starting material polyether polyol with a C.sub.4-C.sub.20 lactone. The polyurethane foam prepared by using the polyurethane composition can achieve inhibited internal heat buildup, high thermal stability and superior tear strength. A polyurethane product prepared with said foam, a method for preparing the polyurethane foam and a method for improving the performance property of the polyurethane foam are also provided.

The present invention provides CMP polishing pads or layers having a unfilled Shore D (2 second) hardness of from 57-77 or a filled Shore D (2 second) hardness of from 18-50, made from a two-component reaction mixture of (i) a liquid aromatic isocyanate component comprising one or more aromatic diisocyanates or a linear aromatic isocyanate-terminated urethane prepolymer having an unreacted isocyanate (NCO) concentration of from 18 to 47 wt. %, based on the total solids weight of the aromatic isocyanate component, and (ii) a liquid polyol component including one or more curatives selected from the group of amines defined by Formulas (I) and (II).